Fabrication of direct Z-scheme FeIn2S4/Bi2WO6 hierarchical heterostructures with enhanced photocatalytic activity for tetracycline hydrochloride photodagradation

A series of direct Z-scheme FeIn₂S₄/Bi₂WO₆ hierarchical heterostructures with intimate interface contacts were synthesized by in-situ growth route and characterized by systematical analyses. All as-prepared FeIn₂S₄/Bi₂WO₆ nanocomposites showed significantly enhanced photocatalytic activity towards photodegradation for the removal of tetracycline hydrochloride (TCH) in comparison with individual FeIn₂S₄ and Bi₂WO₆. Meanwhile, the highest photocatalytic degradation activity can be achieved by modulating adding amount of FeIn₂S₄ in FeIn₂S₄/Bi₂WO₆ nanocomposites and the optimized component ratio of FeIn₂S₄ to Bi₂WO₆ is determined to be 10 wt%. The enhanced photocatalytic activity could be ascribed to efficient separation between photogenerated holes and electrons based on the construction of direct Z-scheme system. The high photocatalytic stability of resultant 10 wt% FeIn₂S₄/Bi₂WO₆ nanocomposites was revealed through six successive recycling reactions. The main intermediate generated during TCH photodegradation was explored by HPLC-MS. Besides, the direct Z-scheme photocatalytic mechanism was confirmed by band position analysis, electron spin resonance (ESR) and active species capture experiment.     

深孔薄壁件挤压模CAD系统

介绍了利用ActiveXAutomation技术，以VB为开发工具，并采用参数化绘图研究开发的深孔薄壁件挤压模CAD系统。     

Design consideration of photocatalytic oxidation reactors using TiO2-coated foam nickels for degrading indoor gaseous formaldehyde

In the design process of the photocatalytic oxidation (PCO) reactor using TiO₂-coated foam nickels, the optimum of catalyst film thickness, light intensity and flow velocity were considered. A model was developed to study the effect of catalyst film thickness on photocatalytic degradation of formaldehyde by a TiO₂-coated foam nickel at continuous flow mode. In this model, external mass transfer and internal molecule diffusion-reaction were considered. A first-order kinetics equation was used to account for the photocatalytic reaction. Two exponential equations were employed to describe the distribution of light intensities in foam nickels and catalyst films, respectively. Validated with experimental data, the model can be used to predict the optimal thickness of catalyst films. A method for determining appropriate light intensities was proposed and discussed. The appropriate light intensity can be obtained by giving a margin, regarded as an excess coefficient, to the light intensity calculated based on the assumption of complete use of excited electron–hole pairs. The excess coefficient needs to be determined experimentally. In addition, the optimal flow velocity of PCO reactors could be consistent with the required one by changing the windward area of foam nickels. Based on the theoretical analyses, a novel PCO reactor containing 15 parallel-connected cells was designed. Each reaction cell was composed of an UV lamp and a TiO₂-coated tubular foam nickel. The performance of the reactor was tested by degrading gaseous formaldehyde at an indoor concentration level. The results showed that the reactor had low pressure loss and good degradation capability.     

超临界水中氧化钙催化泥炭制氢

使用间歇式超临界水反应器,以氧化钙作为催化剂和CO_2化学固定剂,详细考察了Ca/C摩尔比、反应温度、停留时间、压力等条件对泥炭在超临界水中转化制氢的影响。在873 K,Ca/C比为0.61时,CO_2几乎被完全固定,在气相产物中只有氢气、甲烷和低碳烃,碳转化率由未添加CaO时的66.6％提高到82.4％,氢气的产率由2.2 mmol·g~(-1)提高到6.9 mmol·g~(-1)。当反应温度由773 K提高到923 K时,泥炭的裂解反应加剧,气体产物的收率由5.5 mmol·g~(-1)提高到19.5 mmol·g~(-1),但是氢气所占比例由55.4％下降到34.8％。与温度相比,压力和在终温停留时间的影响相对较小。     

汽车NVH控制橡胶减震元件行业的现状与发展

汽车的NVH(Noise,Vibration and Harshness,即噪声、振动和不平顺性)特性是汽车的五大性能指标之一(另外四个性能指标为:安全性、经济性、环保性和可靠性)。汽车的NVH控制是通过控制汽车中有关     

基于对角回归神经网络的电动加载系统

在电动加载系统中，多余力干扰和其他非线性因素影响力矩跟踪精度，传统的控制器控制效果不是很理想。本文建立电动加载系统模型，分析多余力的产生机理，提出了基于对角回归神经网络补偿控制，其计算量小。通过仿真实验，电动加载系统有效的减少了多余力等的影响。     

石油化工废水处理链条式刮油刮泥机结构改造

针对目前石油化工厂常见的刮油刮泥机在结构上存在的不足,对传统刮泥机进行了系统的结构改造设计,主要改造设计包括传动链轮与链条、刮板、导向装置、导轨以及相应的监测装置,提高了整个刮泥机结构强度和技术水平,延长了设备的使用周期,降低了装置的运行费用。     

Reprocessing the MODIS Leaf Area Index products for land surface and climate modelling

Land surface and climate modelling requires continuous and consistent Leaf Area Index (LAI). High spatiotemporal resolution and long-time record data are more in demand nowadays and will continue to be in the future. MODIS LAI products meet these requirements to some degree. However, due to the presence of cloud and seasonal snow cover, the instrument problems and the uncertainties of retrieval algorithm, the current MODIS LAI products are spatially and temporally discontinuous and inconsistent, which limits their application in land surface and climate modelling. To improve the MODIS LAI products on a global scale, we considered the characteristics of the MODIS LAI data and made the best use of quality control (QC) information, and developed an integrated two-step method to derive the improved MODIS LAI products effectively and efficiently on a global scale. First, we used the modified temporal spatial filter (mTSF) method taking advantage of background values and QC information at each pixel to do a simple data assimilation for relatively low quality data. Then we applied the post processing-TIMESAT (A software package to analyze time-series of satellite sensor data) Savitzky-Golay (SG) filter to get the final result. We implemented the method to 10 years of the MODIS Collection 5 LAI data. In comparison with the LAI reference maps and the MODIS LAI data, our results showed that the improved MODIS LAI data are closer to the LAI reference maps in magnitude and also more continuous and consistent in both time-series and spatial domains. In addition, simple statistics were used to evaluate the differences between the MODIS LAI and the improved MODIS LAI.     

数字信号量化处理极值方法解析

信号非均匀量化最优化处理过程,是解析数字信号最大信噪比的关键,本文根据数字信号量化具体约束条件要求,利用线性空间泛函极值、变分等方法验证其求解过程。