Nano fibrillated cellulose-based foam by Pickering emulsion: Preparation,characterizations, and application as dye adsorbent

An ecofriendly and biodegradable porous structure was prepared from drying aqueous foams based on nano fibrillated cellulose (NFC), extracted from softwood pulp by subcritical water/CO₂ treatment (SC-NFC). The primary aim of this work was to use the modified SC-NFC as stabilizer for a water-based Pickering emulsion which upon drying, yielded porous cellulosic materials, a good dye adsorbent. In order to exploit the carboxymethylated SC-NFC (CMSC-NFC, with a degree of substitution of 0.35 and a charge density of 649 μeqv/g) as a stabilizer for water-based Pickering emulsion in subsequent step, an optimized quantity of octyl amine (30 mg/g of SC-NFC) was added to make them partially hydrophobic. A series of dry foam structures were prepared by varying the concentrations of treated CMSC-NFCs and 4 wt% was found to be the optimum concentration to yield foam with high porosity (99%) and low density (0.038 g/cc) along with high compression strength (0.24 MPa), superior to the conventionally extracted NFC. The foams were applied to capture as high as 98% of methylene blue dyes, making them a potential green candidate for treating industrial effluent. In addition, the dye adsorption kinetics and isotherms were found to be well suited with second order kinetics and Langmuir isotherm models.     

A single-phase algorithm for mining high utility itemsets using compressed tree structures

Mining high utility itemsets (HUIs) from transaction databases considers such factors as the unit profit and quantity of purchased items. Two-phase tree-based algorithms transform a database into compressed tree structures and generate candidate patterns through a recursive pattern-growth procedure. This procedure requires a lot of memory and time to construct conditional pattern trees. To address this issue, this study employs two compressed tree structures, namely, Utility Count Tree and String Utility Tree, to enumerate valid patterns and thus promote fast utility computation. Furthermore, the study presents an algorithm called single-phase utility computation (SPUC) that leverages these two tree structures to mine HUIs in a single phase by incorporating novel pruning strategies. Experiments conducted on both real and synthetic datasets demonstrate the superior performance of SPUC compared with IHUP, UP-Growth, and UP-Growth+ algorithms.     

Turbulent natural convection heat transfer from a vertical plate to the power-law fluid at high prandtl numbers

A simple analytical technique for turbulent natural convection heat transfer from an isothermal vertical plate to a power-law fluid is developed. The model is based on the assumption that the turbulent heat transfer rate is controlled by the flow characteristic near the surface in the limit of large Prandtl numbers. The formulation proposed in this work agrees well with the correlations available in the literature.     

Reactively compatibilised polyamide6/ethylene-co-vinyl acetate blends: mechanical properties and morphology

Mechanical properties and morphological studies of compatibilised blends of PA6/EVA-g-MA and PA6/EVA/EVA-g-MA were studied as functions of maleic anhydride content (MA) and dispersed phase (EVA-g-MA) concentrations, respectively at blending composition of 20 wt% dispersed phase (EVA-g-MA or combination of EVA and EVA-g-MA). The maleic anhydride (MA) was varied from 1 to 6 wt% in the PA6/EVA-g-MA blend, whereas MA concentration was fixed at 2 wt% in the ternary compositions with varying level of EVA-g-MA. ATR-IR spectroscopy revealed the formation of in situ copolymer during reactive compatibilisation of PA6 and EVA-g-MA. It was found that notched Izod impact strength of PA6/EVA-g-MA blends increased significantly with MA content in EVA-g-MA. The brittle to tough transition temperature of reactively compatibilised blends was found to be at 23 °C. The impact fractured surface topology reveals extensive deformation in presence of EVA-g-MA whereas; uncompatibilised PA6/EVA blend shows dislodging of EVA domains from the matrix. Tensile strength of the PA6/EVA-g-MA blends increased significantly as compared to PA6/EVA blends. Analysis of the tensile data using predictive theories showed an enhanced interaction of the dispersed phase and the matrix. It is observed from the phase morphological analysis that the average domain size of the PA6/EVA-g-MA blends is found to decrease gradually with increase in MA content of EVA-g-MA. A similar decrease is also found to observe in PA6/EVA/EVA-g-MA blends with increase in EVA-g-MA content, which suggest the coalescence process is slower in presence of EVA-g-MA. An attempt has been made to correlate between impact strength and morphological parameters with regard to the compatibilised system over the uncompatibilised system.     

Wii remote–based low-cost motion capture for automated assembly simulation

This paper describes the development of a Wii remote (Wiimote)–based low-cost motion capture system and demonstrates its application for automated assembly simulation. Multiple Wiimotes are used to form a vision system to perform motion capture in 3D space. A hybrid algorithm for calibrating a multi-camera stereo vision system has been developed based on Zhang’s and Svoboda’s calibration algorithms. This hybrid algorithm has been evaluated and shown accuracy improvement over Svoboda’s algorithm for motion capture with multiple cameras. The captured motion data are used to automatically generate an assembly simulation of objects represented by CAD models in real time. The Wiimote-based motion capture system is practically attractive because it is inexpensive, wireless, and easily portable. Application examples have been developed for a single vision system with two Wiimotes to track the assembly of a microsatellite prototype frame and for an integrated vision system with four Wiimotes to track the assembly of a bookshelf.     

