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Catalytic combustion of dimethyl ether (DME) over hexaaluminate catalyst BaNi0.2Mn0.8Al11O19-δ has been investigated. The catalysts were prepared with the sol-gel method and reverse microemulsion method respectively and characterized by thermogravimetry-differential thermal analysis, X-ray diffraction and transimission electron microscope. It was found that the formation of Mn, Ni modified hexaaluminate was a relatively slow process via two solid state reactions and spinel structure was a transition phase. At the same calcined temperature and time, the catalyst prepared with the reverse microemulsion method could form the hexaaluminate phase more easily than that prepared with the sol-gel method. The catalyst BaNi0.2Mn0.8Al11O19-δ prepared with the reverse micro-emulsion method appeared a plate-like morphology, while it appeared a needle-like morphology when using the sol-gel method. The catalytic activities of catalysts BaNi0.2Mn0.8Al11O19-δ prepared with two different methods for DME combustion were tested. It showed that catalyst prepared with the reverse microemulsion method had better catalytic activity, i.e. T10% of DME had decreased by 45℃, about 90% conversion of diemthyl ether at 380℃. 相似文献
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采用反相微乳法制备和超临界干燥获得前驱体BaO.MnO.6Al2O3。利用TG-DTA曲线和XRD分析对前驱体的热分解过程进行研究,并用Coats-Redfern法和Kissinger法进一步研究前驱体的热分解动力学,获得六铝酸盐催化剂前驱体热分解的机制函数为:积分式G(α)=[-ln(1-α)]4,微分式为:f(α)=(1/4)(1-α)[-ln(1-α)]-3,反应为随机成核和随后生长控制,计算出的活化能Ea=187.80kJ.mol-1。 相似文献
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制备方法对BaNi0.2Mn0.8Al11O19-δ催化燃烧二甲醚的催化活性的影响 总被引:1,自引:0,他引:1
Catalytic combustion of dimethyl ether (DME) over hexaaluminate catalyst BaNi0.2Mn0.8Al11O19-δ has been investigated. The catalysts were prepared with the sol-gel method and reverse microemulsion method respectively and characterized by thermogravimetry-differential thermal analysis, X-ray diffraction and transimission electron microscope. It was found that the formation of Mn, Ni modified hexaaluminate was a relatively slow process via two solid state reactions and spinel structure was a transition phase. At the same calcined temperature and time, the catalyst prepared with the reverse microemulsion method could form the hexaaluminate phase more easily than that prepared with the sol-gel method. The catalyst BaNi0.2Mn0.8Al11O19-δ prepared with the reverse micro-emulsion method appeared a plate-like morphology, while it appeared a needle-like morphology when using the sol-gel method. The catalytic activities of catalysts BaNi0.2Mn0.8Al11O19-δ prepared with two different methods for DME combustion were tested. It showed that catalyst prepared with the reverse microemulsion method had better catalytic activity, i. e. T10% of DME had decreased by 45℃, about 90% conversion of diemthyl ether at 380℃. 相似文献
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