Effect of MoS2/PTFE coatings on performance of Si3N4/TiC ceramics in dry sliding against WC/Co

To enhance the tribological performance of Si₃N₄/TiC ceramics, MoS₂/PTFE composite coatings were deposited on the ceramic substrate through spraying method. The micrographs and basic properties of the MoS₂/PTFE coated samples were investigated. Dry sliding friction experiments against WC/Co ball were performed with the coated ceramics and traditional ones. These results showed that the composite coatings could significantly reduce the friction coefficient of ceramics, and protect the substrate from adhesion wear. The primary tribological mechanisms of the coated ceramics were abrasive wear, coating spalling and delamination, and the tribological property was transited from slight wear to serious wear with the increase of load because of the lower surface hardness and shear strength. The possible mechanisms for the effects of MoS₂/PTFE composite coatings on the friction performance of ceramics were discussed.     

Polyethylene oxide-polypropylene oxide -polyethylene oxide derived porous carbon materials with different molecular weights as ORR catalyst in alkaline electrolytes

Polyethylene oxide (PEO)-polypropylene oxide (PPO)-polyethylene oxide block copolymer having different molecular weights are used as precursors of carbon materials to prepare Hollow -Derivatives carbon material as an electrocatalyst through block copolymer self-assembly. The composition and microstructure of the prepared catalysts are shown by Raman spectroscopy, X-ray diffraction (XRD), Test of nitrogen adsorption and desorption curves, High resolution transmission electron microscopy (HR-TEM) and scanning electron microscopy (HR-SEM). Oxygen was passed into alkaline electrolyte solution until the solution reached saturation state. With molecular weight increasing, the obtained sample gradually changed from block to hollow and spherical. When the molecular weight was 12600 g mol^?1, the evenly hollow carbon nanocages was acquired (C-12600). In O₂ saturated alkaline electrolyte (0.1 M KOH solution), C-12600's limited current density，half-wave potential and initial potential are 5.23 mA cm^?2@0.4 V, 0.72 V and 0.81 V, respectively. And most important is that half-wave potential and onset potential have barely change after 2000 cycles of cyclic voltammetry. As a result, the porous carbon materials exhibited excellent electrocatalytic activity while maintaining high stability in alkaline KOH solution.     

A new perspective of co-doping and Nd segregation effect on proton stability and transportation in Y and Nd co-doped BaCeO3

Bulk and surface properties of proton stability and transportation in Y and Nd co-doped BaCeO₃ (BCYN), especially the effect of Nd segregation, were investigated by first-principles calculations. Since the structure of doped BaCeO₃ at the operating temperature of proton-conducting has been unclear for a long time, we have summarized the latest experimental results and calculated the structure of the asymmetric BCYN for the first time. The results show that compared with Y, Nd doping promotes oxygen vacancy formation, however reduces proton stability. Our calculation can also provide a possible explanation for the formation of space charge layer at the grain boundary of doped BaCeO₃ in experiment. Unlike the stable Y in BCYN, Nd is calculated to be easily segregated, which can facilitate both proton hydration and proton transportation near the surface. Moreover, Nd segregation at the grain boundary is predicted to be beneficial for proton transportation between grains.     

Study on the removal of olefins from naphtha by clay loaded with trifluoromethanesulfonic acid

Journal of Porous Materials - In this work, a trifluoromethanesulfonic acid (TFOH) modified clay (TFOH-Clay) was developed for the removal of trace olefins in heavy naphtha. 5%TFOH-Clay can...     

Enhanced linear magneto-resistance near the Dirac point in topological insulator Bi2(Te1−xSex)3 nanowires

Nano Research - We report the composition and back-gate voltage tuned transport properties of ternary compound Bi2(Te1−xSex)3 nanowires synthesized by chemical vapor deposition (CVD). It is...     

高温酸化助排剂HC2-1的研究

为了满足高温油藏和深井酸化作业残酸返排的需要，通过表面活性剂的筛选和复配研究，得到了高温酸化助排剂HC2—1。其性能评价结果表明，HC2—1具有使用浓度低、表面活性高的特点，在20％的HCI溶液中，当其浓度为50mg／L时，表面张力为20．7mN／m；具有良好的耐温性能，在180℃下恒温48h，HC2—1仍保持较高的表面活性；具有良好的耐盐能力，加有HC2—1的20％HCl溶液和CaCO3反应至HCl完全消耗，整个反应过程体系无新相生成且表面张力基本不变；可增大酸液体系的润湿角，进一步降低毛细管阻力，使酸液返排率由46％提高到97％，在促进酸液返排的同时与原油不发生乳化反应。     

运用NOAA AVHRR和Landsat TM数据估算多年水稻种植面积

介绍了综合运用NOAA AVHRR和Landsat TM数据进行多年水稻种植面积监测的一种方法,以湖北省为例,首先运用Landsat TM数据计算了该省1992年的水稻种植面积;接着运用1992年和1994年的NOAA AVHRR数据分别计算这两年的水稻像元数,以这两年水稻像元数的变化来反映水稻种植面积的变化;最后运用线性模型,估算1994年的水稻种植面积。所得的1994年水稻种植面积与湖北省农调队资料相比精度为84.5%。运用同样的方法估算1995年该省的水稻种植面积,精度达90%以上。