Foams based on low density polyethylene/hectorite nanocomposites: Thermal stability and thermo‐mechanical properties

Novel polymer nanocomposite foams made by a two step compression molding method are analyzed in this article. Nanocomposites of low density polyethylene and an organo‐modified hectorite were first melt compounded and then foamed using a compression molding method. To study the influence of the presence and the amount of hectorite in both mechanical and thermal properties, samples with 3% and 7% content of hectorite were prepared. Polyethylene crystalline characteristics and thermal stability of the samples were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Mechanical properties of foams and solid nanocomposites were analyzed by using dynamical mechanical analysis (DMA). Thermal expansion of the samples was analyzed by thermomechanical analysis. The results indicate that the exfoliation of hectorite platelets was achieved after the foaming process, but not during the melt mixing step. Foams with hectorite nanoparticles exhibit improved thermal stability and mechanical properties when compared with neat polymeric foams. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Governance and Climate Vulnerability Index

Water resources in the Middle East are under enormous stress, due to an increase in population growth and the extensive use of water resources, which exceeds the water demand in this regional bloc. Moreover, climatic changes pose another dimension of stress on water resources; these changes have significant environmental, social, and economic effects. In fact, the governance of these countries has the tendency of increasing this stress or decreasing it, depending on its performance and efficiency in applying policies, legislation and managerial plans towards decreasing the poverty and the vulnerability of the countries specially those suffering from poverty. In this paper, the vulnerability of five countries-Israel, Jordan, Lebanon, Palestine and Syria??will be assessed based on the extent of climate changes and the type of climate governance and their effects on water resources. This paper will introduce a new index, which will be called the Governance and Climate Vulnerability Index (GCVI). The index will measure the vulnerability of each country vis-à-vis water-related issues, while taking into account governance and climatic indicators. The vulnerability of these countries will also be ranked, for purposes of comparison. This paper concludes with the recommendation for governments to develop appropriate water resources management and to improve their environmental policies, including raising awareness on multiple levels. These strategies are expected to lead to decreased vulnerability to climatic changes.     

Spectral efficiency (SE) enhancement of NOMA system through iterative power assignment

Wireless Networks - This paper studies enhancing non-orthogonal multiple access (NOMA) spectral efficiency (SE) through optimizing the assigned power to each NOMA user depending on their channel...     

Saturation swelling and the seeded emulsion polymerisation of styrene at high ionic strength

The effects of adding inorganic electrolyte (below the critical coagulation concentration) have been investigated in two systems for the emulsion polymerisation of styrene. In one system, potassium chloride, at different concentrations, was added at the end of interval I, using three different ionic emulsifiers: potassium octadecanoate which has a low critical micelle concentration (CMC), potassium dodecanoate and sodium dodecyl sulphate (SDS), which have moderately high CMC. A significant increase in the rate of polymerisation was observed in all cases even at the higher levels of electrolyte at which the rate is reduced if the electrolyte is added from the onset of polymerisation. In the second system, the effects of adding sodium chloride, in concentrations up to 0.2_M, on the seeded emulsion polymerisation of styrene have been followed. A significant increase in the rate was observed as electrolyte level was increased, with no significant change in particle size. Saturation swelling measurements indicated a slight increase in monomer concentration inside the particles as electrolyte concentration was increased. Evaluation of the average number of free radicals per particle, n¯, by a steady state approach indicates an increase in the value of n¯ as electrolyte level is increased. The value of n¯ is below 0.5 but approaches this value at the highest electrolyte concentration. The increased surface area of the particles may account for this effect by increasing the capture efficiency of the radicals by the particles.     

Spiritual struggle related to plasma interleukin-6 prior to cardiac surgery.

Spiritual struggle appeared consistently to predict poor health outcomes, including mortality. Despite surging interest in the health benefits of religion and spirituality, the health hassle of existential conflicts and proinflammatory cytokines as a potential physiological mechanism has been overlooked. Based on psychological and theological assumptions, we argue for the universal nature of spiritual struggle, a crisis-related existential conflict, and for investigating its physiological influence as essential to understanding human nature. Increased levels of inflammatory cytokines such as interleukin-6 (IL-6) have been linked with adverse health outcomes and negative emotions. This study thus examined spiritual struggle related to plasma IL-6 in 235 adult patients undergoing cardiac surgery, along with positive religious coping, general coping, and optimism, controlling for standardized clinical medical indicators. Multiple regression analysis, following a preplanned sequence, showed that spiritual struggle (p = .011), behavioral coping (p = .013) were positively associated with excess plasma IL-6, controlling for medical correlates (e.g., left ventricular ejection fraction). We conclude that spiritual struggle, indicating the crisis in an existential relation, and behavioral coping strategies are associated with elevated pre-operative plasma IL-6. The interdisciplinary implications are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Theoretical calculations of the surface tension of Ag(1−x)-Cu(x) liquid alloys

The surface tension of silver-copper binary liquid alloys is calculated, in the frame work of Eyring theory. The calculations were made for different compositions (mole fraction, x_Cu = 0, 0.2, 0.4, 0.6, 0.8 and 1), in the temperature range 1100-1800 K. The surface tension decreases with temperature increase, at a fixed copper fraction x_Cu, and increases with increasing copper content. The calculated results are appropriately compared with existing literature data.     

Co(II)(l-proline)2(H2O)2 solid complex: Characterization,magnetic properties,and DFT computations. Preliminary studies of its use as oxygen scavenger in packaging films

A solid Co^II complex with l-proline as ligand was synthesized and fully characterized using spectroscopic studies, magnetic data, and DFT calculations. Dioxygen scavenging properties were investigated by UV/Vis spectroscopy and oxymetry techniques. The Co-proline system presented very interesting properties in matter of oxygen absorption capacity both in solution and incorporated in a polymer matrix.