NMR-study of the stereochemistry and dynamic behaviour of thioacrylamides

Several model thioacrylamides, Me₂N CH = C(R) C(S) NMe₂ (R = H, Ph — 2a, b ) and (p)MeO C₆H₄ NH CHC(R) C(S) NMe₂ (R = H, Ph — 3a, b ) have been synthesized. The ¹H-n.m.r. spectra have been taken for discussing the E/Z-isomerism of the thioacrylamides and the assignment further strengthened by an added LIS-study. The 2-unsubstituted compounds have been found to exist exclusively in preferred configurations/conformations: 2a — E(s-cis); 3a — Z(s-cis); the 2-phenylsubstituted analogs are of divergent behaviour: in 2b the C(S) NMe₂ moiety is found to be twisted out of the common plane, and 3b prefers the flat s-trans conformations (E(s-trans) ⇌ Z(s-trans)). The compounds show restricted rotations about C¹, N- and C³, N-partial double bonds. The corresponding rotational barriers, determined as ΔG-values by dynamic n.m.r. spectroscopy, are discussed with respect to (i) the resonance branch at C¹, (ii) the influence of substituents, and (iii) the effect of steric hindrance in the thioacrylamide moiety generally.     

Full-Duplex DOCSIS/WirelessDOCSIS Fiber–Radio Network Employing Packaged AFPMs as Optical/Electrical Transducers

A hybrid fiber-radio access network architecture for simultaneous wireline and wireless transmissions of data-over-cable service interface specification (DOCSIS) signals is presented. An all-optical harmonic up-conversion technique using a dual-drive Mach-Zehnder modulator provides the downstream optical signal modulated not only at the intermediate frequency in the 600- to 900-MHz band for wireline transmission but also at the up-converted frequency in the 5.45- to 5.75-GHz band for wireless transmission. An InGaAsP/InGaAsP multiple-quantum-well asymmetric Fabry-Perot modulator/detector has been designed, fabricated, and packaged and has been employed in the base station (BS) as an optical/electrical transducer, simultaneously providing the functions of optical intensity modulation and photodetection. At the BS, the DOCSIS signals are recovered at the wireline and wireless frequencies for the respective feeding of a cable access network or a fixed wireless access network in a highly flexible approach. Full-duplex operation has been demonstrated for both access types in an indoor laboratory environment. In a subsequent small-scale field trial, real-life Internet traffic provided by a local community antenna television system operator has been transported over the present hybrid fiber-radio access network architecture, and simultaneous transmission of both DOCSIS and digital television signals has also been performed.     

Developing the vegetation drought response index for South Korea (VegDRI-SKorea) to assess the vegetation condition during drought events

South Korea has experienced severe droughts and water scarcity problems that have influenced agriculture, food prices, and crop production in recent years. Traditionally, climate-based drought indices using point-based meteorological observations have been used to help quantify drought impacts on the vegetation in South Korea. However, these approaches have a limited spatial precision when mapping detailed vegetation stress caused by drought. For these reasons, the development of a drought index that provides detailed spatial-resolution information on drought-affected vegetation conditions is essential to improve the country’s drought monitoring capabilities, which are needed to help develop more effective adaptation and mitigation strategies. The objective of this study was to develop a satellite-based hybrid drought index called the vegetation drought response index for South Korea (VegDRI-SKorea) that could improve the spatial resolution of agricultural drought monitoring on a national scale. The VegDRI-SKorea was developed for South Korea, modifying the original VegDRI methodology (developed for the USA) by tailoring it to the available local data resources. The VegDRI-SKorea utilizes a classification and regression tree (CART) modelling approach that collectively analyses remote-sensing data (e.g. normalized difference vegetation index (NDVI)), climate-based drought indices (e.g. self-calibrated Palmer drought severity index (PDSI) and standardized precipitation index (SPI)), and biophysical variables (e.g. elevation and land cover) that influence the drought-related vegetation stress. This study evaluates the performance of the recently developed VegDRI-SKorea for severe and extreme drought events that occurred in South Korea in 2001, 2008, and 2012. The results demonstrated that the hybrid drought index improved the more spatially detailed drought patterns compared to the station-based drought indices and resulted in a better understanding of drought impacts on the vegetation conditions. The VegDRI-SKorea model is expected to contribute to the monitoring of drought conditions nationally. In addition, it will provide the necessary information on the spatial variations of those conditions to evaluate local and regional drought risk assessment across South Korea and assist local decision-makers in drought risk management.     

