Installation of Horizontal Wells in Landfilled Waste Using Directional Drilling

Leachate levels within a landfill must often be controlled for environmental and/or regulatory reasons by means of pumping from wells. Conventional vertical wells are usually used for this purpose, but there is a perception that they are inefficient. In this paper, the feasibility of using directional drilling to install horizontal wells for leachate control in landfills is investigated with reference to pilot and full scale field trials at Rainham, U.K. The difficulties of well-screen design and installation in a landfilled waste are discussed; the insights gained during trial installation are described; and the effectiveness of three trial wells is assessed with reference to the leachate flow rates and drawdowns achieved, in comparison with conventional vertical wells. It is concluded that the drilling rig used must be sufficiently powerful to cope with the likelihood of at least partial borehole collapse around the well-screen during installation; that the screen slot size can be based on at least the D30 particle size of the waste and a natural filter allowed to develop around the well (provided that the resulting well screen is strong enough); and that as experience with the technology grows, directionally drilled horizontal wells could represent a viable, cost effective alternative to conventional vertical wells for leachate control in landfills.     

A study of the early stages of tempering of iron-carbon martensites by atom probe field ion microscopy

The redistribution of carbon atoms during the early stages of ageing and tempering of iron-carbon martensites has previously been studied only by indirect methods. The computer-controlled atom probe field ion microscope permits the direct, quantitative determination of carbon concentrations at the atomic level, and thus all the stages of the martensite decomposition process become amenable to direct study. Analyses of a low-carbon martensite, Fe-1.0 at. pct C, (Fe-0.21 wt pct C), water quenched and tempered for 10 min at 150 °C, showed a matrix carbon content of only 0.14 at. pct. Analysis of a 2 nm diam area centered on a lath boundary showed a local concentration of 2.01 at. pct C. There is some evidence that this carbon level is associated with the presence of a thin film of retained austenite at the boundary. In the case of a higher carbon martensite, Fe-0.64 at. pct Mn, 3.47 at. pct C, (Fe-0.65 wt pct Mn-0.78 wt pct C) water quenched and aged for approximately 24 h at room temperature, analysis of twinned regions showed a matrix carbon level of 2.7 at. pct and a concentration enrichment to 6.9 at. pct in a region 2 nm diam, centered on the coherent twin interface. Assuming the segregated carbon to be located in a single atomic layer at the twin interface, this result indicates that a carbon concentration of 24 at. pct exists locally at the boundary. These results appear to be the first direct demonstration of the segregation of carbon atoms to lattice defects in carbon martensites. Tempering of the higher carbon martensite for 1 h at 160 °C produced further segregation of carbon to the region of twin interfaces. The matrix carbon content fell to 1.5 at. pct and the average carbon content over a 2 nm diam region at the interface rose to 8.7 at. pct. The width of the carbon segregated regions also increased, which seems to imply that incipient carbide precipitation in the plane of the twin boundaries is occurring at this stage of the tempering process. Formerly with the Department of Metallurgy and Science of Materials, University of Oxford     

Model-based interpretation of ERS-1 SAR images of Arctic sea ice

Interpretation of Synthetic Aperture Radar (SAR) images of sea ice is complex because of the natural variability of sea ice and sensor-induced effects, such as speckle. Most of the research on SAR image interpretation has focused on the winter months and algorithms were developed to classify sea ice successfully under cold conditions. However, interpretation of SAR images during the seasonal transitions has proved difficult due to rapidly changing weather conditions. In this paper we address the application of SAR during the transition from summer to the fall freeze-up. This period is important because it signals the start of significant new ice growth, which affects the air-ocean heat exchange and injects brine into the upper layers of the ocean. We have interpreted SAR images of the sea ice in terms of the basic ice characteristics by using shipborne radar measurements of sea ice during the freeze-up and models derived from these measurements. We have shown that the model-based approach is effective in interpreting SAR images during this seasonal transition. This work also provides the physical mechanisms responsible for the large increase in backscatter observed at the end of the summer melt season.     

