Effects of unequal reactivity of functional groups on gelation phenomena in polyurethane systems

A model to describe the effect of unequal reactivity on curing of a diisocyanate with water, polyol and a diol was developed. The model predicts whether a given initial composition would gel or not and the fractional conversions of functional groups at the gel point. It has been shown that the relative speeds of reaction of water and hydroxyl groups can be used to classify water's behaviour as that of a (i) nonreactive diluent (ii) monofunctional blocking agent and (iii) chain extender capable of connecting branch points.     

Regression-based weight generation algorithm in neural network for solution of initial and boundary value problems

This paper introduces a new algorithm for solving ordinary differential equations (ODEs) with initial or boundary conditions. In our proposed method, the trial solution of differential equation has been used in the regression-based neural network (RBNN) model for single input and single output system. The artificial neural network (ANN) trial solution of ODE is written as sum of two terms, first one satisfies initial/boundary conditions and contains no adjustable parameters. The second part involves a RBNN model containing adjustable parameters. Network has been trained using the initial weights generated by the coefficients of regression fitting. We have used feed-forward neural network and error back propagation algorithm for minimizing error function. Proposed model has been tested for first, second and fourth-order ODEs. We also compare the results of proposed algorithm with the traditional ANN algorithm. The idea may very well be extended to other complicated differential equations.     

A study of global vs. local properties for maleic anhydride modified polypropylene nanocomposites

Nanoindentation of organomodified clay filled maleated polypropylene (MAPP) was investigated. The study aims to identify the relative increase in local stiffness in comparison to the increase in mechanical properties of the bulk in polypropylene-based nanocomposites. Such a study allows one to assess confined material property in addition to increased filler volume at the local scale. A mixture of highly intercalated and well exfoliated clay structures, when dispersed in MAPP matrix, was observed under transmission electron microscopy. The degree of exfoliation was found to increase with clay loading, which was attributed to the higher viscosity and mechanical shear forces during melt compounding. Instrumented indentation was performed on (1) clay aggregate supported by MAPP matrix, (2) clay-matrix boundary, and (3) the MAPP matrix. The clay aggregated region generally showed higher stiffness as compared to the matrix. And, the relative increase in indentation stiffness is substantially higher than the relative increase in tensile and compressive stiffnesses for clay reinforced systems. Polymer chain confinement and topological constraint appeared to be operative to enhance local stiffness in the clay aggregated region. Good correlation was, however, obtained between the change in macroscopic stiffness and the change in highly local indentation stiffness as a result of clay reinforcement.     

Solving singular control problems using uniform trigonometrization method

This study investigates the application of a recently developed construct, the uniform trigonometrization method (UTM), to the singular control problems in chemical engineering. The UTM involves minimal modifications to the original problem, thereby generating near-singular control solutions that can be used for conceptual design and serve as an alternate to direct techniques like nested and simultaneous approaches. Eight classical singular control problems with known analytical solutions and three complex singular control problems from chemical engineering domain are solved in this study. The results obtained using the UTM for these problems are found to match well with the literature and are of higher resolution as compared to the results obtained using a direct pseudospectral-based solver. The ability of the UTM to handle complex chemical engineering problems with both singular controls and state path constraints has also been demonstrated in this study.     

Developing Faculty ICT Competencies Inside and Outside the Library

Despite all the financial resources that are directed to support and acquire learning technologies, the results have been generally disappointing. Faculty are eager to use technology but lack the technical skills, ability, and experience. Library staff includes a talent tool rich in Information and Communication Technologies (ICT)/WEB 2.0 technical expertise and experience. In terms of content sourcing and procurement, library technical services and selection staff have broad knowledge of the marketplace for online information and content as well as experience in licensing access. They have a firm grasp of the transaction process, workflows, pricing, and licensing negotiations. Content development and sourcing inevitably involves access management, online storage, copyright, and licensing—things at which libraries are good. ICT deployment is changing teaching and learning on campuses, and the roles of those involved in teaching and learning are also changing. Whether formally through mandated library services, or informally through back channels, library staff are supporting faculty new technology use as well as faculty teaching materials content sourcing and procurement.     

Harmonic modification and data adaptive filtering based approach to robust pitch estimation

A novel and robust pitch estimation method is presented in this paper. The basic idea is to reshape the speech signal using a combination of the dominant harmonic modification (DHM) and data adaptive time domain filtering techniques. The noisy speech signal is filtered within the ranges of fundamental frequencies to obtain the pre-filtered signal (PFS). The dominant harmonic (DH) of the PFS is determined and enhanced its amplitude. Normalized autocorrelation function (NACF) is applied to that modified signal. Then empirical mode decomposition (EMD) based data adaptive time domain filtering is applied to the NACF signal. Partial reconstruction is performed in EMD domain. The pitch period is determined from the partially reconstructed signal. The experimental results show that the proposed method performs better than the other recently developed methods for noisy and clean speech signals in terms of gross and fine pitch errors.     

