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排序方式: 共有815条查询结果,搜索用时 31 毫秒
1.
Ezequiel R. Soulé Guillermo E. Eliçabe Roberto J. J. Williams 《Polymer Bulletin》2008,60(2-3):417-423
An unexpected experimental finding is reported where the primary morphology developed during polymerization-induced
phase separation in a rubber-modified thermoplastic practically disappears at high conversions. This process
was evidenced by light scattering (LS) and scanning electron microscopy (SEM) for a particular composition
of solutions of polyisobutylene oligomers (PIB) in isobornylmethacrylate (IBoMA), during the free-radical
polymerization of the monomer. The primary phase separation produced a dispersion of domains rich in PIB
containing significant amounts of the monomer (IBoMA). Polymerization of the monomer in these domains occurred
at high overall conversions producing the filling of dispersed domains with a PIBoMA-PIB blend that could
not be distinguished from the matrix. Under these conditions the final material had the appearance of a
homogeneous blend. 相似文献
2.
This article reviews the application of a coupled squeeze flow and intermolecular diffusion model, which was used to predict the quality and size of microwelds in plastics. Weld widths predictions were compared with previously presented experimental results using moving heat source models and temperature fields. The motivation for this work was to develop and verify a model based on fundamental principles that could accurately predict weld size and strength for conventional plastic welding techniques as well as novel techniques such as laser microwelding. It is envisioned that the resulting model could be used to predict proper welding parameters, including laser power and travel speed, to produce welds of varying size. Although insight into weld quality can be derived from this model, it was not the goal of this work to accurately predict weld strength for laser microwelding because of the difficulty in measuring weld strength on the micron scale. However, as reported in Part 1, weld strength for impulse welds were accurately predicted. In this model it was found that variable temperature histories, rather than a single value of maximum weld temperature, allows more accurate modeling of the welding process. In this work (Part 2), microwelds as small as 11 μm in width were produced with transmission infrared welding. In addition, welds over 150‐μm wide were also generated and the model was able to predict the range of weld widths that were found experimentally. It was found that the predictions were in very good agreement with the experimental results. There was some deviation between the experimental data and the model at the extreme parameters and it is believed that this was due to the temperature‐dependent material properties as well as optical aberrations. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers 相似文献
3.
Robert R. Gillies Jayne Brim Box Jürgen Symanzik Eli J. Rodemaker 《Remote sensing of environment》2003,86(3):411-422
Impervious surface area (ISA) was derived for a period from 1979 to 1997 from Landsat MSS and TM data for the Line Creek watershed that lies to the south of the city of Atlanta, GA. The change in ISA is presented as an ecological indicator to examine the cumulative water resource impacts on mussel population in three sub-watersheds of Line Creek—namely, Line, Flat, and Whitewater creeks. The satellite analysis shows that ISA expansion occurred substantially from 1987 to 1997 and is predominantly in industrial, commercial, and shopping center (ICS) complexes but also in smaller lot-size residential development. Evidence of mussel habitat degradation is indicated and loss of species (in the region of 50 to 70%) is present in areas where ISA expansion is observed—specifically in ICS complex development in and around Peachtree City that drains directly into the Line and Flat creeks. This is in marked contrast to Whitewater Creek where overall development of ISA is less and no major loss of mussel species is observed. 相似文献
4.
OBJECTIVE: To investigate the efficacy of the rectus abdominis muscle flap (RAMF) technique for the closure and augmentation of small, non-compliant bladder exstrophies. PATIENTS AND METHODS: The RAMF technique was used in two girls and two boys (mean age at operation, 31.7 months, range 3-72) with bladder exstrophy. The clinical outcome and urodynamics were assessed during a follow-up of 29 months to 6 years (mean 49.2 months) and included imaging, cystoscopy, biochemical and microbiological studies. RESULTS: There were no urinary tract infections, metabolic problems or electrolyte disturbances and kidney function remained normal in all patients. Radiography confirmed intact function and anatomy of the urinary tract and cystoscopy showed complete coverage of the inner peritoneal layer of RAMF with uroepithelium. No stone formation or mucus production were detected. Currently, three patients void using clean intermittent catheterization through the native urethra and the fourth through an appendiceal Mitrofanoff valve. However, the bladder volume was insufficient at the late follow-up and three patients required bladder augmentation. CONCLUSIONS: The RAMF technique is a good alternative for closing bladder exstrophies and achieves an increase in bladder capacity; however, although there is a mild improvement in bladder capacity and compliance. RAMF should not be used as a bladder augmentation procedure. The technique is indicated in the closure of large bladder defects, bladder exstrophies with small, inelastic, non-compliant bladder remnants and failed primary closures. 相似文献
5.
