利用色彩转换膜实现白色有机电致发光研究

利用蓝色有机发光二极管(BOLED)激发色彩转换膜的方法,制备了一种新型的白色有机电致发光器件(WOLED)。BOLED的发光层采用CBP主体掺杂高效蓝色荧光染料N-BDAVBi来制备;色彩转换膜是将橙红色荧光颜料VQ-D24均匀分散到A、B环氧树脂中涂敷、固化而成。通过调整与分析转换膜的厚度和荧光颜料的掺杂比例来优化白光器件的发光光谱,获得了色稳定性较高的WOLED。当驱动电压由7V升至14V时,WOLED的色坐标(CIE)仅在(0.33,0.32)和(0.34,0.28)间变化,器件最高电流效率约为7.3cd/A(4.35mA/cm2),最高亮度为12000cd/m2(14V)。     

White organic light emitting devices with a color conversion layer

A white organic light emitting device (WOLED) combining the blue organic light emitting device with a red color conversion layer (CCL) is reported, which includes a fluorescent material N-(4-((E)-2-(6-((E)-4-(diphenylamino) styryl)naphtha len-2-yl)vinyl) phenyl)-N-phenylbenzenamine (N-BDAVBi) doped into 4,4′-N,N′-dicarbazole-biphenyl (CBP) as the blue light emitting layer, and the poly (2-methoxy-5-(2′-ethylhexoxy)-1,4-phenylene vinylene (MEH-PPV) as a red CCL. By optimizing the concentration of MEH-PPV in the CCL, a good white light emission is obtained, which shows that the stable CIE coordinates of (0.33, 0.34) will have a slight change when the driving voltage is increased from 6 to 11 V. The maximum brightness and current efficiency of the optimized device are 11294 cd/m² and 6.4 cd/A, respectively.