Fuzzy logic techniques for navigation of several mobile robots

In this paper, navigation techniques for several mobile robots as many as one thousand robots using fuzzy logic are investigated in a totally unknown environment. Fuzzy logic controllers (FLC) using different membership functions are developed and used to navigate mobile robots. First a fuzzy controller has been used with four types of input members, two types of output members and three parameters each. Next two types of fuzzy controllers have been developed having same input members and output members with five parameters each. Each robot has an array of ultrasonic sensors for measuring the distances of obstacles around it and an infrared sensor for detecting the bearing of the target. These techniques have been demonstrated in various exercises, which depicts that the robots are able to avoid obstacles as well as negotiate the dead ends and reach the targets efficiently. Amongst the techniques developed, FLC having Gaussian membership function is found to be most efficient for mobile robots navigation.     

Application of evolutionary optimization techniques for finding the optimal set of concentric circular antenna array

In this paper the maximum sidelobe level (SLL) reductions, optimal beam patterns and optimal beam widths of various designs of three-ring planar concentric circular antenna arrays (PCCAA) are examined using three different classes of evolutionary optimization techniques to finally determine the global optimal three-ring PCCAA design and then establish some sort of ranking among the techniques. Apart from physical construction of a PCCAA, one may broadly classify its design into two major categories: uniformly excited arrays and non-uniformly excited arrays. The present paper assumes non-uniform excitations and uniform spacing of excitation elements in each three-ring PCCAA design and a design goal of maximizing SLL reduction associated with optimal beam patterns and beam widths. The design problem is modeled as an optimization problem for each PCCAA design and solved using different evolutionary optimization techniques to determine an optimum set of normalized excitation weights for PCCAA elements, which, when incorporated, results in a radiation pattern with optimal (maximum) SLL reduction. Among the various PCCAA designs, one which yields the global minimum SLL with global minimum first null beamwidth is the global optimal design. In this work the three-ring PCCAA containing (N₁ = 4, N₂ = 6, N₃ = 8) elements proves to be such global optimal design. The optimization techniques employed are real coded GA (RGA), canonical PSO (CPSO), craziness based PSO (CRPSO), evolutionary programming (BEP), hybrid evolutionary programming (HEP). While ranking the techniques after 30 total runs for each design, HEP, CRPSO, RGA, CPSO, BGA hold the first five ranks in order of optimization capability. HEP yields global minimum SLL (?32.86 dB) and global minimum BWFN (77.0°) for the optimal design. BEP often changes the rank from second to fifth depending on the design set. Further, when compared to a uniformly excited PCCAA having equal number of elements and same radii a reduction of major lobe beamwidth is also observed in the optimal non-uniformly excited case.     

Deterministic extractors for small-space sources

We give polynomial-time, deterministic randomness extractors for sources generated in small space, where we model space s sources on ${\{0,1\}}^n$ as sources generated by width $2^s$ branching programs. Specifically, there is a constant $\eta >0$ such that for any $\zeta >n^{?\eta }$, our algorithm extracts $m=(\delta ?\zeta )n$ bits that are exponentially close to uniform (in variation distance) from space s sources with min-entropy δn, where $s=\Omega ({\zeta }^{3}n)$. Previously, nothing was known for $\delta ?1/2$, even for space 0. Our results are obtained by a reduction to the class of total-entropy independent sources. This model generalizes both the well-studied models of independent sources and symbol-fixing sources. These sources consist of a set of r independent smaller sources over ${\{0,1\}}^{?}$, where the total min-entropy over all the smaller sources is k. We give deterministic extractors for such sources when k is as small as $\mathsf{polylog}(r)$, for small enough ?.     

An eigenvalue approach to the risk sensitive control problem in near monotone case

Risk sensitive control problem under near monotonicity condition is considered. We prove existence of a solution to the corresponding Hamilton-Jacobi-Bellman equation by an eigenvalue approach. Existence of an optimal control has also been proved.     

In-house contamination of potable water in urban slum of Kolkata, India: a possible transmission route of diarrhea

We have investigated and determined the potentiality of different water sources, both for drinking and domestic purposes, in diarrheal disease transmission in diarrhea endemic foci of urban slums in Kolkata, India in a one and half year prospective study. Out of 517 water samples, collected from different sources, stored water (washing) showed higher prevalence of fecal coliforms (58%) (p < 0.0001) in comparison with stored (drinking) samples (28%) and tap/tubewell water (8%) respectively. Among different sources, stored water (washing) samples had the highest non-permissible range of physico-chemical parameters. Fecal coliform levels in household water containers (washing) were comparatively high and almost 2/3 of these samples failed to reach the satisfactory level of residual chlorine. Interestingly, 7% stored water (washing) samples were found to be harboring Vibrio cholerae Improper usage of stored water and unsafe/poor sanitation practices such as hand washing etc. are highlighted as contributory factors for sustained diarrheal episodes. Vulnerability of stored water for domestic usage, a hitherto unexplored source, at domiciliary level in an urban slum where enteric infections are endemic, is reported for the first time. This attempt highlights the impact of quality of stored water at domiciliary level for fecal-oral contamination vis-à-vis disease transmission.