D Ben-Yehuda S Krichevsky EA Rachmilewitz A Avraham GA Palumbo F Frassoni D Sahar H Rosenbaum O Paltiel M Zion Y Ben-Neriah 《Canadian Metallurgical Quarterly》1997,90(12):4918-4923
We previously reported that the abl promoter (Pa) undergoes de novo DNA methylation in the course of chronic myelocytic leukemia (CML). The clinical implications of this finding are the subject of the present study in which samples of CML patients, including a group treated with interferon alpha (IFNalpha) were surveyed. The methylation status of the abl promoter was monitored by polymerase chain reaction (PCR) amplification of the Pa region after digestion with several site-methylation sensitive restriction enzymes. Some 74% of the DNA samples from blood and marrow drawn in the chronic phase were nonmethylated, similar to control samples from non-CML patients. The remaining 26% were partially methylated in the abl Pa region. The latter samples were derived from patients who were indistinguishable from the others on the basis of clinical presentation. Methylated samples were mostly derived from patients known to have a disease of longer duration (26 months v 7.5 months, P = .01). Samples of 30 IFNalpha-treated patients were sequentially analyzed in the course of treatment. Fifteen patients with no evidence of Pa methylation before treatment remained methylation-free. The remainder, who displayed Pa methylation before treatment, reverted to the methylation-free status. The outcome is attributed to IFNalpha therapy, as the Pa methylation status was not reversed in any of the patients treated with hydroxyurea. Methylation of the abl promoter indicates a disease of long-standing, most likely associated with a higher probability of imminent blastic transformation. It appears to predict the outcome of IFNalpha therapy far better than the cytogenetic response. 相似文献
6.
Minor Thomas R.; Dess Nancy K.; Ben-David Eli; Chang Wei-Chao 《Canadian Metallurgical Quarterly》1994,20(4):402
The present study determined whether individual differences in neophobia during an open-field pretest predict vulnerability to inescapable electric shock, as measured by 2 tests of learned helplessness in rats. Shuttle-escape latencies and saccharin finickiness increased across groups that had received increasing numbers of inescapable shocks 24 hr earlier. Dispersion in the test measure as well as the percentage of variance explained by pretest neophobia were greater when no or few shocks were delivered in the interpolated stress phase. Pretest neophobia was positively related to stress vulnerability in both tests under these conditions. Further increments in stressor severity overwhelmed even the most stress-resistant rats, thereby decreasing dispersion in the test measure and eliminating the predictive value of pretest neophobia. This pattern of outcomes was more robust for the shuttle-escape measure of helplessness. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
7.
A series of poly(vinyl chloride) (PVC)/polyaniline (PANI) blends plasticized and protonated simulataneously by bis(2-ethylhexyl) hydrogen phosphate, bis(4-nitrophenyl) phosphate, diphenyl phosphate, or dibenzyl phosphate was prepared by a mass homogenization technique. Thermal analysis studies by means of thermo-gravimetric analysis (TGA) and differential scanning calorimetry (DSC) revealed that PVC/PANI blends with bis(2-ethylhexyl) hydrogen phosphate were characterized by the highest thermal stability values. Kinetic analysis of the decomposition process by the isoconversional Friedman method showed that the activation energy did not change substantially over the broad conversion range; further advanced kinetic analysis by a nonlinear regression method revealed that the kinetic function that was the best approximation for the experimental data was based on a reaction of nth order. 相似文献
8.
Analysis of advertisements in Israeli newspapers over the past decade has shown that American symbols have been widely used to market an array of consumer goods. Products made in America, Israel, or other countries are marketed with some sort of American angle by invoking America's values, symbols, landscapes, or lifestyle. Using both qualitative and quantitative methods, we analyzed how central components of the nation-state/national sphere—language, flag, political leaders, borders, landscapes, and sights—are reflected in advertising. We attempt to show how social values metamorphose, shedding their "Israeliness" and taking on an American veneer. Using Israel as an example may provide a test case for the Americanization process in other societies at the turn of the millennium. 相似文献
9.
Rattok Jack; Ross Barbara; Ben-Yishay Yehuda; Ezrachi Ora; Silver Saralyn; Lakin Phyllis; Vakil Eli; Piasetsky Eugene; Zide Ellen; Diller Leonard 《Canadian Metallurgical Quarterly》1992,6(4):395
Within a clinical demonstration program, 59 traumatically brain-injured patients were treated with 1 of 3 mixes of treatment. Mix 1 included cognitive remediation (CGR), small-group interpersonal (SGI) communication training, therapeutic community activities, and personal counseling. Mix 2 was similar to Mix 1 but stressed SGI exercises and eliminated CGR. Mix 3 emphasized CGR and eliminated SGI exercises. The efficacy of the treatment mixes was evaluated with performance on neuropsychological tests, improved independence in functional activities, measures of intra- and interpersonal functioning, and vocational outcome. Ss' participation in the program, irrespective of treatment mix, yielded improvements in (1) self-image, (2) quality of interpersonal relatedness and interaction, (3) involvement with others in naturalistic settings, and (4) vocational outcome. Overall, data point to the superiority of the balanced mix (Mix 1) over Mixes 2 and 3. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
10.
A new functional perturbation method (FPM) for calculating the probabilistic response of stochastically heterogeneous, linear elastic structures is developed. The method is based on treating the governing differential operator as well as the unknown displacement function as a functional of material modulus field. By executing a functional perturbation around the homogeneous case, a set of successive differential equations is obtained and solved, from which the average and variance of any local parameter (displacements, stresses, strains) can be found. For a linear problem, the equations to be solved in each approximation order differ from the one for the homogeneous case by a pseudo external loading (right hand side) part only. Thus, only the Green function for the homogeneous case is needed for an analytical solution of the corresponding heterogeneous problem. A one dimensional stochastically heterogeneous rod embedded in a uniform shear resistant elastic medium is solved as an example. The statistical variance of displacements and stresses are found analytically, including the edge regions. Morphological (grain size) and material (modulus) effects on the stochastic response are demonstrated. The above results are essential for estimating the stochastic features of local stress concentrations, which are the source for many strength-related macro properties of materials. Extensive usage of generalized functions (Dirac operator and its derivatives) is needed for the analysis. 相似文献