Enhancing the Selectivity and Transparency of the Electron Contact in Silicon Heterojunction Solar Cells by Phosphorus Catalytic Doping

An intrinsic hydrogenated amorphous silicon (a-Si:H(i)) film and a doped silicon film are usually combined in the heterojunction contacts of silicon heterojunction (SHJ) solar cells. In this work, a post-doping process called catalytic doping (Cat-doping) on a-Si:H(i) is performed on the electron selective side of SHJ solar cells, which enables a device architecture that eliminates the additional deposition of the doped silicon layer. Thus, a single phosphorus Cat-doping layer combines the functions of two other layers by enabling excellent interface passivation and high carrier selectivity. The overall thinner layer on the window side results in higher spectral response at short wavelengths, leading to an improved short-circuit current density of 40.31 mA cm⁻² and an efficiency of 23.65% (certified). The cell efficiency is currently limited by sputter damage from the subsequent transparent conductive oxide fabrication and low carrier activation in the a-Si:H(i) with Cat-doping. Numerical device simulations show that the a-Si:H(i) with Cat-doping can provide sufficient field effect passivation even at lower active carrier concentrations compared to the as-deposited doped layer, due to the lower defect density.     

Fingerprint‐Inspired Conducting Hierarchical Wrinkles for Energy‐Harvesting E‐Skin

In the field of bionics, sophisticated and multifunctional electronic skins with a mechanosensing function that are inspired by nature are developed. Here, an energy‐harvesting electronic skin (energy‐E‐skin), i.e., a pressure sensor with energy‐harvesting functions is demonstrated, based on fingerprint‐inspired conducting hierarchical wrinkles. The conducting hierarchical wrinkles, fabricated via 2D stretching and subsequent Ar plasma treatment, are composed of polydimethylsiloxane (PDMS) wrinkles as the primary microstructure and embedded Ag nanowires (AgNWs) as the secondary nanostructure. The structure and resistance of the conducting hierarchical wrinkles are deterministically controlled by varying the stretching direction, Ar plasma power, and treatment time. This hierarchical‐wrinkle‐based conductor successfully harvests mechanical energy via contact electrification and electrostatic induction and also realizes self‐powered pressure sensing. The energy‐E‐skin delivers an average output power of 3.5 mW with an open‐circuit voltage of 300 V and a short‐circuit current of 35 µA; this power is sufficient to drive commercial light‐emitting diodes and portable electronic devices. The hierarchical‐wrinkle‐based conductor is also utilized as a self‐powered tactile pressure sensor with a sensitivity of 1.187 mV Pa^‐1 in both contact‐separation mode and the single‐electrode mode. The proposed energy‐E‐skin has great potential for use as a next‐generation multifunctional artificial skin, self‐powered human–machine interface, wearable thin‐film power source, and so on.     

Expatriate cultural values alignment: The mediating effect of cross‐cultural adjustment level on innovative behaviour

Multinational companies assign expatriates to bridge the scarcity of employees with innovative behaviour from the local labour market. Despite expatriates' significant role in inducing innovative ideas for multinational companies, the existing literature has scarcely examined those antecedent factors that affect their innovative behaviour. Even though previous studies indicated the determinant impact of host countries' culture on the expatriates' work‐related behaviour, little is known about how far it affects their innovative behaviour. Therefore, drawing on the person‐environment fit theory, this study examines the impact of personal value orientation and the host country's culture alignment on expatriates' innovative behaviour. The study covers 149 expatriates, from nine countries, who work in the high‐tech industrial zone of Shenzhen, South China's industrial hub. Moreover, it applies a structural equation model using Amos^TM 23 to conduct the analysis. The results reveal that personal value orientation fit with the host country's national culture has a significant impact on expatriates' innovative behaviour. Cross‐cultural adjustment level is found to mediate this relationship. Theoretical and practical implications are discussed, and suggestions for future research are drawn from the study's limitations.     

Ground-based passive microwave remote sensing observations of soilmoisture at S-band and L-band with insight into measurementaccuracy

A ground-based experiment in passive microwave remote sensing of soil moisture was conducted in Huntsville, AL, from July 1-14, 1996. The goal of the experiment was to evaluate the overall performance of an empirically-based retrieval algorithm at S-band and L-band under a different set of conditions and to characterize the site-specific accuracy inherent within the technique. With high temporal frequency observations at S-band and L-band, the authors were able to observe large scale moisture changes following irrigation and rainfall events, as well as diurnal behavior of surface moisture among three plots, one bare, one covered with short grass and another covered with alfalfa. The L-band emitting depth was determined to be on the order of 0-3 or 0-5 cm below 0.30 cm³/cm³ with an indication that it is less at higher moisture values. The S-band emitting depth was not readily distinguishable from L-band. The uncertainty in remotely sensed soil moisture observations due to surface heterogeneity and temporal variability in variables and parameters was characterized by imposing random errors on the most sensitive variables and parameters and computing the confidence limits on the observations. Discrepancies between remotely sensed and gravimetric soil moisture estimates appear to be larger than those expected from errors in variable and parameter estimation. This would suggest that a vegetation correction procedure based on more dynamic modeling may be required to improve the accuracy of remotely sensed soil moisture