Rheological Property and Stress Development during Drying of Tape-Cast Ceramic Layers

Rheological property and stress development of tape-cast ceramic layers derived from nonaqueous alumina (A1₂O₃)-poly(vinyl butyral) (PVB) suspensions were observed during drying. Casting suspensions exhibited strong shear-thinning behavior, with a low shear Newtonian plateau apparent viscosity >10² Pa^.s. The apparent suspension viscosity displayed a power-law dependence on the A1₂O₃ volume fraction during the initial stage of drying (<30% solvent loss). Stress development, measured by a cantilever deflection method, and parallel weight loss measurements were performed during the drying of tape-cast layers and pure binder coatings. Maximum drying stresses (σ_max) of 1.37-0.77 MPa were observed for plasticized tapes cast at gap heights of 150-400 μm. In contrast, nonplasticized tapes of similar thickness displayed a more gradual stress increase, with σ_max values approximately an order of magnitude higher than their plasticized counterparts. The stress histories of the corresponding binder coatings were quite similar to the tape-cast layers, albeit slightly lower σ _max values were observed. Stresses decayed beyond σ_max with a logarithmic time dependence to an almost constant value of 0.2-0.4 MPa for the plasticized tapes. Based on these observations, process methodologies have been offered to minimize stress development and retention in tape-cast ceramic layers     

Persistent, bioaccumulative and toxic substances in fish: human health considerations

Fish are important dietary items that provide essential nutrients. Fish however, bioaccumulate monomethyl mercury (MMHg) and organo-halogenated pollutants (OHP) that are persistent bioaccumulative and toxic substances (PBTS). Unlike man-made OHP, MMHg is mainly of natural origin but background concentrations of aquatic systems are determined by the environmental Hg-methylating potential. Industrial activities can modulate environmental discharges and fish bioaccumulation of PBTS. Fish and seafood consumption are associated with human body load of PBTS, but farming practices that utilize fishmeal increase the terrestrial food chain resulting in farm-animal accumulation of PBTS. These substances are neurotoxic and endocrine active that can impact humans and wild life, but chemical characteristics of MMHg and OHP modulate interactions with animal tissues. MMHg is protein reactive with a faster metabolism (months) than OHP that are stored and slowly (years) metabolized in fat tissues. Except for brain-Hg, neither Hg nor OHP in tissues are markers of toxic effects; however, deficits in neurobehavioral test-scores of children have been shown in some fish-eating populations. These deficits are transient and within normal range, and are not prodromes of neurological diseases. Although population studies show that consumption of fish at current levels of contamination do not explain neurological disorders, endocrine activity remains controversial. Understanding risk of hazard caused by fish-PBTS consumption requires a wide range of expertise. We discuss chemical, toxic, metabolic, and ecological characteristics associated with PBTS in fish. There are proven health outcome derived from fish consumption, while risk of exposure to avoidable PBTS is a chance that can be minimized by societal actions.     

Influence of core stiffness on the behavior of tall timber buildings subjected to wind loads

This study analyzes the feasibility of the use of cross-laminated timber (CLT) as a load-bearing structural element in a 40-story building based on Chinese design requirements. The proposed design of the high-rise concrete–CLT building utilizes the core–outrigger system. Concrete is used for the central core and outriggers, and CLT is used for the rest of the structure of the building. Finite element models with different types of connections were developed using SAP2000 to analyze the lateral behavior of the building under wind action. The finite element models with rigid connections deduce the wind load distributions on individual structural elements, which determine the total number and the stiffness of fasteners of the CLT panels. Accordingly, spring links with equivalent stiffness that simulate the mechanical fasteners were employed in SAP2000. The results indicate that CLT increases the lateral flexibility of the building. A closed concrete core was substituted by two half cores to measure the requirement of the maximum lateral deflection. However, the acceleration at the building top still exceeded the limitation prescribed in Chinese Code JGJ 3–2010 owing to the lightweight of CLT and decreased stiffness of the hybrid building. To restrict this top acceleration within the limit, further approaches to increase the stiffness in the weak direction of the building are required. Methods such as the modification of the floor layout, increase in the thickness of walls, and addition of extra damping capacity should be considered and verified in the future.     

“生活里充满了惊奇!”时尚鞋子品牌Mary Ching设计师的家

第一次见到Mary Ching品牌的时尚高跟鞋,是在博雅珊画廊主人的家庭派对上。优雅的女主人一袭黑色天鹅绒的礼服,配上那双水蛇皮高跟鞋,高贵和性感便不露声色地显现,魅力更是华光四射。就在那个派对上,我认识了Mary Ching的女设计师和创始者,华裔英籍的     

Alternative approaches to trip distribution modelling: A retrospective review and suggestions for combining different approaches

Abstract.  Various alternative approaches are available in the literature for modelling trip distribution. The objective of this paper is to provide a review of this literature with the view of summarising the general nature of the current state of practise and what is now available for practical modelling work. Both aggregate and disaggregate destination choice models are considered, a classification of them will be proposed and suggestions for further research will be given as well. One outcome of this review is that significant contributions are emerging from mixed models (e.g., gravity-opportunity, random utility, intervening opportunities models, etc). In particular, the review will highlight the benefit of integrating different approaches like the introduction of intervening opportunities factors within random utility models.     

库尼奥办公楼设计

这个恍若由一层层硬币堆叠的办公楼因为增加了一扇通透光洁的玻璃外壳,就使得它占据了达·米兰诺集团新中心的最显眼位置。这种曼妙的空间结构设计打破了工业建筑的传统设计模式,也和以往那些办公室的传统设计思路不同,归结来就是在一个灰色的大环境里创造出一片充满生机盎然的绿色区域,让人们在这里能够有轻     

都市里的世外桃源

"上海是一个繁华的国际大都市,我想在我位于市中心的家中开辟一片净地,让自己忘却身处世俗的喧哗。"这是Ching对新家的期待,经过多个月与设计师和施工队伍的辛苦工作和协调已经远远超越了这个期待。     

Fish meal in animal feed and human exposure to persistent bioaccumulative and toxic substances

Persistent and bioaccumulative toxic substances (PBTSs) that end up in fish are health hazards and the object of fish-consumption advisories. Some of these substances are present as extraneous contaminants, e.g., man-made lipophilic pollutants such as organohalogen pollutants, and others such as monomethyl mercury can be considered naturally occurring. Omnivores (e.g., poultry and swine) and especially ruminants that are fed contaminated fish meal can pass monomethyl mercury and organohalogen pollutants to eggs, meat, and dairy products. Differences in fish meal PBTS profiles and farm animal (e.g., poultry, swine, cattle, and farmed fish) physiology modulate PBTSs in animal products. Fish-consumption advisories issued to protect human health do not extend to fish by-products fed to farmed animals. Animals (especially farmed fish) that are fed fish meal can bioconcentrate monomethyl mercury in protein matrices, and organohalogen pollutants can be passed on in the fat components of derived foods. Policies to decrease exposure to monomethyl mercury and organohalogen pollutants must consider farming practices that use fish by-products. A risk assessment of toxic contaminants in fish meal may indicate that food safety objectives must consider the human health impact of foods derived from animals fed contaminated meal.