Application of GA-Optimized ANNs to Predict the Water Content,CO2 and H2S Absorption Capacity of Diethanolamine (DEA) in Khangiran Gas Sweetening Plant

Theoretical Foundations of Chemical Engineering - In this work, with the aim of accurate prediction of water content, H2S and CO2 absorption capacity of diethanolamine (DEA) solvent in Khangiran...     

Lattice structure on some fuzzy algebraic systems

In this paper, we study the lattice structure of some fuzzy algebraic systems such as (G-)fuzzy groups, some fuzzy ordered algebras and fuzzy hyperstructures. We prove that under suitable conditions, these structures form a distributive or modular lattice. This research partially is supported by the “ Fuzzy Systems and its Applications Center of Excelence, Shahid Bahonar University of Kerman, Iran”.     

Performance of combined cobalt—nickel—zirconia and HZSM-5 catalyst systems for carbon monoxide hydrogenation

The synthesis of hydrocarbons via hydrogenation of carbon monoxide was investigated over cobalt—nickel—zirconia catalysts of various compositions in combination with zeolite HZSM-5 in “mixed bed” and “follow bed” arrangements. These combinations resulted in the formation of aromatics in amounts as high as 30-35 wt% under relatively mild operating conditions (1 atm, 250–280°C). Although the olefinicity of C₂ and C₃ fractions in the product stream was higher in the mixed bed compared to the follow bed arrangement, the selectivities to aromatics were comparable in the two bed arrangements. The aromatic selectivity was found to be sensitive to operating conditions. The formation of aromatics was favored at high HZSM-5/metal catalyst ratios, low space velocities and high reaction temperatures. The product distributions obtained using various metal/zeolite bifunctional catalysts have been discussed.     

Production of biodiesel from waste fryer grease using mixed methanol/ethanol system

Transesterification of waste fryer grease (WFG) containing 5–6 wt.% free fatty acid (FFA) was carried out with methanol, ethanol, and mixtures of methanol/ethanol maintaining the oil to alcohol molar ratio of 1:6, and initially with KOH as a catalyst. Mixtures of methanol and ethanol were used for transesterification in order to use the better solvent property of ethanol and rapid equilibrium using methanol. Formation of soap by reaction of FFA present in WFG with KOH instigated difficulty in the separation of glycerol from biodiesel ester. To untangle this problem, two-stage (acid and alkali catalyzed) method was used for biodiesel synthesis. More than 90% ester was obtained when two-stage method was used compared to ∼ 50% ester in single stage alkaline catalyst. In the case of mixed alcohol, a relatively smaller amount of ethyl esters was formed along with methyl esters. Acid value, viscosity, and cetane number of all the esters prepared from WFG were within the range of the ASTM standard. Esters obtained from WFG showed good performance as a lubricity additive.     

Reducing interchannel crosstalk in long-haul DWDM systems

Nonlinear interaction between signal channels may result in significant performance degradation in transoceanic dense wavelength-division-multiplexing (WDM) transmission systems operated at high bit rates. In this paper, we report that the nonlinear crosstalk for systems with high spectral efficiency can be suppressed if WDM channels are launched with orthogonal relative states of polarization. It is shown that for adjacent channels (that experience the strongest nonlinear interaction) the launched relative state of polarization is maintained over the large distance of low polarization-mode dispersion fiber typically used in undersea systems. Numerical studies, as well as experimental results, are presented for standard and dispersion slope-matched dispersion maps     

Application of orthogonal collocations to some transport phenomena problems in co-axial cylinders and spheres

Collocation methods are developed for the solution of some differential equation models for transport phenomena problems in one-and two-dimensions in co-axial annuli of spherical and cylindrical shapes. General formulae are developed to obtain orthogonal polynomials over an arbitrary interval using two types of weighting functions. The convergence and accuracy of the methods are demonstrated using two test problems, i.e., calculation of effectiveness factors in (a) a spherical pellet with peripherally deposited catalyst and (b) a Raschig ring type cylindrical catalyst pellet. Comparisons of results obtained from the present methods with analytic solutions for the first-order reactions indicate good agreement. Numerical solutions are also obtained for the second-and the third-order reactions for which analytic solutions are not available. Results obtained in terms of a new Thiele modulus involving the ratio of volume of peripherally deposited part of catalyst to exterior surface area indicate that this normalization brings effectiveness factor versus Thiele modulus curves close together for co-axial spherical and long cylindrical pellets, as it does for these geometries without the inner co-axial portion.     