Two calculations concerning the critical aluminium content in Fe20Cr5Al alloys

Alloys for high temperature applications rely on a protective oxide layer formed by selective oxidation. In Fe20Cr5Al type alloys the useful lifetime is governed by the depletion of aluminium by oxidation down to a critical aluminium content. Following spallation of the oxide scale the bare metal is exposed to air and catastrophic failure due to breakaway oxidation occurs if the aluminium content is too low. In this paper a model for the calculation of the critical aluminium content is presented. Based on Wagner's ideas on selective oxidation in ternary alloys, the critical aluminium content is calculated as that corresponding to the transition between external and internal oxidation. The resulting aluminium contents are temperature dependent and cover the range of values 0 to 3.5 wt.% reported in the literature. In the second part of the paper aluminium depletion profiles in Fe20Cr5Al plates have been calculated assuming a parabolic growth law for the oxidation process. The solution of the differential equation is an extension of the one dimensional solution presented by Whittle and coworkers for chromium depletion in FeCr sheet material, to three dimensions. Because of the increased consumption of aluminium at the corners of the sample, the critical aluminium content is first reached there. Based on the calculation, the reduction in lifetime, due to premature breakaway oxidation at the corners can be estimated.     

Downstream signals initiated in mast cells by Fc epsilon RI and other receptors

The significant contributions this past year to our understanding of IgE receptor (Fc epsilon RI) signaling in mast cells include studies with truncated Syk in a vaccinia expression system and Syk-negative variants of rat basophilic (RBL-2H3) cells. These studies demonstrate an essential role for Syk in initiating signals for secretion and release of arachidonic acid via phospholipase A2 and mitogen-activated protein kinase. A newly recognized addition to the repertoire of Fc epsilon RI-mediated signaling systems is the activation of sphingosine kinase, which contributes to calcium mobilization in mast cells. Advances have been made in our understanding of other receptors that regulate proliferation and differentiation of mast cells, and in our understanding of the ability of mast cells to mount acquired and acute responses to antigenic and bacterial challenge.     

Application of plane waves for accurate measurement of microwavescattering from geophysical surfaces

The authors utilized the concept of a compact antenna range to obtain plane-wave illumination to accurately measure scattering properties of simulated sea ice. They also made simultaneous measurements using conventional antennas. Measured scattering coefficients obtained with the plane-wave system at 10 GHz decreased by about 35 dB when the incidence angle increased from 0° to 10°. Scattering coefficients derived from data collected with the radar system at 13.5 GHz using conventional far-field antennas decreased by about 20 dB over the same angular region. This demonstrates that the far-field properties of a widebeam antenna are inadequate for measuring the angular scattering response of smooth surfaces. They believe that application of the compact antenna range concept for scattering measurements has a wide range of applications and is the solution to the long-standing problem of how to directly measure scattering consisting of coherent and incoherent components     

Sustained activation of phospholipase D via adenosine A3 receptors is associated with enhancement of antigen- and Ca(2+)-ionophore-induced secretion in a rat mast cell line

The adenosine analog, N-ethylcarboxamidoadenosine (NECA), causes transient activation of phospholipase C and an enhancement of antigen-induced secretion in a rat mast cell (RBL-2H3) line via adenosine A3-receptors (Ramkumar et al., J. Biol. Chem. 268:16887, 1993) by a mechanism that is inhibited by bacterial toxins and potentiated by dexamethasone (Ali et al., J. Biol. Chem. 265:745-753, 1990). Here we show that NECA synergizes the secretory response to Ca(2+)-ionophore as well as to antigen. The ability of NECA to synergize the secretory responses persisted for 10 to 20 min, long after the early phospholipase C-mediated reactions to NECA had subsided. NECA caused, however, a dose-dependent sustained activation of phospholipase D, as indicated by the formation of [3H]phosphatidic acid, or in the presence of 0.3% ethanol, [3H]phosphatidylethanol. This activation was associated with a sustained increase in diglycerides, in protein kinase C activity and in the phosphorylation of myosin light chains by protein kinase C. The generation of diglycerides was enhanced in dexamethasone-treated cells and suppressed in cells that had been treated with cholera toxin or pertussis toxin. Collectively, the studies suggested that the generation of diglycerides via phospholipase D and the associated activation of protein kinase C were, by themselves, insufficient signals for secretion in RBL-2H3 cells, but that these reactions synergized responses to stimulants such as antigen or A23187 that caused substantial increases in [Ca2+]i.     

