退火温度对NiZn铁氧体薄膜性能的影响

用溶胶-凝胶(Sol-Gel)法在Si(100)基片上沉积了NiZn铁氧体薄膜,研究了退火温度对薄膜结构和磁性能的影响.XRD研究表明,薄膜具有立方尖晶石结构,但当退火温度为900 ℃时,有SiO2相出现,发生了明显的Si扩散.原子力显微镜(AFM)究表明,退火温度升高,薄膜晶粒尺寸逐渐变大,粗糙度相应增加.随着退火温度的升高,薄膜的饱和磁化强度(Ms)呈先增加后降低的趋势,而矫顽力(Hc)与Ms变化相反.当退火温度为700 ℃时,薄膜具有最优磁性能,Ms=360×103 A/m,Hc=6 764 A/m.     

NiZn铁氧体薄膜制备技术的研究进展

综述了近10年来国内外NiZn铁氧体薄膜制备技术的研究进展，并对其发展进行了展望。其中，溅射、喷雾热分解、脉冲激光沉积等技术得到了有效应用；而对一些新的工艺方法，如溶胶-凝胶法、超声波增强化学镀技术等也进行了深入的研究。     

Microstructure and magnetic properties of NiZn ferrite thin films prepared by sol-gel method

Ti^4＋ substitution for Fe^3＋ in Ni0.5Zn0.5Fe2O4 （NZF） ferrite thin films were realized by sol-gel method and annealing at 600℃for 30 min in the air. Crystal structure and lattice constant determination was performed by X-ray diffractometer （XRD）. Surface microstructure was observed by scanning electron microscope （SEM） and atomic force microscope （AFM）, and the magnetic properties were measured by vibrating sample magnetometer （VSM）. XRD analyses of the samples show that Ni0.5＋xZn0.5TixFe2-2xO4 （NZTF） films with x varing from 0 to 0.15 in steps of 0.05 are composed of single phase with spinel structure. And the lattice parameter, particle size and the diffraction intensity of the films increase with substitution of Ti as the result of the larger radius ions entering the lattice. SEM and AFM show homogeneous grain size of each sample, but there is a few differences in grain size with different Ti-substitution contents. As the nonmagnetic Ti^4＋ substitutes Fe^3＋, both the saturation magnetization and coercivity decrease.