全文获取类型
收费全文 | 190篇 |
免费 | 17篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 4篇 |
综合类 | 1篇 |
化学工业 | 47篇 |
金属工艺 | 15篇 |
机械仪表 | 5篇 |
建筑科学 | 9篇 |
能源动力 | 14篇 |
轻工业 | 19篇 |
水利工程 | 4篇 |
石油天然气 | 5篇 |
无线电 | 24篇 |
一般工业技术 | 22篇 |
冶金工业 | 16篇 |
原子能技术 | 2篇 |
自动化技术 | 23篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 3篇 |
2021年 | 10篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2018年 | 13篇 |
2017年 | 15篇 |
2016年 | 9篇 |
2015年 | 4篇 |
2014年 | 10篇 |
2013年 | 19篇 |
2012年 | 11篇 |
2011年 | 15篇 |
2010年 | 6篇 |
2009年 | 9篇 |
2008年 | 5篇 |
2007年 | 5篇 |
2006年 | 4篇 |
2005年 | 2篇 |
2004年 | 1篇 |
2003年 | 4篇 |
2002年 | 2篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1971年 | 2篇 |
排序方式: 共有210条查询结果,搜索用时 31 毫秒
1.
Nur Lina Rashidah Mohd Rashid Abdullah Abdul Samat Abdul Azim Jais Mahendra Rao Somalu Andanastuti Muchtar Nurul Akidah Baharuddin Wan Nor Roslam Wan Isahak 《Ceramics International》2019,45(6):6605-6615
The performance of low-to-intermediate temperature (400–800?°C) solid oxide fuel cells (SOFCs) depends on the properties of electrolyte used. SOFC performance can be enhanced by replacing electrolyte materials from conventional oxide ion (O2-) conductors with proton (H+) conductors because H+ conductors have higher ionic conductivity and theoretical electrical efficiency than O2- conductors within the target temperature range. Electrolytes based on cerate and/or zirconate have been proposed as potential H+ conductors. Cerate-based electrolytes have the highest H+ conductivity, but they are chemically and thermally unstable during redox cycles, whereas zirconate-based electrolytes exhibit the opposite properties. Thus, tailoring the properties of cerate and/or zirconate electrolytes by doping with rare-earth metals has become a main concern for many researchers to further improve the ionic conductivity and stability of electrolytes. This article provides an overview on the properties of four types of cerate and/or zirconate electrolytes including cerate-based, zirconate-based, single-doped cerate–zirconate and hybrid-doped cerate–zirconate. The properties of the proton electrolytes such as ionic conductivity, chemical stability and sinterability are also systematically discussed. This review further provides a summary of the performance of SOFCs operated with cerate and/or zirconate proton conductors and the actual potential of these materials as alternative electrolytes for proton-conducting SOFC application. 相似文献
2.
3.
Graphite electrodes were prepared by mixing calcined coke and coal tar pitch. They were pressed under 250 kg cm–2 and heat treated up to 2800° C. Rectangles measuring 70 mm x 40 mm x 8 mm were anodically polarized under galvanostatic and potentiostatic conditions. Electrolyses were conducted at 10–50 mA cm–2 for periods ranging from 10–120 hours in Na2SO4 solutions acidified with sulphuric acid to various pH values. The wear of graphite anodes increased with decreasing bath temperature, increasing acid concentration, decreasing pH of the electrolyte and increasing current density. A model is suggested which assumes that corrosion takes place via the formation of a lamellar crystal compound with the formula (C
8
0
O)(OH)3HSO
4
–
·2H2SO4.The compound is unstable at higher temperatures when corrosion is effected by oxidation of graphite by atomic oxygen. The formation of the carbon ions was found to be a necessary precondition for the formation of the complex. 相似文献
4.
A polyaniline–TiO2 composite (PTC) was prepared by oxidative polymerization of aniline in phosphoric acid with ammonium persulphate, in the presence of TiO2. The composite was characterized by spectroscopic methods. An acrylic paint containing the PTC was prepared and the coating formed on magnesium alloy was evaluated by electrochemical impedance spectroscopy after exposure to salt spray test for a period of 250 h. The coating containing the PTC was found to protect the magnesium alloy more efficiently than the coating containing polyaniline. 相似文献
5.