Different isozymes of protein kinase C mediate feedback inhibition of phospholipase C and stimulatory signals for exocytosis in rat RBL-2H3 cells

Previous studies indicated that rat basophilic RBL-2H3 cells contained the Ca(2+)-dependent alpha and beta and the Ca(2+)-independent delta, epsilon, and zeta isoforms of protein kinase C (PKC); of these, PKC beta and delta were the most potent transducers of signals for exocytosis in antigen-stimulated permeabilized cells. Exocytosis, nevertheless, was still dependent on an elevated free Ca2+. (Ozawa, K., Szallasi, Z., Kazanietz, M. G., Blumberg, P. M., Mischak, H., Mushinski, J. F., and Beaven, M. A. (1993) J. Biol. Chem. 268, 1749-1756). We now demonstrate that PKC alpha and epsilon, exclusively, inhibit antigen-induced hydrolysis of inositol phospholipids in the same permeabilized RBL-2H3 cells. Unlike secretion, the inhibitory actions occurred at a basal concentration (0.1 microM) of free Ca2+. The inhibitory actions of the two isozymes were potentiated by 20 nM phorbol 12-myristate 13-acetate. As indicated by the effects of the phorbol ester, the probable mechanism was reduced tyrosine phosphorylation of phospholipase C gamma 1. The negative regulation of phospholipase C was apparent in intact cells, because the PKC inhibitor Ro31-7549 or down-regulation of PKC with phorbol ester enhanced antigen-induced hydrolysis of inositol phospholipids. The concentrations of the various isozymes of PKC in RBL-2H3 cells, as estimated by immunoblotting studies, were sufficient for promotion of exocytosis (i.e. beta and delta) and inhibition of phospholipid hydrolysis (i.e. alpha and epsilon).     

Stoichiometry Effects in TiAl and TiAlCr Alloys

Analytical electron microscopy methods have been used to establish correlatjons between lattice parameters and phase compositions in binary TiAl and ternary TiAlCr alloys based on Ti-48 at.-%Al.On traversing the stoichiometric composition in the binary TiAl system the lattice parameters show linear relationships with Al concentration suggesting antisite defects influence the structural parameters. The relationship between lattice parameters and phase composition in the ternary TiAl (Cr) phase is influenced by the site occupation behaviour of Cr in the TiAl lattice. Comparisons are made between" bulk" and" local" measurements for obtaining such information in complex two-phase alloys. Possible implications for the mechanical properties are briefly discussed.     

Carbide precipitation in certain alloys of the Co-Ni-Cr-C system

An investigation is reported of structural and hardness changes during the precipitation of Cr₂₃C₆ from f c c supersaturated solid solution in various alloys of the Co-Ni-Cr-C system containing 25 wt % Cr and 0.15 to 0.25 wt % C. The work extends results previously reported on a Co-25.3 wt % Cr-0.26 wt % C alloy, by studying the effect of adding nickel to replace cobalt (either wholly or completely) and hence changing the stacking fault energy. The addition of 10% nickel was found to increase the nucleation rate of matrix precipitation; precipitate particles also nucleated on partial dislocations with associated stacking fault formation. With approximately 55% nickel and 0.15% carbon, there was little matrix precipitation; instead precipitation occurred predominantly on dislocations, as rods growing along 1 1 0 directions; the main climb morphology was the formation of dislocation dipoles. Substantial precipitation hardening effects were obtained, particularly in the cobalt-rich alloys with 0.25% carbon. In a ternary Ni-25 wt % Cr-0.25 wt % C alloy, a non-uniform precipitate dispersion formed involving nucleation in the matrix and on dislocations. An investigation was also made of the effect of prior strain (1 to 10%) on the ageing of the Co-25.3 wt % Cr-0.26 wt % C alloy. Deformation of the f c c solution-treated material produced faulting and also the formation of h c p phase. On ageing, Cr₂₃C₆ precipitation occurred within the lamellae; at long ageing times after 10% deformation carbide particle coarsening, and matrix recrystallization occurred concurrently, and the recrystallization was accompanied by the transformation of the f c c matrix to h c p phase.