全文获取类型
收费全文 | 1061篇 |
免费 | 22篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 10篇 |
化学工业 | 230篇 |
金属工艺 | 55篇 |
机械仪表 | 35篇 |
建筑科学 | 11篇 |
矿业工程 | 6篇 |
能源动力 | 44篇 |
轻工业 | 54篇 |
水利工程 | 7篇 |
石油天然气 | 4篇 |
无线电 | 90篇 |
一般工业技术 | 287篇 |
冶金工业 | 90篇 |
原子能技术 | 15篇 |
自动化技术 | 146篇 |
出版年
2023年 | 6篇 |
2022年 | 17篇 |
2021年 | 29篇 |
2020年 | 16篇 |
2019年 | 19篇 |
2018年 | 24篇 |
2017年 | 25篇 |
2016年 | 20篇 |
2015年 | 17篇 |
2014年 | 31篇 |
2013年 | 76篇 |
2012年 | 50篇 |
2011年 | 79篇 |
2010年 | 66篇 |
2009年 | 58篇 |
2008年 | 60篇 |
2007年 | 59篇 |
2006年 | 35篇 |
2005年 | 29篇 |
2004年 | 24篇 |
2003年 | 21篇 |
2002年 | 23篇 |
2001年 | 20篇 |
2000年 | 27篇 |
1999年 | 26篇 |
1998年 | 23篇 |
1997年 | 16篇 |
1996年 | 19篇 |
1995年 | 13篇 |
1994年 | 9篇 |
1993年 | 9篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 9篇 |
1988年 | 8篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1983年 | 9篇 |
1982年 | 12篇 |
1981年 | 7篇 |
1980年 | 10篇 |
1979年 | 13篇 |
1978年 | 4篇 |
1977年 | 5篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1971年 | 2篇 |
排序方式: 共有1084条查询结果,搜索用时 0 毫秒
1.
In the catalytic reaction of an iron(III) porphyrin with t-BuOOH, CumOOH, H2O2 and C6F5IO, cyclohexene was used as a probe substrate. The selective hydroxylation of cyclohexene by hydroperoxides proceeds through radical path and this has been utilized for successful dioxygen activation/autooxidation. For other oxidants epoxide was the major product and the reactions proceed through non-radical path. 相似文献
2.
3.
Sinha Swati Shaw Siddharth Biswas Kunal De Debashis Das Samir Chandra Sarkar Angsuman Bandyopadhyay Jaya 《Microsystem Technologies》2021,27(11):4087-4100
Microsystem Technologies - Single-Walled Carbon Nanotubes (SWCNTs) are widely used as potential carriers in drug delivery systems. The objective of this work was to observe the effects of pristine,... 相似文献
4.
Eugenia Awuah Boadi Samuel Shin Samuel Yeroushalmi Bok-Eum Choi Peijun Li Bidhan C. Bandyopadhyay 《International journal of molecular sciences》2021,22(6)
Proximal tubular (PT) acidosis, which alkalinizes the urinary filtrate, together with Ca2+ supersaturation in PT can induce luminal calcium phosphate (CaP) crystal formation. While such CaP crystals are known to act as a nidus for CaP/calcium oxalate (CaOx) mixed stone formation, the regulation of PT luminal Ca2+ concentration ([Ca2+]) under elevated pH and/or high [Ca2+] conditions are unknown. Since we found that transient receptor potential canonical 3 (TRPC3) knockout (KO; -/-) mice could produce mild hypercalciuria with CaP urine crystals, we alkalinized the tubular pH in TRPC3-/- mice by oral acetazolamide (0.08%) to develop mixed urinary crystals akin to clinical signs of calcium nephrolithiasis (CaNL). Our ratiometric (λ340/380) intracellular [Ca2+] measurements reveal that such alkalization not only upsurges Ca2+ influx into PT cells, but the mode of Ca2+ entry switches from receptor-operated to store-operated pathway. Electrophysiological experiments show enhanced bicarbonate related current activity in treated PT cells which may determine the stone-forming phenotypes (CaP or CaP/CaOx). Moreover, such alkalization promotes reactive oxygen species generation, and upregulation of calcification, inflammation, fibrosis, and apoptosis in PT cells, which were exacerbated in absence of TRPC3. Altogether, the pH-induced alteration of the Ca2+ signaling signature in PT cells from TRPC3 ablated mice exacerbated the pathophysiology of mixed urinary stone formation, which may aid in uncovering the downstream mechanism of CaNL. 相似文献
5.
