The article investigates the finite sample properties of estimators for spatial autoregressive models where the disturbance
terms may follow a spatial autoregressive process. In particular we investigate the finite sample behavior of the feasible
generalized spatial two-stage least squares (FGS2SLS) estimator introduced by Kelejian and Prucha (1998), the maximum likelihood
(ML) estimator, as well as that of several other estimators. We find that the FGS2SLS estimator is virtually as efficient
as the ML estimator. This is important because the ML estimator is computationally burdensome, and may even be forbidding
in large samples, while the FGS2SLS estimator remains computationally feasible in large samples.
Received: 20 January 2001 / Accepted: 31 August 2001 相似文献
A simple practical equivalent continuum numerical model for simulating the behavior of jointed rock mass has been extended to three-dimensional using FLAC3D. This model estimates the properties of jointed rock mass from the properties of intact rock and a joint factor (Jf), which is the integration of the properties of joints to take care of the effects of frequency, orientation, and strength of joint. A new FISH function has been written in FLAC3D specifically for modeling jointed rocks using the Duncan and Chang hyperbolic model. This model has been validated first with simple element tests at different confining pressures for different rocks with different joint configurations. Explicit modeling of the joints has also been done in element tests and results obtained compare well with the results of equivalent continuum model and also with experimental results. Further, this has been applied for a case study of a large underground power house cavern in the Himalayas. The analysis has been done under various stages of excavation, assigning a null model available in FLAC3D for simulating the excavation. 相似文献
A tricyclazole selective chitosan/Fe3O4 magnetic molecularly imprinted polymer (MMIP) was synthesized using non-covalent binding polymerization involving methacrylic acid (MAA) as functional monomer, divinylbenzene (DVB-80) as crosslinker, 2,2'-azobisisobutyronitrile as initiator, acetonitrile/toluene (75:25, v/v) as porogenic solvent and tricyclazole as template. Surface morphology and magnetic characterization of the prepared imprinted and non-imprinted polymers were done using scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectrometry and vibrating sample magnetometry, respectively. The adsorption kinetic data fitted best in pseudo-second-order model. The adsorption equilibrium was achieved in 30 min and the maximum binding capacity was 4579.9 µg/g. The Freundlich isotherm model was found suitable for explaining the binding isotherm data (R2 > 0.99). Negative values of thermodynamic parameters ∆G (Gibb’s free energy), ∆H (enthalpy), and ∆S (entropy) revealed exothermic and spontaneous nature of adsorption processes. It also revealed decreased randomness at the solid–liquid interface during sorption. The scatchard plot analysis suggested heterogeneity of binding sites on MMIPs. The molecular recognition selectivity of MMIPs towards tricyclazole was much higher, as compared to its structural analogues, tebuconazole (α = 28.58) and hexaconazole (α = 37.16). The MMIPs were successfully applied to separate and enrich tricyclazole from fortified samples of rice and water, with a recovery percentage of 89.4% and 90.9%, respectively. These reusable imprinted polymers possessing high selectivity and specificity can be utilized as an adsorbent for solid-phase extraction in sample preparation for tricyclazole residue analysis in complex environmental matrices.
The quantum-dot cellular automata (QCA) is considered to be one of the ground-breaking nanotechnologies developed over the last two decades. A layered T (LT) logic cell library is constructed herein, and the methodology is extended to generic adder and subtractor module designs. The two proposed algorithms lead to more efficient QCA layout designs for an n-bit ripple carry adder (RCA) and subtractor based on an effective clock zone assignment approach. The suggested one-, four-, and eight-bit RCAs and subtractors surpass most of their existing counterparts by offering lower effective area and cell complexity. A comparative analysis is presented regarding the complexity, irreversible power dissipation, and Costα of the proposed n-bit layouts from a cost estimation purview.
Part and attribute based representations are widely used to support high-level search and retrieval applications. However, learning computer vision models for automatically extracting these from images requires significant effort in the form of part and attribute labels and annotations. We propose an annotation framework based on comparisons between pairs of instances within a set, which aims to reduce the overhead in manually specifying the set of part and attribute labels. Our comparisons are based on intuitive properties such as correspondences and differences, which are applicable to a wide range of categories. Moreover, they require few category specific instructions and lead to simple annotation interfaces compared to traditional approaches. On a number of visual categories we show that our framework can use noisy annotations collected via “crowdsourcing” to discover semantic parts useful for detection and parsing, as well as attributes suitable for fine-grained recognition. 相似文献
Estimation of reliability and the number of faults present in software in its early development phase, i.e., requirement analysis or design phase is very beneficial for developing reliable software with optimal cost. Software reliability prediction in early phase of development is highly desirable to the stake holders, software developers, managers and end users. Since, the failure data are unavailable in early phase of software development, different reliability relevant software metrics and similar project data are used to develop models for early software fault prediction. The proposed model uses the linguistic values of software metrics in fuzzy inference system to predict the total number of faults present in software in its requirement analysis phase. Considering specific target reliability, weightage of each input software metrics and size of software, an algorithm has been proposed here for developing general fuzzy rule base. For model validation of the proposed model, 20 real software project data have been used here. The linguistic values from four software metrics related to requirement analysis phase have been considered as model inputs. The performance of the proposed model has been compared with two existing early software fault prediction models. 相似文献
Purpose: To develop and optimize nanoemulsion (NE)-based emulgel (EG) formulation as a potential vehicle for topical delivery of tea tree oil (TTO).Methodology: Central composite design was adopted for optimizing the processing conditions for NE preparation by high energy emulsification method viz. surfactant concentration, co-surfactant concentration, and stirring speed. The optimized NE was developed into emulgel (EG) using pH sensitive polymer Carbopol 940 and triethanolamine as alkalizer. The prepared EG was evaluated for its pH, viscosity, and texture parameters, ex vivo permeation at 37?°C and stability. Antimicrobial evaluation of EG in comparison to conventional gel and pure TTO was also carried out against selected microbial strains.Results and discussion: Optimized NE had particle size and zeta potential of 16.23?±?0.411?nm and 36.11?±?1.234?mV, respectively. TEM analysis revealed the spherical shape of droplets. The pH of EG (5.57?±?0.05?) was found to be in accordance with the range of human skin pH. EG also illustrated efficient permeation (79.58?μL/cm2) and flux value (JSS) of 7.96?μL cm2/h through skin in 10?h. Viscosity and texture parameters, firmness (9.3?±?0.08?g), spreadability (2.26?±?0.06?mJ), extrudability (61.6?±?0.05?mJ), and adhesiveness (8.66?±?0.08?g) depict its suitability for topical application. Antimicrobial evaluation of EG with same amount of TTO as conventional gel revealed broader zones of growth inhibitions against all the selected microbial strains. Moreover, EG was also found to be nonirritant (PII 0.0833). These parameters were consistent over 90 d.Conclusion: TTO EG turned out to be a promising vehicle for the topical delivery of TTO with enhanced therapeutic efficacy. 相似文献