Evolution of fretting fatigue damage and relaxation of residual stress in shot-peened Ti-6Al-4V

The evolution of fretting fatigue damage was investigated in shot-peened Ti-6Al-4V samples, by measuring the changes in the surface residual stress, using the X-ray diffraction technique. The surface residual stress was found to relax as the number of fretting fatigue cycles increased. The relaxation behavior of the residual stress with the increasing number of fretting fatigue cycles was observed to occur in three stages. In the first 20 pct of the fretting fatigue life, a drastic relaxation was observed. In the second part (between 20 and 70 pct), a gradually increasing behavior was observed. During the last 20 to 30 pct of the fretting fatigue life, a dramatic relaxation of the residual stress was found to occur. A complete relaxation of the residual stress occurred in the fracture region. A scanning electron microscope observation of the microstructure of the damaged region was used to examine the mechanisms leading to the relaxation of the residual stress. The development of delaminations at the early stages of the accumulation of the fretting fatigue damage was observed to be the main cause of the initial relaxation. The generation of microcracks from the voids left behind by the delaminations is responsible for the additional relaxation of the residual stress. The coalescence of the microcracks generated from different delaminated regions produced yet more relaxation of residual stress and, ultimately, the final fracture of the specimen.     

Fretting fatigue crack initiation behavior using process volume approach and finite element analysis

This study investigates crack initiation behavior by incorporating fretting fatigue process volume. Three critical plane based fretting fatigue crack initiation parameters are characterized by computing their averaged values over the process volume and then comparing with their counterparts obtained from the localized approach. Two approaches are used: first one involves the computation of parameter at several points over a rectangular region and then its average, and second approach computes the average state of stress/strain over a radial region from which the averaged parameter is calculated. Both approaches require pre-determination of a critical location at or around which the process volume needs to be placed. Effects of size and location of process volume on the averaged value of parameters are studied in detail. Two radii of cylindrical pad are analyzed to investigate the effect of severity of stress gradient on process volume approach. Effects of finite element mesh refinement are also investigated. Averaged value of parameter decreases with the increase of process volume size. This decrease is higher when the process volume is located in the region that is away from the contact zone. Further, a parameter based on normal stress on the critical plane shows more dependence on the size of process volume than that based on shear stress or on a combination of both shear and normal stresses. Orientation of crack initiation changes within a range that is well within the scatter band of experimental observations as the process volume size increases. Averaged value of parameter for a pad with higher stress gradient has a larger reduction with the increase of process volume size than that with a lower stress gradient. Process volume size has less effect on the averaged value of parameter with coarser finite element mesh. Finally, the localized approach provides a conservative value of fretting fatigue crack initiation parameter compared to its counterpart based on the process volume.     

Genetic Deletion of Mmp9 Does Not Reduce Airway Inflammation and Structural Lung Damage in Mice with Cystic Fibrosis-like Lung Disease

Elevated levels of matrix metalloprotease 9 (MMP-9) and neutrophil elastase (NE) are associated with bronchiectasis and lung function decline in patients with cystic fibrosis (CF). MMP-9 is a potent extracellular matrix-degrading enzyme which is activated by NE and has been implicated in structural lung damage in CF. However, the role of MMP-9 in the in vivo pathogenesis of CF lung disease is not well understood. Therefore, we used β-epithelial Na⁺ channel-overexpressing transgenic (βENaC-Tg) mice as a model of CF-like lung disease and determined the effect of genetic deletion of Mmp9 (Mmp9^-/-) on key aspects of the pulmonary phenotype. We found that MMP-9 levels were elevated in the lungs of βENaC-Tg mice compared with wild-type littermates. Deletion of Mmp9 had no effect on spontaneous mortality, inflammatory markers in bronchoalveolar lavage, goblet cell metaplasia, mucus hypersecretion and emphysema-like structural lung damage, while it partially reduced mucus obstruction in βENaC-Tg mice. Further, lack of Mmp9 had no effect on increased inspiratory capacity and increased lung compliance in βENaC-Tg mice, whereas both lung function parameters were improved with genetic deletion of NE. We conclude that MMP-9 does not play a major role in the in vivo pathogenesis of CF-like lung disease in mice.