Biswas Uttara Rakshit Jayanta Kumar Das Joyashree Bharti Gaurav Kumar Suthar Bhuvneshwer Amphawan Angela Najjar Monia 《SILICON》2021,13(3):885-892
Silicon - In the present report, a photonic crystal based micro-ring resonator (MRR) structure is proposed which is very compact in size and has very fast response and is employed for temperature... 相似文献
6.
The rates of absorption of CO2 into water and 0.1 kmol/m3 aqueous solutions of MEA, DEA and AMP were measured in a stirred cell with a flat gas-liquid interface in the presence of fine activated carbon particles. Experiments showed that the rates of absorption increased significantly with increases in the loading of activated carbon up to about 6 kg/m3 and thereafter remained constant. 相似文献
7.
Rajib Bandyopadhyay Mahuya Bandyopadhyay Yoshihiro Kubota Yoshihiro Sugi 《Journal of Porous Materials》2002,9(2):83-95
AlPO4-5 and AlPO4-11 were synthesized by dry-gel conversion (DGC) method. Steam-assisted conversion (SAC) and vapor-phase transport (VPT) techniques were applied for this purpose. The synthesis was successful in presence of a certain minimum amount of external bulk water, without which the crystallization failed. Crystallization by VPT method was slower than corresponding SAC and HTS method. SAPO analogs of the samples, SAPO-5 and SAPO-11 were also synthesized by DGC method. Samples made by DGC methods had higher yield than the conventional hydrothermal synthesis (HTS); otherwise the samples showed similar characteristics as that made by HTS. XRD, SEM and N2-adsorption results showed high crystallinity and purity of the samples made by DGC, and 27Al MAS NMR spectra indicated the tetrahedral framework nature of Al. SAPO-5 and SAPO-11 were tested for their catalytic activity in isopropylation of biphenyl, and in terms of conversion and selectivity, SAPO-5 was found to be suitable for this application. 相似文献
8.
Arijit Sur Vignesh Ramanathan Jayanta Mukherjee 《Multimedia Tools and Applications》2014,68(3):805-825
In this paper, a block based steganographic algorithm has been proposed where a sequence of secret bits are embedded into a set of pixels by rearranging the pixel locations. This algorithm has been devised as an improvement over existing statistical restoration based algorithms in order to reduce the additive noise which occurs due to embedding. It is shown that the proposed scheme substantially reduces the additive noise compared to existing statistical restoration based schemes. 相似文献
9.
Bandyopadhyay Soma Thakur S. S. Mandal J. K. 《Innovations in Systems and Software Engineering》2021,17(1):45-52
Innovations in Systems and Software Engineering - Recommender system is a computer-based intelligent technique which facilitates the customers to fulfill their purchase requirements. In addition to... 相似文献
10.
The flame spraying process, which is a common industrial thermal spraying application, has been analyzed by means of three-dimensional
computational fluid dynamics (CFD) simulations. The process used at the Volvo Aero Corporation for the coating of fan and
compressor housings has been modeled. The process uses the Metco 6P torch (Metco, Westbury, NY), which ejects a mixture of
acetylene and oxygen at high speed through a ring of 16 orifices to form the flame. A stream of argon gas flowing through
an orifice in the center of the ring carries a powder of nickel-covered bentonite through the flame to the spray substrate.
The torch is cooled by a flow of air through an outer ring of 9 orifices. The simulation emulated reality closely by including
the individual inlets for fuel, cooling air, and injected particles. The gas combustion was simulated as a turbulent, multicomponent
chemically reacting flow. The standard, two-equation k-ε turbulence model was used. The chemical reaction rates appeared as
source terms in the species transport equations. They were computed from the contributions of the Arrhenius rate expressions
and the Magnussen and Hjertager eddy dissipation model. The first simulations included several intermediate chemical substances
whose predicted concentration agreed favorably with measurements. Later, more simplified simulations incorporated only the
global chemical reaction involving the initial and the final products, with corrections to the thermal properties being made
to account for the missing intermediaries. The gas velocity and temperature fields predicted by the later simulations compared
satisfactorily to those predicted by the earlier, more elaborate, ones. Therefore, the final simulations, which incorporated
injected particles, were conducted employing the simplified model with only the global reaction. An in-house finite difference
code was developed to calculate particle properties. Allowance was made for elliptical shapes, phase changes, and internal
heat transfer with regard to the composite material. The particle velocities and temperatures predicted by the final simulations
compared fairly well with experimental results obtained with the optical DPV2000 system. 相似文献