电场局域增强介质阻挡放电对CO2氧化生物质焦油制合成气的影响

以苯为生物质气化焦油的模型分子,在全新设计的电场局域增强的介质阻挡放电(DBD)低温等离子体反应器中开展苯与CO₂反应制合成气的实验研究,考察了放电电压和CO₂初始浓度对苯与CO₂转化率的影响。结果表明,以氩气为载气的280μL/L苯和3000μL/L CO₂混合气在流速250 mL/min、放电功率60.3 W条件下,苯和CO₂的转化率最高可达40.2%和67.3%,产物H₂与CO的摩尔比达到0.132;苯能显著促进CO₂转化,而CO₂初始浓度对苯转化率影响小,且CO₂能显著降低苯降解的中间产物丙酮。结合发射光谱分析,推测了苯与CO₂制合成气的反应过程,表明苯的亲核属性可能是CO₂转化效果提高的主要因素。本研究为温和条件下CO₂氧化生物质气化焦油制合成气奠定了基础。     

Effect of power parameters on micro-discharge induced by corona discharge

This research mainly describes the generation and diagnosis of plasma using a wire-plate discharge device driven by different power supplies, aimed at investigating the effect of driving source parameters on micro-discharge induced by a corona. The influence of parameters such as waveform, duty ratio and bias voltage on discharge characteristics was explored preliminarily. Experiment results show that the determination of volt-ampere characteristics under different driving source waveforms indicates that the application of square and pulse waveforms shows great advantages over that of sawtooth and sinusoidal waveforms. Similarly, the photo-thermal effects of the system were investigated by comparing the high-voltage electrode temperature and relative emission intensity of N₂ (C³П_u →B³П_g , 0–0, 337 nm), where square and pulse waveforms also achieved better performance. But the pulse waveform had a slight advantage over the square waveform in terms of energy conversion. Further, investigations of the duty ratio and bias voltage applied on the pulse waveform were conducted, and the results indicate that the duty ratio could effectively improve the discharge power and thermal effect to a certain extent; however, the application of bias voltage on the pulse signal had little influence on the discharge power and thermal effect.