一种提高光电倍增器光电阴极量子效率的方法

提出了一种可以提高光电倍增管光电阴极量子效率的方法。通过分析光电阴极的光电发射过程,从提高光子吸收率Pa和光电子迁移至真空一侧材料表面的几率Pe出发,确定可以在光电阴极膜层结构设计上增加合适的膜层,该膜层具有高带隙和减反射的作用。由于光电倍增管的外壳通常为细长的玻璃管,而常规的溅射设备为50mm的大靶,直接使用大靶对细管内部镀膜,效率低下且均匀性差。在常规大靶的基础上进行改造,成功实现了在细管内部快速均匀镀膜。使用分光设备测试光电阴极的光谱响应,结果表明,改进产品的光电阴极量子效率从常规的25%提高至35%。     

Fabrication of high-quality ZnS buffer and its application in Cd-free CIGS solar cells

This paper provides the fabrication of Cd-free Cu（In,Ga）Se2 （CIGS） solar cells on soda-lime glass substrates. A high quality ZnS buffer layer is grown by chemical bath deposition （CBD） process with ZnSO4-NH3-SC （NH2）2 aqueous solution system. The X-ray diffraction （XRD） result shows that the as-deposited ZnS film has cubic （111） and （220） diffraction peaks. Scanning electron microscope （SEM） images indicate that the ZnS film has a dense and compact surface with good crystalline quality. Transmission measurement shows that the optical transmittance is about 90% when the wavelength is beyond 500 nm. The bandgap （Eg） value of the as-deposited ZnS film is estimated to be 3.54 eV. Finally, a competitive efficiency of 11.06% is demonstrated for the Cd-free CIGS solar cells with ZnS buffer layer after light soaking.