A case of split notochord syndrome: presence of dorsal enteric diverticulum adjacent to the dorsal enteric fistula

Like umblical enteric remnants (eg, umblical sinus and omphalomesenteric fistula), enteric remnants can be seen on the dorsal aspect of the body (dorsal enteric sinus, dorsal enteric fistula IDEF], dorsal enteric diverticulum) in conjunction with complete cleft of the vertebral column. Complete cleft of the vertebral column associated with gastrointestinal tract and central nervous system anomalies is known as "split notochord syndrome" (SNS). The authors present an unreported variant of SNS having dorsal enteric diverticulum adjacent to the DEF. The patient died 17 days after surgical repair.     

From embedded sensors to sensorial materials—The road to function scale integration

Ubiquitous computing is about to become part of our everyday lives by integrating hundreds of “invisible” to us computing devices in our environment, so that they can unobtrusively and constantly assist us. This will imply more and smaller “invisible” sensors, homogeneously distributed and at the same time densely packed in host materials, responding to various stimuli and immediately delivering information. In order to reach this aim, the embedded sensors should be integrated within the host material, heading towards sensorial materials. The first step is to omit all parts that are not needed for the sensorial task and to find new solutions for a gentle integration. This is what we call function scale integration. The paper discusses sensor embedding in the human hand as an example of integration in nature, new technological applications and main challenges associated with this approach.     

Synthesis and properties of chitosan-modified poly(vinyl butyrate)

Modification of chitosan by grafting of vinyl butyrate was carried out in homogeneous phase using potassium persulfate as redox initator and 1.5% acetic acid as solvent. The percent grafting and grafting efficiency were analysed and the high grafting efficiency up to 94% was observed. The effects of reaction variables such as monomer concentration, initiator concentration, temperature and reaction time were investigated. It was observed that the solubility of chitosan was markedly reduced after grafting with vinyl butyrate. The grafted product is insoluble in common organic solvents as well in dilute organic and inorganic acids. Characterization of the graft copolymers were carried out by using Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC) and Scanning Electron Microscopy (SEM) technics. Characteristic signal of carbonyl group was observed at 1,731 cm⁻¹ which belongs to the poly vinyl butyrate segments in the graft copolymer. The melting transition of the chitosan main chain in the copolymer shifted to 124°C from its original value 101°C. In addition to these, we have also studied topology of the graft copolymer and the SEM micrograph showed continuous homogenous matrix which means there is no phase separation.     

Synthesis of novel acrylic modified water reducible alkyd resin: Investigation of acrylic copolymer ratio effect on film properties and thermal behaviors

New four‐component water reducible acrylic modified alkyd resins that are based on 1,3‐propanediol and contain different ratios of acrylic copolymer (AC) were synthesized by using a novel four‐stage fatty acid method. The final content of solids in the water reducible acrylic modified alkyd resins was 60% by weight. After the modified alkyd resin films were cured at 150°C for 1 h, it was observed that the use of AC as the modifier component had improved their physical and chemical surface coating properties and thermal behaviors. Experimental results show that the optimum AC ratio is 40% of the equivalent amount of AC to alkyd resin. Low‐volatile organic compounds (VOC) content water reducible acrylic modified alkyd resins yielded soft and flexible films with high chemical/thermal resistance, suitable for manufacturing of surface coating binders. POLYM. ENG. SCI., 56:947–954, 2016. © 2016 Society of Plastics Engineers     

Revised stratigraphy of the Tertiary deposits of Istanbul and their engineering properties

For over 50 years, the Upper Oligocene–Upper Miocene sedimentary sequence in Istanbul has been considered to be formed of two distinct sequences separated by an unconformity. However, recent field observations and an analysis of numerous borehole data indicate the Gürp?nar, Çukurçe?me and Güngören Formations are in fact a single sequence of alternating clay–sand/sandstone beds/lenses, here named the Avc?lar Formation. The Bak?rköy Formation, which is typically composed of carbonate rocks, conformably overlies the Avc?lar Formation. The paper provides the geotechnical parameters of the units within the Avc?lar Formation which it is hoped will facilitate selecting suitable geotechnical and engineering geological parameters to represent the deposits and minimize errors in the interpretation/evaluation of in-situ conditions.     

Dislocation etch pits and growth of arsenic-antimony single crystals

Single crystals of an arsenic-antimony solid solution have been grown at the minimum melting point (612‡C) composition (25.5 at.% arsenic) where the solidus and liquidus touch. Pyramidal etch pits produced on (111) cleavage faces mark the sites of emergence of dislocations; dislocation densities are low, ranging between 10³ and 10⁵ per cm². The relationship between an unambiguous, right handed axial set and etch pit orientation on the (111) surface is established. The permissible Burgers vectors and dislocation reactions are detailed and are related to the observed etch pit types. In general, the results obtained also apply to the A7 structure elements themselves and amend previous findings of the crystallographic relationships between dislocation directions and etch pits.     

The elastic constants of antimony-25.5 at. % arsenic alloy single crystals

The six independent elastic constants of single crystals of the homogeneous, minimum melting point alloy of composition antimony 74.5 at. % and arsenic 25.5 at. % have been measured. The elastic behaviour of the alloy is compared with that of the rhombohedral A7 structure elements arsenic and antimony and is found to show characteristics consistent with those expected for layer-type crystals. Elastic wave velocity surface cross-sections, particle displacement and energy flux vectors and Young's modulus are presented and discussed. The Debye temperature is 219 K.     

Forecasting highway casualties under the effect of railway development policy in Turkey using artificial neural networks

This study presents forecast of highway casualties in Turkey using nonlinear multiple regression (NLMR) and artificial neural network (ANN) approaches. Also, the effect of railway development on highway safety using ANN models was evaluated. Two separate NLMR and ANN models for forecasting the number of accidents (A) and injuries (I) were developed using 27 years of historical data (1980–2006). The first 23 years data were used for training, while the remaining data were utilized for testing. The model parameters include gross national product per capita (GNP-C), numbers of vehicles per thousand people (V-TP), and percentage of highways, railways, and airways usages (TSUP-H, TSUP-R, and TSUP-A, respectively). In the ANN models development, the sigmoid and linear activation functions were employed with feed-forward back propagation algorithm. The performances of the developed NLMR and ANN models were evaluated by means of error measurements including mean absolute percentage error (MAPE), mean absolute error (MAE), root mean square error (RMSE), and coefficient of determination (R ²). ANN models were used for future estimates because NLMR models produced unreasonably decreasing projections. The number of road accidents and as well as injuries was forecasted until 2020 via different possible scenarios based on (1) taking TSUPs at their current trends with no change in the national transport policy at present, and (2) shifting passenger traffic from highway to railway at given percentages but leaving airway traffic with its current trend. The model results indicate that shifting passenger traffic from the highway system to railway system resulted in a significant decrease on highway casualties in Turkey.