Synthesis,characterization and charge transport properties of Pr–Ni Co-doped SrFe2O4 spinel for high frequency devices applications

Ferrites are materials of interest due to their broad applications in high technological devices and a lot of research has been focused to synthesize new ferrites. In this regard, an effort has been devoted to synthesize spinel Pr–Ni co-substituted strontium ferrites with a nominal formula of Sr_1-xPr_xFe_2-yNi_yO₄ (0.0 ≤ x ≤ 0.1, 0.0 ≤ y ≤ 1.0). The cubic structure of pure and Pr–Ni co-substituted strontium ferrite samples calcinated at 1073 K for 3 h has been confirmed through X-ray diffraction (XRD). Average sizes of crystallites (18–25 nm) have been estimated from XRD analysis and nanometer particle sizes of synthesized ferrites have been further verified by scanning electron microscopy (SEM). SEM results have also shown that particles are mostly agglomerated and all the samples possess porosity. It has been observed that at 298 K, the values of resistivity (ρ) increase, while that of AC conductivity, dielectric loss, and dielectric constants decrease with increasing amounts of Pr³⁺ and Ni²⁺ ions. The values of dielectric parameters initially decrease with frequency and later become constant and can be explained on the basis of dielectric polarization. Electrochemical impedance spectroscopy (EIS) studies show that the charge transport phenomenon in ferrite materials is mainly controlled via grain boundaries. Overall, synthesized ferrite materials own enhanced resistivity values in the range of 1.38 × 10⁹–1.94 × 10⁹ Ω cm and minimum dielectric losses, which makes them suitable candidates for high frequency devices applications.     

Boosting the activity of FeOOH via integration of ZIF-12 and graphene to efficiently catalyze the oxygen evolution reaction

Transition metal oxyhydroxides have been used as promising electrocatalysts for water splitting however, their catalytic activity is restricted due to low surface area and poor conductivity. Herein, we report novel composite FeOOH@ZIF-12/graphene composite as electrocatalyst for water oxidation, whereby ZIF-12 provide extra surface for the FeOOH dispersion whilst graphene act as excellent electron mediator. The composite shows a low overpotential value of 291 mV to attain a current density of 10 mA cm^?2 and a low Tafel slope value of 78 mV dec^?1. The catalyst offers a maximum current density of 101 mA cm^?2, while it gives a turnover frequency (TOF) value of 0.031 s^?1 at an overpotential of 291 mV only. The excellent activity and remarkable stability of composite is attributed to highly conductive and porous support.     

Characterization and optimization of linearly tapered slot antenna pattern

A parametric study of linearly tapered slot antenna (LTSA) in air and a method for optimization of its pattern are presented. A method of moments code is utilized to investigate the behavior of LTSA’s as the length, height and the taper angle varies. It is shown that the antenna pattern can be improved using a top layer of dielectric material with varying permittivity.     

Cit-CSP及其应用

介绍了Cit-CSP--Cit/E-commerce信息安全保障平台子系统，并阐述了它所提供的消息摘要、块加密、加密(公钥)、签名和MAC等功能和服务。     

基于加载算法的室内无线信道OFDM接收机的性能

本文研究了无线局域网中使信号频谱得到优化的一种简单OFDM子载波加载算法。此算法基于边缘自适应（Margin Adaptive）加载准则及其在室内无线信道上的性能。     

Microscale and mesoscale discrete models for dynamic fracture of structures built of brittle material

In this work we present the discrete models for dynamic fracture of structures built of brittle materials. The models construction is based on Voronoi cell representation of the heterogeneous structure, with the beam lattice network used to model the cohesive and compressive forces between the neighboring cells. Each lattice component is a geometrically exact shear deformable beam which can describe large rigid body motion and the most salient fracture mechanisms. The latter can be represented through the corresponding form of the beam constitutive equations, which are derived either at microscale with random distribution of material properties or at a mesoscale with average deterministic values. The proposed models are also placed within the framework of dynamics, where special attention is paid to constructing the lattice network mass matrix as well as the corresponding time-stepping schemes. Numerical simulations of compression and bending tests is given to illustrate the models performance.     

The Cultural Politics of Aerial Vision: Le Corbusier in Brazil (1929)

The early twentieth-century invention of the airplane brought on a cultural euphoria that influenced the works and writings of urbanists, architects, artists, and science-fiction writers during the 1920s and 1930s. Le Corbusier's urban design for Rio de Janeiro—which he sketched, so he claimed, from an airplane—offers a visual basis to study how the aesthetic experience of flight was translated spatially, visually, and politically into his design of the future city. The polemics informing Le Corbusier's aerial "discovery" of South American geography revealed that there was a new empowerment in the act of looking from above, and that the spatial characteristics of his subsequent design interventions evoked that empowerment.     

Stress resultant geometrically non-linear shell theory with drilling rotations. Part III: Linearized kinematics

A consistent formulation of the geometrically linear shell theory with drilling rotations is obtained by the consistent linearization of the geometrically non-linear shell theory considered in Parts I and II of this work. It was also shown that the same formulation can be recovered by linearizing the governing variational principle for the three-dimensional geometrically non-linear continuum with independent rotation field. In the finite element implementation of the presented shell theory, relying on the modified method of incompatible modes, we were able to construct a four-node shell element which delivers a very high-level performance. In order to simplify finite element implementation, a shallow reference configuration is assumed over each shell finite element. This approach does not impair the element performance for the present four-node element. The results obtained herein match those obtained with the state-of-the-art implementations based on the classical shell theory, over the complete set of standard benchmark problems.     

Forecasting based on sectoral energy consumption of GHGs in Turkey and mitigation policies

Recently, global warming and its effects have become one of the most important themes in the world. Under the Kyoto Protocol, the EU has agreed to an 8% reduction in its greenhouse gas (GHG) emissions by 2008–2012. The GHG emissions (total GHG, CO₂, CO, SO₂, NO₂, E (emissions of non-methane volatile organic compounds)) covered by the Protocol are weighted by their global warming potentials (GWPs) and aggregated to give total emissions in CO₂ equivalents. The main subject in this study is to obtain equations by the artificial neural network (ANN) approach to predict the GHGs of Turkey using sectoral energy consumption. The equations obtained are used to determine the future level of the GHG and to take measures to control the share of sectors in total emission. According to ANN results, the maximum mean absolute percentage error (MAPE) was found as 0.147151, 0.066716, 0.181901, 0.105146, 0.124684, and 0.158157 for GHG, SO₂, NO₂, CO, E, and CO₂, respectively, for the training data with Levenberg–Marquardt (LM) algorithm by 8 neurons. R² values are obtained very close to 1. Also, this study proposes mitigation policies for GHGs.     

A panoramic view of Li7P3S11 solid electrolytes synthesis,structural aspects and practical challenges for all-solid-state lithium batteries

The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm^-1, and deformability, the sulfide-based Li₇P₃S₁₁ solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li₇P₃S₁₁ could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li₇P₃S₁₁-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries.