Synthesis of Co3O4 @ Organo/Polymeric Bentonite Structures as Environmental Photocatalysts and Antibacterial Agents for Enhanced Removal of Methyl Parathion and Pathogenic Bacteria

Two green nanocomposites of Co₃O₄ decorated CTAB/bentonite (Co@CT/BE) and chitosan/bentonite (Co@CH/BE) were synthesized as enhanced and environmental photocatalysts and antibacterial agents. As photocatalysts, the products were applied in the effective oxidation of toxic methyl parathion pesticide (MP) in wastewater under a visible light source. The application of Co@CH/BE (0.02 g) resulted in the complete oxidation of MP (50 mg/L) after 40 min and complete mineralization after 60 min. while the complete oxidation and mineralization of MP (50 mg/L) by Co@CT/BE was recognized after 75 min and 100 min, respectively. The Co@CH/BE composite is of higher activity than Co@CT/BE and can cause complete oxidation for MP at high concentrations up to 100 mg/L after 75 min. The oxidation pathway was illustrated considering the existence of the hydroxyl radicals as the active oxidizing species and the identified secondary organic compounds during the oxidation tests. The detected intermediate converted into end products of CO₂ and inorganic anions of SO₄^?2, NO₃^?, and PO₄^?3 at the final stages of the oxidation processes. As antibacterial agents, the two composites exhibit considerable inhabitation zones of about 20 mm against both the Gram-positive Staphylococcus aureus and Gram-negative bacterium Vibrio Sp. The synthetic Co@CH/BE showed the best antibacterial properties with 200 μg/mL as minimum inhibitory against Staphylococcus aureus.

     

Correction to: Synthesis of Co3O4 @ Organo/Polymeric Bentonite Structures as Environmental Photocatalysts and Antibacterial Agents for Enhanced Removal of Methyl Parathion and Pathogenic Bacteria

Journal of Inorganic and Organometallic Polymers and Materials -     

A subspace approach to adaptive narrow-band interferencesuppression in DSSS

We address the problem of suppression of a digital narrow-band interferer in direct-sequence spread spectrum (DSSS) communications. We focus on the adaptive suppression method proposed by Honig, Madhow and Verdti (see IEEE Trans. Inform. Theory, vol.41, p.944-960, 1995) for wide-band interference, applying it to a narrow-band interferer. We identify the eigenspaces of the system dynamics to analyze the convergence of the adaptive version of the minimum mean square error (MMSE) algorithm for this application. Using this subspace approach we are able to: (1) significantly decrease the convergence times via a new constraint on the step size in adaptation; (2) introduce a simple parameterization of the mean output energy (MOE) and signal-to-interference ratio (SIR) to compare performance of various receivers; and (3) identify modes of operation where the algorithm will cease to effectively cancel interference. We propose a new adaptive receiver that avoids the convergence anomalies identified, while capitalizing on the new step size for faster convergence. Simulation results to support theoretical results are presented     

The effect of type of atmospheric gas on milling behavior of nanostructured Ti6Al4V alloy

Recently fabrication of titanium alloys through solid state processes such as mechanical alloying has been greatly taken into consideration. In the present investigation the effects of common atmospheric impurities, oxygen and nitrogen, on the fabrication procedure and milling behavior of nanostructured Ti–6Al–4V alloy during mechanical alloying (MA) was studied. In this regards, elemental powders were milled under three different protective atmospheres of air, 90% and 99.998% pure Argon. Results indicated that, samples milled under Ar with 90% purity featured the best behavior and reached a nanostructure and subsequent amorphous state in shorter time periods. This was considered to be due to Ti lattice distortion made by interstitial element such as O₂ and N₂.     

Reliability analysis and inspection updating by stochastic response surface of fatigue cracks in mixed mode

The analysis of engineering structures under fatigue crack growth aims at ensuring an appropriate reliability level over the entire operational lifetime. This paper deals with a new approach, namely the Stochastic Response Surface, to couple finite element analysis and reliability methods. The stochastic collocation method provides an explicit expression of the limit state function related to fatigue failure. This expression is used in first and second order reliability methods in order to compute the failure probability at a given structural age. When inspection is carried out, the structural reliability can be easily updated in terms of the observed crack length. Two numerical applications dealing with fatigue crack growth are presented to illustrate the proposed method, showing its performance in terms of numerical efficiency and accuracy.     

