对位取代酚钾与10′10′-二烃基-9,9′-联二吖啶盐电荷转移光谱的研究

对位取代酚钾与１０′１０′－二烃基－９，９′－联二啶盐电荷转移光谱的研究宋化灿＊＊英柏宁郑祥礼（中山大学化学系，广州５１０２７５）关键词硝酸１０，１０′－二烃基－９，９′－联二啶盐，对位取代酚钾，电荷转移络合物，电子亲合能１０，１０′－二烃基－９，９...     

宽频带油纸绝缘介电响应的全过程谱图提取和定量分析

为深入而全面地解释油纸绝缘材料在宽频带内介电响应的微观机理,基于普适弛豫定律和凝聚态物理经典理论,利用响应谱图受温度影响的频移特性,通过势垒能级这一本征参量建立油纸绝缘材料频域介电谱与热刺激电流曲线在表征同类介电过程时的联系,并进一步以复介电常数实部与虚部关联关系和复介电常数一阶偏微分方程的数据处理手段,形成具有可靠理论依据的宽频带介电过程微观机理综合分析新方法。基于此,依次在宽频带内提取和观察了电荷的各类运动过程。分析结果表明,在较宽温度范围内,油纸绝缘材料的频域介电谱曲线从低频到高频依次包括低频弥散、交流电导和电极极化、界面极化及偶极子转向极化等独立介电过程,并根据相关理论模型和试验数据对上述各独立过程进行定量研究,确定其微观物理机制、频谱函数和发生条件。该研究揭示了油纸绝缘材料在全频域范围的电荷运动规律,为频域介电谱法应用于电力设备绝缘评估提供了新的理论分析思路。     

A Dilute Fluorinated Phosphate Electrolyte Enables 4.9 V-Class Potassium Ion Full Batteries

Potassium ion batteries using graphite anode and high-voltage cathodes are considered to be optimizing candidates for large-scale energy storage. However, the lack of suitable electrolytes significantly hinders the development of high-voltage potassium ion batteries. Herein, a dilute (0.8 m ) fluorinated phosphate electrolyte is proposed, which exhibits extraordinary compatibility with both graphite anode and high-voltage cathodes. The phosphate solvent, tris(2,2,2-trifluoroethyl) phosphate (TFP), has weak solvating ability, which not only allows the formation of robust anion-derived solid electrolyte interphase on graphite anode but also effectively suppresses the corrosion of Al current collector at high voltage. Meanwhile, the high oxidative stability of fluorinated TFP solvent enables stable ultrahigh-voltage (4.95 V) cycling of a potassium vanadium fluorophosphate (KVPO₄F) cathode. Using TFP-based electrolyte, the 4.9 V-class potassium ion full cell based on graphite anode and KVPO₄F cathode shows rather remarkable cycling performance with a high capacity retention of 87.2% after 200 cycles. This study provides a route to develop dilute electrolytes for high-voltage potassium ion batteries, by utilizing solvents with both weak solvating ability and high oxidative stability.     

张家界市建筑形象建设规划浅探

张家界是我国著名的风景旅游度假城市，当前，围绕转型提质，张家界正加快推进相关基础设施建设。在这一过程中，一度由于缺乏总体规划而出现建筑形象的杂驳失衡，对城市形象造成了负面影响。本文将以打造山水景观旅游度假城市为标准，对张家界城市建筑的形象与风格进行粗浅的规划研究。     

An integrated technology CAD system for process and devicedesigners

A workstation-based integrated system with a highly interactive X/Motif user interface is discussed. At present, TSUPREM3, TSUPREM4 and TPISCES have been integrated into this system. The components of the integrated TCAD system include a generic process recipe editor, a mask editor, a 2-D wafer structure builder (using 1-D/2-D process simulation profiles), a mesh generator for 2-D device simulation, a device simulation recipe editor, and graphical postprocessors for both process and device analysis. The user of this system inputs the specification of a process recipe and the layout of the device structure to be fabricated. The system then runs process and device simulation using incremental and shared simulation strategies to generate wafer structure and electrical device characteristics. An interactive user interface guides the user through the process and device simulation flow. thereby aiding what-if analysis of process and device tradeoffs     

