胡萝卜丁中维生素C在热风辅助射频干燥过程中降解的动力学模型

目的研究热风辅助射频(hot air-assisted radio frequency,HA-RF)干燥过程中维生素C随温度变化的降解动力学模型。方法在6.5 cm极板间距和60℃热风系统条件下进行HA-RF干燥,重点研究胡萝卜丁中维生素C在干燥过程中的降解动力学,包括脱氢抗坏血酸(dehydroascorbic acid,DHAA)和抗坏血酸(ascorbic acid,AA)。总维生素C含量采用2,4-硝基苯肼分光光度法测定,AA采用2,6-二氯吲哚酚滴定法测定。结果HA-RF干燥过程中维生素C的降解规律符合一级可逆模型,其降解活化能为40.54 kJ/mol。DHAA活化能为35.83 kJ/mol,表明DHAA的稳定性低于AA。结论本研究使用的干燥温度为62.5~77.5℃,较高的干燥温度下维生素C降解速率较高,较低处理温度下的降解过程具有更好的模型适应度(R2>0.98)。     

提高深井硬地层钻井速度技术难点及对策

乌龙1井地层为南方海相沉积,地层古老、岩石硬度大、研磨性强、可钻性差、地层倾角大(最大为80°)井斜难以控制、蹩跳钻严重,制约了该地区深井钻井速度。文章介绍了解决提高钻井速度这一瓶颈问题,从深井优快钻井及其配套技术、硬地层钻进的钻头优选、优化钻井参数、引用新技术、新工艺、新工具等方面进行了探索,钻井速度有了大幅度地提高,对类似井具有一定的借鉴作用。     

ZnGa2O4纳米晶的制备和结构表征

采用喷射共沉淀法制备了ZnGa2O4 纳米晶，XRD、SEM和TEM结构分析结果表明，喷射共沉淀法制备的ZnGa2O4的纳米晶颗粒细小均匀，形状完整，与化学共沉淀法相比，粒子尺寸明显减小，小于10nm，同时ZnO杂相峰消失，分析了喷射共沉淀法的机理，并对实验结果进行了解释。     

JOINING MECHANISMS OF β''''-Al2O3 CERAMIC AND PYREX GLASS TO Al MATRIX COMPOSITE

The bonding of β'-Al2O3 and pyrex glass to Al matrix composites by anodic bonding process is achieved. The microstructure of the bonded interface and the joining mechanisms are analyzed with scanning electron microscope (SEM), energy dispersive X-ray fluorescence spectrometer (EDX). It is observed that the bonding region across the interface consists of the metal layer, oxide transitional layer and the ceramic layer, with the transitional layer composed of surface region and sub-surface region. The bonding process can mainly be categorized into anodic bonding process and solid state diffusing process. The pile-up of the ions and its drift in the interface area are the main reasons for anode oxidation and joining of the interface. The temperature, voltage and the drift ions in the ceramic or glass during the bonding process are the essential conditions to solid state diffusing and oxide bonding at the interface. The voltages, temperature, pressure as well as the surface state are the main factors that influence the anodic bonding.     

确定最佳起爆点的磁探测仪研究

雷的作战效果取决于雷体起爆时距离目标的远近程度,为了改善现存部分库存雷没有确定最佳起爆点这一现状,在此设计了确定最佳起爆点的磁探测仪.本探测仪采用磁阻传感器探测目标,目标信号经过后续的放大电路,微分电路处理,确定最佳起爆点,并在最佳起爆点时输出触发信号,引爆雷体.本设计还为以后智能雷的发展提供了一些研究思路.     

Outage capacities and optimal power allocation for fading multiple-access channels

We derive the outage capacity region of an M-user fading multiple-access channel (MAC) under the assumption that both the transmitters and the receiver have perfect channel side information (CSI). The outage capacity region is implicitly obtained by deriving the outage probability region for a given rate vector. Given a required rate and average power constraint for each user, we find a successive decoding strategy and a power allocation policy that achieves points on the boundary of the outage probability region. We discuss the scenario where an outage must be declared simultaneously for all users (common outage) and when outages can be declared individually (individual outage) for each user.     

混凝土结构的质量通病——裂缝

从材料、结构构造、施工工艺、地基变形、温湿度变形等方面论述了混凝土裂缝产生的原因 ,提出只有真正了解裂缝产生的原因 ,才能有针对性地采取有效措施 ,确保工程质量     

Ring‐opening polymerization of D,L‐lactide by rare earth 2,6‐dimethylaryloxide

Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)₃) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)₃ exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 10⁴ g mol^?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)₃ has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)₃ is 69.6 kJ mol^?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry