Novel electrospun polymer electrolytes incorporated with Keggin‐type hetero polyoxometalate fillers as solvent‐free electrolytes for lithium ion batteries

In this study, solvent‐free nanofibrous electrolytes were fabricated through an electrospinning method. Polyethylene oxide (PEO), lithium perchlorate and ethylene carbonate were used as polymer matrix, salt and plasticizer respectively in the electrolyte structures. Keggin‐type hetero polyoxometalate (Cu‐POM@Ru‐rGO, Ni‐POM@Ru‐rGO and Co‐POM@Ru‐rGO (POM, polyoxometalate; rGO, reduced graphene oxide)) nanoparticles were synthesized and inserted into the PEO‐based nanofibrous electrolytes. TEM and SEM analyses were carried out for further evaluation of the synthesized filler structures and the electrospun nanofibre morphologies. The fractions of free ions and crystalline phases of the as‐spun electrolytes were estimated by obtaining Fourier transform infrared and XRD spectra, respectively. The results showed a significant improvement in the ionic conductivity of the nanofibrous electrolytes by increasing filler concentrations. The highest ionic conductivity of 0.28 mS cm^?1 was obtained by the introduction of 0.49 wt% Co‐POM@Ru‐rGO into the electrospun electrolyte at ambient temperature. Compared with solution‐cast polymeric electrolytes, the electrospun electrolytes present superior ionic conductivity. Moreover, the cycle stability of the as‐spun electrolytes was clearly improved by the addition of fillers. Furthermore, the mechanical strength was enhanced with the insertion of 0.07 wt% fillers to the electrospun electrolytes. The results implied that the prepared nanofibres are good candidates as solvent‐free electrolytes for lithium ion batteries. © 2020 Society of Chemical Industry     

Experimental and computational study of gas–solid fluidized bed hydrodynamics

The hydrodynamics of a two-dimensional gas–solid fluidized bed reactor were studied experimentally and computationally. Computational fluid dynamics (CFD) simulation results from a commercial CFD software package, Fluent, were compared to those obtained by experiments conducted in a fluidized bed containing spherical glass beads of 250– in diameter. A multifluid Eulerian model incorporating the kinetic theory for solid particles was applied in order to simulate the gas–solid flow. Momentum exchange coefficients were calculated using the Syamlal–O’Brien, Gidaspow, and Wen–Yu drag functions. The solid-phase kinetic energy fluctuation was characterized by varying the restitution coefficient values from 0.9 to 0.99. The modeling predictions compared reasonably well with experimental bed expansion ratio measurements and qualitative gas–solid flow patterns. Pressure drops predicted by the simulations were in relatively close agreement with experimental measurements at superficial gas velocities higher than the minimum fluidization velocity, U_mf. Furthermore, the predicted instantaneous and time-average local voidage profiles showed similarities with the experimental results. Further experimental and modeling efforts are required in a comparable time and space resolutions for the validation of CFD models for fluidized bed reactors.     

Developing an Interactive Spatial Multi-Attribute Decision Support System for Assessing Water Resources Allocation Scenarios

Water Resources Management - In water resource management, assessing water resource allocation scenarios (WRASs) is an important multi-attribute decision making (MADM) problem. It involves...     

Colloidal Quantum Dot Infrared Lasers Featuring Sub-Single-Exciton Threshold and Very High Gain

The use of colloidal quantum dots (CQDs) as a gain medium in infrared laser devices has been underpinned by the need for high pumping intensities, very short gain lifetimes, and low gain coefficients. Here, PbS/PbSSe core/alloyed-shell CQDs are employed as an infrared gain medium that results in highly suppressed Auger recombination with a lifetime of 485 ps, lowering the amplified spontaneous emission (ASE) threshold down to 300 µJ cm⁻², and showing a record high net modal gain coefficient of 2180 cm⁻¹. By doping these engineered core/shell CQDs up to nearly filling the first excited state, a significant reduction of optical gain threshold is demonstrated, measured by transient absorption, to an average-exciton population-per-dot 〈N^th〉_g of 0.45 due to bleaching of the ground state absorption. This in turn have led to a fivefold reduction in ASE threshold at 〈N^th〉_ASE = 0.70 excitons-per-dot, associated with a gain lifetime of 280 ps. Finally, these heterostructured QDs are used to achieve near-infrared lasing at 1670 nm at a pump fluences corresponding to sub-single-exciton-per-dot threshold (〈N^th〉_Las = 0.87). This work brings infrared CQD lasing thresholds on par to their visible counterparts, and paves the way toward solution-processed infrared laser diodes.     

Effects of stray magnetic forces on position error signals during a long seeking-and-settling process

This paper is to study how stray magnetic forces encountered in a long seeking process affect position errors of a hard disk drive after it finishes the seek and settles. The study consists of three parts: analysis of stray magnetic forces, numerical modeling, and analysis of numerical results. In the analysis of stray magnetic forces, we lump the stray magnetic forces into three components D1, D2 and D4. Specifically, D1 is a pair of stray magnetic forces in the plane of the voice coil. The two forces act on the two equal legs of the voice coil. In addition, the two forces point to and away from the pivot center, respectively. D2 is a pair of stray magnetic forces out of the plane of the voice coil. The two forces are equal in magnitudes but opposite in directions. The two force components also act on the two equal legs of the voice coil. D4 is identical to D2, except that the two force components in D4 act in the same direction. In the numerical study, we adopt a numerical model that includes a spinning spindle motor, a spinning disk pack with multiple disks, a stationary base plate with a top cover, and a slewing head-stack assembly. Moreover, multiple bearings are present in the model to connect the multiple components. In particular, fluid-dynamic bearings connect the rotating spindle and disk pack with the base plate, pivot bearings connect the base plate with the head-stack assembly, and air bearings connect the spinning disk pack with head sliders located at the tip of the slewing head-stack assembly. Also, the numerical model assumes that the head-stack assembly seeks according to a user-specified seeking profile. Numerical simulations show two major conclusions. First, stray magnetic force component D1 does not lead to significant position errors when the head-stack assembly settles. Stray magnetic force components D2 and D4, however, can affect the position errors by significantly exciting torsion and bending modes of the head-stack assembly. Second, a flex cable can significantly increase position errors below 1 kHz during settling.     

Theoretical calculation simulation studies of ABV nuclear reactor coupled with desalination system

In this paper, research has been conducted on the floating type nuclear power plant named as ABV reactor which is designed for district heating, power, and sea water desalination by OKBM facility at Russia. This reactor was tested under different thermal loads during the designing phase, and three modules have been investigated. Theoretical calculations and simulation studies have been performed on these three modules having specifications as ABV‐6M with 47MW_th, ABV‐6 with 38MW_th, and ABV‐3 with 18MW_th.The results obtained from these modules have been calculated mathematically and verified by simulation. We have compared the originally derived data of ABV desalination system with our theoretical and simulation analysis. The results from two desalination techniques including RO and RO + MED have been calculated and are presented in this paper with details. The results obtained from both analysis show that the efficiency of ABV nuclear reactor desalination system increases with the decrease in corresponding water cost ratio. Copyright © 2015 John Wiley & Sons, Ltd.     

Theoretical investigation of plasma dynamical behavior and halo current analysis

In this paper, a novel system has been developed for plasma disruption conditions followed by downward vertical displacement. During the disruption, size and orientation of plasma decreases, which gives the halo current circulated around each contacting point in radial as well as in poloidal directions. Therefore, a new mathematical model has been developed, which gives the interaction forces of halo current, vertical, and radial plasma dynamical behavior (linear and nonlinear). This theoretical approach showed that the tokamak plasma has two connecting points in order to distinguish between the stable and unstable position. This model can particularly give the magnetic field change points and changing of flux, which are more convenient in order to discuss the static and tilting position of plasma behavior. Numerical techniques have been calculated in terms of plasma dynamical behavior, that is, Electromagnetic/plasma, Vertical Displacement Event (VDE) stages, and initial interaction between the forces under specific time interval. The objective of the research is to developed theoretical and computational model in order to investigate the dynamical behavior of plasma under disruption conditions. This is the novel method, and no work has been reported so far. Copyright © 2015 John Wiley & Sons, Ltd.     

Biogenic Amine Contents in Non-alcoholic Beers: Screening and Optimization of Derivatization

A rapid, sensitive, and reproducible high-performance liquid chromatographic procedure for the determination of nine biogenic amines in non-alcoholic beers was developed by an optimized benzoylation procedure. A Plackett–Burman factorial design was used in order to screen the statistically significant variables. The significant factors of biogenic amine benzoylation, reagent volume and pH, were optimized by a complete factorial response surface design, and optimal reaction conditions were generated. The optimized method showed good linearity (correlation coefficients > 0.997) and good recoveries (from 88.6 to 104.7 %). The repeatability and reproducibility of method were >3.9 and >4.6 %, respectively. Moreover, the detection limits of biogenic amines were calculated between 0.05 and 0.15 μg/ml in wine samples. The optimized method has been applied to the determination of biogenic amine contents of non-alcoholic beers consumed in Iran. Their values ranged from 0 to 2.56 mg/l, no significant differences (p?>?0.05) were observed between the analyzed samples, and none of these samples surpass the toxic levels reported in the literature.