Diffusion of two associated solvents in various compositions through a swelling polymer material,EVAc

The particular sorption by a swelling polymer with the transfer of hydrocarbons was studied in order to evaluate some barrier properties of this material. The transfer of two types of solvents through two varieties of ethylene vinyl acetate was investigated: absorption of pure toluene and pure n‐hexane and absorption of a toluene/hexane mixture in various compositions. A comparison between the two processes showed that these transfers were very different and depended on two factors: vinyl acetate content and composition of the mixture. The kinetics of absorption were calculated for various compositions. The profiles of concentration as well as the kinetics of swelling were evaluated using a numerical model deduced from the general theory of radial diffusion of a substance with change in dimensions. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2099–2106, 2007     

Natural occurrence of zearalenone in Tunisian wheat grains

Fusarium mycotoxins are worldwide occurring in cereals and they are frequently reported in fresh or stored grains. Cereals represent a staple food for the Tunisian population; it therefore has a high social, economic and nutritional relevance. Zearalenone (ZEN) is a non-steroidal estrogenic mycotoxin produced by a variety of Fusarium fungi in temperate and warm countries. Fungi-producing ZEN contaminates corn, barley, wheat, sorghum and rice. A total of 205 samples of wheat were collected during the harvest year of 2010 from the major cropping areas in Tunisia and they were analyzed for zearalenone contamination. The aim of this study was to investigate for the first time the presence of ZEN in widely-consumed cereals in Tunisia, especially durum and tender wheat, to compare the levels of contamination by ZEN with the European norms and to suggest some factors that can promote the production of ZEN in Tunisia. To perform this study, we developed and validated in our laboratory conditions an HPLC method for quantitative analysis of ZEN in solid cereal samples. Our results showed that the incidence of ZEN contamination was 75%. The levels of contamination determined in the positive samples ranged between 3 and 560 μg/kg with a mean value of 60 μg/kg. These important amounts of ZEN in wheat can be attributed to the Tunisian climate, warm temperature and prolonged wetness witch are favor to Fusarium growth and mycotoxin production during the cultivation and the final ripening period of wheat grains.     

Optimal Sizing of a DBD Ozone Generator Using Response Surface Modeling

Dielectric barrier discharge (DBD) reactors used as ozone generators are well known today and widely used for water treatment and air disinfection. The purpose of this article is to propose an experimental procedure based on the response surface modeling in order to optimize the geometrical dimensions of the cylindrical shape ozone generator, i.e., the discharge gap and the electrodes length. Because an effective ozone generator is expected to give high ozone concentration with a minimum of power requirements, the applied high voltage was associated with the geometrical parameters to carry out a composite centered faces design. Obtained results indicate that for an efficient ozone generator, length of the electrodes needs to be optimized while the discharge gap should be minimized.     

Functional Causality between Oil Prices and GDP Based on Big Data

This paper examines the causal relationship between oil prices and the Gross Domestic Product (GDP) in the Kingdom of Saudi Arabia. The study is carried out by a data set collected quarterly, by Saudi Arabian Monetary Authority, over a period from 1974 to 2016. We seek how a change in real crude oil price affects the GDP of KSA. Based on a new technique, we treat this data in its continuous path. Precisely, we analyze the causality between these two variables, i.e., oil prices and GDP, by using their yearly curves observed in the four quarters of each year. We discuss the causality in the sense of Granger, which requires the stationarity of the data. Thus, in the first Step, we test the stationarity by using the Monte Carlo test of a functional time series stationarity. Our main goal is treated in the second step, where we use the functional causality idea to model the co-variability between these variables. We show that the two series are not integrated; there is one causality between these two variables. All the statistical analyzes were performed using R software.     

The Spray-Pyrolyzed Copper Oxide Properties Based Precursor Concentration

Silicon - In this work, we report the effects of the precursor concentration on some physical properties of the spray pyrolyzed copper oxide films (CSi1-CSi4) on porous silicon substrates. Useful...     

Synthesis of CdS Nanoparticles by Hydrothermal Method and Their Effects on the Electrical Properties of Bi-based Superconductors

Cadmium sulfide (CdS) nanoparticles were synthesized by hydrothermal process and have been characterized by x-ray diffraction (XRD), transmission electron microscopy (TEM), and energy-dispersive x-ray spectroscopy (EDXS) system. The effect of added CdS nanoparticles on the superconducting properties and flux pinning capability in (Bi,Pb)₂Sr₂Ca₂Cu₃O_y system (denoted as (Bi,Pb)-2223) has been reported. Hydrothermal method is an effective route to synthesize CdS nanoparticles with good crystallinity and having average grain size of about 12 nm. Then, small amounts (0–0.4 wt%) of nanosized CdS particles were added to Bi-2233 samples using a solid-state reaction route. The transport critical current densities and the electrical resistivity ρ(T, H) were performed using the four-probe technique. The results show that samples sintered by small amount of CdS nanoparticles (≤?0.3 wt%) exhibit the higher critical current densities and energy pinning in applied magnetic fields compared to free added sample. Consequently, the addition of CdS could introduce effective pinning centers which account for the improvement in superconducting properties in the Bi-2223 materials.     

