Relationships of tensile strength with crosslink density for the high-carbon black-filled EPDM compounds with various softeners

Equilibrium swelling and rheological tests were adopted to systematically investigate the effects of softener type and dosage on the crosslink densities. The results turned out that the chemical crosslink density could be distinguished from the physical crosslink density by comparing the results of equilibrium swelling and rheological tests. The liquid butadiene (LB) as a softener leads to the greatest reduction in crosslink density, followed by polyethylene wax (PW) and paraffinic oil (PO). The tensile strength decreases with increasing PO content while shows peak values with increase of LB and PW contents. The dependencies of chemical crosslink density on the aging time under 150°C are quite different for the three softeners, which can be expected from the double crosslinking networks consisting of small softener and large main crosslinking networks. Further investigation has been performed to correlate the tensile strength with chemical crosslink density of ethylene propylene diene monomer elastomer vulcanizates. Three different linear relationships can be obtained for the softeners independent of the aging time. It can now be expected from this study that the role of some new softeners in rubber compounds is not only confined to plasticization but also forms crosslinking networks in the peroxide-cured rubbers.     

TiAl基合金粉末爆炸烧结特性常数的测算

本文测算了自蔓延高温合成TiAl基合金粉末的爆炸烧结特性常数值：γ＝1．44，lgβ＝25．25，并为试验证实，这为获取大尺寸TiAl基合金提供了理论依据。     

黑色颜料的制备及其性能的研究

利用Co-Cr-Mn-Fe四元系颜料开发出陶瓷用黑釉配方,并在生产中试用,有烧成温度低,颜料与基釉的适应性好,黑釉烧成的合格率高等特点。     

KINETICS OF OXIDATION LEACHING OF Ag IN AMMONIACAL SOLUTIONS

研究了Ag在NH_3-O_2和NH_3-H_2O_2水溶液体系中的浸取行为.结果表明,在常压下氧化剂浓度低时(如在NH_3-O_2体系中),浸取反应受在Ag表面上生成的氧化物膜所阻碍;而在浓度足够高的氧化剂时(如在NH_3-H_2O_2体系中),浸取过程可在不生成氧化物膜的条件下进行,此时Ag的溶解速度受传质步骤控制.文中讨论了在氨性溶液中Ag氧化浸取的反应机理.     

保形参数四次插值算法

利用四次的Bézier曲线段构造了GC2连续的参数四次插值样条曲线,该样条曲线是保形的和局部的,且计算十分简单,所有的Bézier点由型值点和曲率直接计算产生,避免了求解矢量方程.最后,给出了一个数值实例.     

催化剂加载对连续碳纤维表面生长碳纳米管的影响

通过化学气相沉积(CVD)在碳纤维表面还原得到均匀细小的催化剂颗粒并在碳纤维表面催化生长了均匀、规整的碳纳米管(CNTs)。系统研究了催化剂种类以及浓度对碳纳米管产量和微观组织结构的影响,探究了碳纤维的浸润性能和单丝强度的变化。结果表明,Ni的催化活性最高,Co的催化活性适中,产生的CNTs较为均匀、规整,当催化剂浓度为0.02mol/L时,碳纤维表面生长CNTs多尺度增强体的拉伸强度最大。碳纤维表面生长CNTs,促使碳纤维的表面粗糙度增加,与树脂之间的结合变强,从而提高了碳纤维与环氧树脂之间的浸润性。     

QM-Y系半导体气敏传感器的失效分析

通过对气体传感器的可靠性试验,得到了元件失效的主要类型,对失效元件从微观和宏观进行了分析,找到了一些引起元件失效的主要原因,对元件的实际应用和批量生产有着极其重要的价值。     

基于Yoshida材料模型的帽形件回弹仿真分析

以1. 2 mm厚HC340/590DP帽形件为研究对象,采用Dynaform冲压仿真和冲压试验相结合的方法,探究了压边力、成形间隙、翻边角度等工艺参数对回弹的影响。结果显示,采用考虑随动硬化的Yoshida材料模型计算的回弹结果与试验测量结果的变化趋势一致,成形、翻边模拟结果精度在75%以上。对于帽形件的回弹,改变成形工艺对回弹量的影响最大,调整成形间隙或翻边角度也有一定影响,但在一定范围内调整压边力对回弹量的影响不大。     

基于GO法的高速动车组受电弓系统可靠性评估

在列车牵引供电系统中,接触网的电能通过受电弓流入牵引传动系统,受电弓其可靠性对整个列车的安全运行有很大影响.使用GO法对受电弓系统进行可靠性评估,介绍了受电弓的结构和工作原理,进而分析了受电弓的故障类型,给出了受电弓系统部件的历史维修数据,利用GO法对受电弓气路系统进行定量分析和定性分析.通过定量分析,得到受电弓系统的可靠性参数值,通过定性分析,指出了受电弓系统的薄弱环节为碳滑板.