后世博时代的建筑创作

2010年上海世博会已圆满落幕,中国迎来了＂后世博＂时代的挑战,而中国的建筑设计在经历了2008年奥运建筑思潮的冲击之后,将再一次接受世博创意建筑浪潮的洗礼。     

Rapid characterization and modeling of pattern-dependent variationin chemical-mechanical polishing

Pattern-dependent effects are a key concern in chemical-mechanical polishing (CMP) processes. In oxide CMP, variation in the interlevel dielectric (ILD) thickness across each die and across the wafer can impact circuit performance and reduce yield. In this work, we present new test mask designs and associated measurement and analysis methods to efficiently characterize and model polishing behavior as a function of layout pattern factors-specifically area, pattern density, pitch, and perimeter/area effects. An important goal of this approach is rapid learning which requires rapid data collection. While the masks are applicable to a variety of CMP applications including back-end, shallow-trench, or damascene processes, in this study we focus on a typical interconnect oxide planarization process, and compare the pattern-dependent variation models for two different polishing pads. For the process and pads considered, we find that pattern density is a strongly dominant factor, while structure area, pitch, and perimeter/area (aspect ratio) play only a minor role     

后处理设施放射性液体贮罐泄漏事故环境释放源项估算

放射性液体泄漏事故是后处理设施典型的事故,泄漏事故通常发生在设备室。高放废液贮槽泄漏后气载放射性核素生成包括两个过程:一是在泄漏放射性液体的过程中惰性气体从溶液中释放,以及与空气、地板相互作用产生的气溶胶;二是泄漏后的蒸发过程(包括冲洗前稀释前和稀释后)。气溶胶在设备室内生成后会发生沉积,同时随着设备室排风系统,经过滤后向环境排放。本文给出了一种放射性溶液贮槽泄漏事故源项估算方法,实现了事故泄漏质量、泄漏活度、设备室气载放射性活度浓度及积分浓度、环境释放源项估算,为事故应急决策和响应行动提供数据支持。     

基于正交试验的梭心冷挤压成形工艺研究及模具优化设计

为提高模具寿命,降低试模成本,文章对缝纫机梭心的冷挤压成形工艺和模具的设计优化进行了研究。为解决其传统工艺中端面不平的问题,设计了带有限流套的新模具结构;根据梭心的结构特点,提出了2种梭心冷挤压成形工艺方案,利用DEFORM-3D有限元模拟软件对工艺方案分别进行数值模拟,发现采用2个工步的成形方案模拟出的挤压件成形效果好;基于正交试验采用方差分析法和极差分析法共同分析,以成形载荷及其凸模磨损量的大小作为评判指标,获得最佳工艺参数组合;采用最佳的参数组合来探寻不同摩擦因数对成形载荷的影响、不同凸模初始硬度对凸模磨损量影响规律;通过优化后挤压件的损伤因子云图、等效应变云图以及折叠角云图分析,验证了优化模具的可行性。该研究对梭心零件的实际生产及其相似零件的生产提供了参考。     

退役汽车保险杠的同级回收利用

针对退役汽车保险杠塑料回收利用问题,提出了塑料喷丸表面除漆与回收料改性再生的技术方法。通过有限元仿真和实际除漆实验研究了保险杠表面塑料喷丸除漆的过程,仿真与实际实验结果说明了在80 m/s的垂直喷丸速度下,可以有效去除保险杠表面油漆,并且基体材料不受到破坏。在保险杠除漆回收料中添加聚丙烯(PP)新料、纳米蒙脱土(nano-MMT)、PP接枝马来酸酐(PP-g-MAH),通过双螺杆挤出机制备改性保险杠回收料,并测试了其拉伸与弯曲性能、缺口冲击强度、洛氏硬度和熔体流动速率,发现在除漆回收料/PP新料/nano-MMT/PP-g-MAH质量比为7/3/1/1的改性再生配方下,改性回收料的各项性能基本达到同级利用的标准要求,退役汽车保险杠材料的价值利用梯度得到提高。