Direct generation of subpicosecond chirp-free pulses at 10 GHz froma nonpolarization maintaining actively mode-locked fiber ring laser

0.7-1.3 ps highly stable, transform-limited, sech²-shaped pulses at 10 GHz in the 1536-1569 nm wavelength region from a nonpolarization maintaining (PM), single intensity modulator, actively and harmonically mode-locked fiber ring laser have been directly generated. Little degradation of long-term stability of the laser operation was observed due to the non-PM nature of the laser cavity     

Full-duplex overlay cognitive wireless powered communication network using RF energy harvesting

In this paper, a novel full-duplex overlay cognitive wireless powered communication network (FD-OCWPCN) is proposed where a full-duplex (FD) hybrid-access point (H-AP) supports the full access of all battery-free secondary users (SUs). The H-AP broadcasts wireless power to empower the nearby SUs in the downlink (DL) phase while decoding the information transmitted uplink (UL) phase by the SUs, simultaneously. To overcome the self-interference (SI) phenomenon in FD-OCWPCN, the problem of maximizing the system sum-throughput with optimal UL-DL transmission/reception time and H-AP’s transmit power allocation is considered. This problem is non-convex under perfect/imperfect SI cancelation (SIC), so we employ the active interference temperature control and the gradient projection techniques to effectively reduce it into a convex problem. Closed-form expressions for the perfect/imperfect SIC cases are also derived. To assess the performance of the FD-OCWPCN, a comparison with a half-duplex OCWPCN (HD-OCWPCN) is provided. The achievable average sum-throughput for different FD/HD-OCWPCN is compared in the context of the average and peak transmit power at the H-AP, the number of SUs, path loss exponent and fairness metric. The simulation results depict the superiority of the FD-OCWPCN over the HD-OCWPCN for the perfect SIC and the effective imperfect SIC.

     

Castor oil-based polyurethane coatings containing benzyl triethanol ammonium chloride: synthesis,characterization, and biological properties

In the present work, benzyl triethanol ammonium chloride (BTEAC) was employed as a reactive bactericidal additive for preparing of polyurethane coatings. In this regard, castor oil as a renewable resource-based polyol, polyethylene glycol (PEG1000), and BTEAC were reacted with toluene diisocyanate. Physical, mechanical, and thermal characteristics as well as biocompatibility and antibacterial properties of polyurethanes were evaluated. The prepared polyurethanes showed two-phase structure with soft and hard segments glass transition temperature transitions in the range of 18–70 and 85–153 °C, respectively. Initial modulus and tensile strength were improved for coatings with higher BTEAC content, while elongation at break and thermal stability were decreased. Hydrophilicity of coatings was increased for polyurethanes based on higher content of BTEAC and PEG1000. Polyurethanes with higher BTEAC content showed better cytocompatibility for mouse L929 fibroblast cells. Moreover, coatings with higher hydrophilicity and BTEAC content displayed superior antibacterial activity against both Escherichia coli and Staphylococcus aureus bacteria.     

Synthesis and Spark Plasma Sintering of Mg2Si Nanopowder by Mechanical Alloying and Heat Treatment

In this investigation, a two‐step method for the preparation of magnesium silicide (Mg₂Si) nanopowder was studied. This method is known as mechanical alloying followed by heat treatment. The results showed that the compositions of the combustion products depended on the milling time, heat treatment temperature, and starting mixtures. Pure Mg₂Si nanopowder was formed after short milling time and heat treatment, from Mg and Si powders with the mole ratio of 2.1:1 (Mg:Si) at 500°C in Ar atmosphere. Using the Mg₂Si nanopowder, Mg₂Si ceramic was produced by spark plasma sintering at 800°C under 50 MPa for 15 min. Composition and structure of reactants and products were examined by X‐ray diffraction (XRD), field emission scanning electron microscopy (FE‐SEM) and high‐resolution transmission electron microscopy (HR‐TEM).