Ayman M. Atta Manar E. Abdel‐Raouf Shimaa M. Elsaeed Abdel‐Azim A. Abdel‐Azim 《应用聚合物科学杂志》2007,103(5):3175-3182
Unsaturated polyester resin (UP) was prepared from glycolyzed oligomer of poly(ethylene terephthalate) (PET) waste based on diethylene glycol (DEG). New diacrylate and dimethacrylate vinyl ester resins prepared from glycolysis of PET with tetraethylene glycol were blended with UP to study the mechanical characteristics of the cured UP. The vinyl ester resins were used as crosslinking agents for unsaturated polyester resin diluted with styrene, using free‐radical initiator and accelerator. The mechanical properties of the cured UP resins were evaluated. The compressive properties of the cured UP/styrene resins in the presence of different vinyl ester concentrations were evaluated. Increasing the vinyl ester content led to a pronounced improvement in the compression strength. The chemical resistances of the cured resins were evaluated through hot water, solvents, acid, and alkali resistance measurements. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3175–3182, 2007 相似文献
6.
Yuko ShimodaM. Ekram Azim Gurbir PerharMaryam Ramin Melissa A. KenneySomayeh Sadraddini Alex GudimovGeorge B. Arhonditsis 《Journal of Great Lakes research》2011,37(1):173-193
Climatic change is recognized as an important factor capable of influencing the structural properties of aquatic ecosystems. Lake ecosystems are particularly sensitive to climate change. Several long time-series studies have shown close coupling between climate, lake thermal properties and individual organism physiology, population abundance, community structure, and food-web structure. Understanding the complex interplay between climate, hydrological variability, and ecosystem structure and functioning is essential to inform water resources risk assessment and fisheries management. The purpose of this paper is to present the current understanding of climate-induced changes on lake ecosystem phenology. We first review the ability of climate to modulate the interactions among lake hydrodynamics, chemical factors, and food-web structure in several north temperate deep lakes (e.g., Lake Washington, Lake Tahoe, Lake Constance, Lake Geneva, Lake Baikal, and Lake Zurich). Our aim is to assess long-term trends in the physical (e.g., temperature, timing of stratification, and duration of ice cover), chemical (e.g., nutrient concentrations), and biological (e.g., timing of the spring bloom, phytoplankton composition, and zooplankton abundance) characteristics of the lakes and to examine the signature of local weather conditions (e.g., air temperature and rainfall) and large-scale climatic variability (e.g., ENSO and PDO) on the lake physics, chemistry and biology. We also conducted modeling experiments to quantify the relative effect of climate change and nutrient loading on lake phenology. These modeling experiments focused on the relative changes to the major causal associations underlying plankton dynamics during the spring bloom and the summer stratified period. To further understand the importance of climate change on lakes, we propose two complementary directions of future research. First, additional research is needed to elucidate the wide array of in-lake processes that are likely to be affected by the climate change. Second, it is essential to examine the heterogeneity in responses among different water bodies. The rationale of this approach and its significance for dealing with the uncertainty that the climate signals cascade through lake ecosystems and shape abiotic variability and/or biotic responses have been recently advocated by several other synthesis papers. 相似文献
7.
Signal processing can be performed in time domain as well as intransform domain. Frequency domain is perhaps the most widely used domain for transform domain signal processing. In this paper we analyze sequency domain (SD) signal processing as an alternate to the conventional frequency domain signal processing. We perform signal processing in sequency domain using conjugate-symmetric sequency-ordered complex Hadamard transform and compare the results with those of discrete Fourier transform. We observe that in comparison with frequency spectrum, spectral energy of sequency spectrum is spread over the entire spectrum. We performed signal and image denoising in SD and found that our designed SD filters effectively denoise the signals. 相似文献
8.
9.
Azim Ziyaei Halimehjani M. Ali Alaei Farzaneh Soleymani Movahed Negin Jomeh Mohammad R. Saidi 《Journal of Sulfur Chemistry》2016,37(5):529-536
An effective approach for the synthesis of 2-(alkylthio)thiazol-4(5H)-ones from alkyl dithiocarbamates and chloroacetyl chloride in the presence of NaHCO3 has been developed. Good to excellent yields of products, simple reaction conditions and general applicability are the most important advantages of this protocol. 相似文献
10.