Effect of pre-deposition annealing on physical properties of CZTSSe thin films deposed by RF-sputtering based on nanoparticles synthesized by solvothermal technique

This work aims to highlight the beneficial effect of annealing of Cu₂ZnSn(S,Se)₄ (CZTSSe) nanoparticles (NPs) on the properties of the obtained films by RF-magnetron sputtering at room temperature (RT) and at 200 °C. The CZTSSe targets used for the deposition are obtained using nanoparticles synthesized by solvothermal technique. It is denoted that the elemental composition of thin films becomes independent of the growth temperature in the case of annealed CZTSSe NPs. The optical investigation gives that the gap energy is ranging between 1.26 and 1.40 eV with an Urbach’s energy between 100 and 200 meV. By using the Wemple and Didominico model to analyze the refractive index spectra, we have identified common oscillator energy for all CZTSSe thin films and dispersion energy ranging from 2.63 to 5.81 eV. CZTSSe thin films obtained by means of annealed NPs exhibit higher dielectric constant and refractive index. The dispersion of different parameters with experimental conditions is analyzed via a common relationship that illustrates the linear dependence of n₀, E_d, ε_s, and ε_L on the square of the valence difference (ΔZ). The conductivity spectra are deduced, and a theoretical model was identified to fit the permittivity spectra. The obtained results are promising for solar cell applications.

     

Novel thiophene symmetrical Schiff base compounds as corrosion inhibitor for mild steel in acidic media

The inhibiting effect of two Schiff bases on the corrosion of the mild steel (MS) in 1 M HCl has been studied by electrochemical impedance spectroscopy (EIS) and Tafel polarisation measurements. The Schiff bases, 4,4′-bis(3-carboxaldehyde thiophene) diphenyl diimino ether (L₁) and 4,4′-bis(3-carboxaldehyde thiophene) diphenyl diimino ethane (L₂), were synthesized using 3-carboxaldehydethiophene and its corresponding amine. Polarisation curves reveal that both compounds are mixed type (cathodic/anodic) inhibitors and inhibition efficiency (% IE) increases with increasing concentration of compounds. It is suggested that their effects depend on their concentrations and the molecular structures. Adsorption of compounds on mild steel surface is spontaneous and obeys Langmuir’s isotherm.     

Accounting for input-model and input-parameter uncertainties in simulation

To account for the input-model and input-parameter uncertainties inherent in many simulations as well as the usual stochastic uncertainty, we present a Bayesian input-modeling technique that yields improved point and confidence-interval estimators for a selected posterior mean response. Exploiting prior information to specify the prior probabilities of the postulated input models and the associated prior input-parameter distributions, we use sample data to compute the posterior input-model and input-parameter distributions. Our Bayesian simulation replication algorithm involves: (i) estimating parameter uncertainty by randomly sampling the posterior input-parameter distributions; (ii) estimating stochastic uncertainty by running independent replications of the simulation using each set of input-model parameters sampled in (i); and (iii) estimating input-model uncertainty by weighting the responses generated in (ii) using the corresponding posterior input-model probabilities. Sampling effort is allocated among input models to minimize final point-estimator variance subject to a computing-budget constraint. A queueing simulation demonstrates the advantages of this approach.     

Excess Conductivity Investigation of Y<Subscript>3</Subscript>Ba<Subscript>5</Subscript>Cu<Subscript>8</Subscript>O<Subscript>18±<Emphasis Type="Italic">δ</Emphasis></Subscript> Superconductors Prepared by Various Parameters of Planetary Ball Milling Technique

Superconducting samples of type Y₃Ba₅Cu₈O_18±δ were elaborated by using a planetary high-energy ball milling (HEBM) technique with various parameters. Phases, microstructure, and superconductivity have been examined using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and electrical resistivity measurements. SEM investigation shows the occurrence of nanoentities embedded into the superconducting matrix for samples prepared by a ball milling technique. The main objective of this study is to investigate the influence of ball milling parameters on the fluctuation-induced conductivity (FIC). The electrical resistivity versus temperature, ρ(T), above T _c was analyzed using Lawrence–Doniach (LD) and Aslamazov–Larkin (AL) models. Different fluctuation regimes indicated by short-wave fluctuation (SWF) and three-dimensional (3D), two-dimensional (2D), one-dimensional (1D), and critical region (CR) fluctuations were identified. The coherence length at zero temperature, the effective layer thickness, the critical magnetic fields, and the critical current densities are determined. The superconducting parameters strongly depend on the planetary ball milling technique, and the results are explained in relevancy to the microstructure. It was found that the achievement of a microstructure with well-dispersed nanoentities is an effective way for introducing pinning centers for enhancing critical current density and flux pinning capability of bulk Y-358.