Phase Stability in Mechanically Alloyed Mg–Ni System Studied by Experiments and Thermodynamic Calculations

In this study, microstructural evolution of Mg–Ni alloy during mechanical alloying(MA) was investigated.Also, a thermodynamic approach was utilized to predict the most stable phases formed in Mg–Ni alloy after MA. The phase composition and microstructural properties of Mg–Ni alloy were assessed by X-ray diffractometry, high-resolution field emission scanning electron microscopy and high-resolution transmission electron microscopy. The results showed that ball milling of magnesium and nickel powder mixture for 70 h yields nanostructural Mg2Ni compound with an average grain size of ~20 nm. Thermodynamic calculations revealed that in the composition ranges of 0.0 \ XMg\ 0.03(at.%)and 0.97 \ XMg\ 1, there is no driving force for amorphous phase formation. In the composition range of 0.07 \ XMg\ 0.93, the change of Gibbs free energy for amorphous phase formation was more negative than solid solution.While for XMg= 0.66(nominal composition of Mg2Ni intermetallic phase), the change of Gibbs free energy for intermetallic phase was found to be more negative than both amorphous and solid solution phases indicating that Mg2Ni intermetallic compound is the most stable phase, in agreement with the experimental observations.     

LaCrO3/CuFe2O4 Composite-Coated Crofer 22 APU Stainless Steel Interconnect of Solid Oxide Fuel Cells

Metallurgical and Materials Transactions A - Rapidly rising contact resistance and cathode Cr poisoning are the major problems associated with unavoidable chromia scale growth on ferritic stainless...     

MgO single-crystal as an efficient thermal neutron filter

A formula is given which, for neutron energies in the range 10⁻⁴ < E < 10 eV, permits calculation of the nuclear capture, thermal diffuse and Bragg scattering cross-sections as a function of magnesium oxide (MgO) temperature and crystal parameters. Computer program has been developed to calculate the total neutron cross-section and transmission through mono-crystalline MgO. The calculated neutron transmission and effective attenuation coefficient values for MgO-single crystal at different temperatures are compared with measured ones. An overall agreement is indicated between the formula fits and experimental data. A feasibility study for the use of MgO-single crystal is discussed in terms of the optimum MgO-single crystal thickness, mosaic spread, temperature and cutting plane for efficient transmission of thermal-reactor neutrons, and also for rejection of the accompanying fast neutrons and gamma rays.     

Power up-grading study for the first Egyptian research reactor

In the present work, power up-grading study is performed, for the first Egyptian Research Reactor (ET-RR-1), using the present fuel basket with 4×4 fuel rods, (17.5 mm pitch), and a proposed fuel basket with 5×5 fuel rods, (14.0 mm pitch), without violating the thermal hydraulic safety criteria. These safety criteria are; fuel centerline temperature (fuel melting), clad surface temperature (surface boiling), outlet coolant temperature, and maximum heat flux (critical heat flux ratio). Different thermal reactor powers (2–10 MW) and different core coolant flow rates (450, 900, 1350 m³ h⁻¹) are considered. The thermal hydraulic analysis was performed using the subchannel code COBRA-IIIC for the estimation of temperatures, coolant velocities and critical heat flux. The neutronic calculations were performed using WIMS-D4 code with 5 — group neutron cross section library. These cross sections were adapted to use in the two-dimensional (2-D) diffusion code DIXY for core calculations. The study concluded that ET-RR-1 power can be upgraded safely up to 4 MW with the present 4×4-fuel basket and with the proposed 5×5-fuel basket up to 5 MW with the present coolant flow rate (900 m³ h⁻¹). With the two fuel arrays, the reactor power can be upgraded to 6 MW with coolant flow rate of 1350 m³ h⁻¹ without violating the safety criterion. It is also concluded that, loading the ET-RR-1 core with the proposed fuel basket (5×5) increases the excess reactivity of the reactor core than the present 4×4 fuel matrix with equal U-235 mass load and gave better fuel economy of fuel utilization.     

Candidate architectures for emerging IoV: a survey and comparative study

Intelligent Transportation System (ITS) is observing significant evolution in terms of technology and investment worldwide. This has given birth to the new concept of Internet of vehicles (IoV) as one of the leading applications of the Internet of Things. IoV aims to offer a better sharing of information and communication between vehicles, enabling higher cooperation for common interests. IoV is increasingly attracting the interest of a significant body of research. The e ort was mostly focused on solving various problems encountered in traditional VANETs, such as lack of coordination between vehicles, insufficient information, scalability, etc. Rapidly, IoV observed, particularly interesting advances taking advantage of exponential growth in communication and data analysis technologies. This includes cloud and/or fog computing, large data analytics, machine learning, and artificial intelligence. In this paper, we make a survey of the existing and recently proposed architecture solutions for IoV systems. Moreover, we define a list of criteria, features, and properties associated to the various architectures in order of making critical and insightful comparisons and assessments. Finally, we outline the key future research perspectives on the topic and define the key technical aspects that will help drive the future of IoV architectures.