Cellular polypropylene‐based piezoelectric films

Cellular polypropylene‐calcium carbonate based piezoelectric films were obtained using biaxial stretching and gas‐mediated inflation followed by a corona discharge treatment using home‐made devices. The obtained results revealed a cellular structure that develops at the interface between the solid particles and the polymer matrix and the final piezoelectric coefficient was found to depend both on the gas pressure profile and on time. The inflation step gives better results when the gas pressure is increased in stepwise manner allowing the gas to adequately intrude the cavities and maintain the required pressure. The overall results are discussed in terms of processing conditions and in terms of the developed microstructure. POLYM. ENG. SCI., 2012. © 2012 Society of Plastics Engineers     

Performance evaluation of the Over-The-Air activation procedure in a large scale LoRaWAN

LoRaWAN is a promising LPWAN technology for IoT connectivity. It offers long-range and wide-area communication at low-power, low cost and low data rate. LoRaWAN performance has been evaluated according to many features such as coverage, scalability, physical layer parameters, communication reliability and latency. Existing studies assume that the LoRaWAN end-devices are already connected to the LoRa NetServer. Therefore, the performance of LoRaWAN activation procedure has not been well investigated. In this work, we study the performance of LoRaWAN during the Over-The-Air activation procedure. This process enables a large number of end-devices to join the network before being able to exchange any kind of packets. Thus, we analyze the average activation delay and the average energy consumption for an end-device in a large scale LoRaWAN. To achieve this goal, we first implement the Over-The-Air activation procedure in ns-3, especially in the ’lorawan’ module and conduct extensive simulations. Then, we elaborate a mathematical model using Markov-chain to evaluate both the delay and the energy consumption analytically. Our study shows that in a LoRaWAN cell composed of 1000 end-devices, the average activation delay for an end-device is about 35 minutes and this activation requires an average of three join-packet transmissions and an average energy consumption of 0.0887J.

     

Effect of Pores on Mechanical Behavior. Application to a Composite Material

The effect of microscopic pores on the behavior of a ductile material during deformation are experimentally and numerically investigated taking into account the history of loading. The object of the investigation is a polyester-resin-based composite material with inclusions of glass beads. During moulding of these constituents, pores are left in the material because of the resin viscosity. The experimental technique used for the characterization of the effect of pores is a tensile test. Constitutive equations of poroelastoplasticity have been developed according to the micromechanical consideration. The material model developed by Gurson is extended to this composite material. Numerical results have been obtained and compared with the experimental ones.     

Coxiella burnetti infectious endocarditis. Apropos of a case

Chronic forms of Q fever (endocarditis) are rare, but are responsible for severe and desperately recurrent infections, resulting in multiple valve replacements with a reserved prognosis. The authors report the case of a 35-year-old patient with a known history of rheumatic fever, who developed blood culture negative infectious endocarditis on a mitral bioprosthesis. The diagnosis of Q fever was based on serological arguments. Despite long-term antibiotic therapy, serology remained strongly positive and was associated with repeated mitral valve disinsertion. The patient died immediately after the fourth operation in a context of haemodynamic failure. This clinical case emphasizes the importance of performing Q fever serology in any case of culture negative endocarditis and the therapeutic difficulties encountered in chronic recurrent endocarditis.     

Hypotension, hypoglycemia and hypouricemia recorded after repeated administration of aqueous leaf extract of Olea europaea L

This study is concerned by the determination of the toxicity of an Olea europaea L.aqueous leaf extract after repeated administrations. Female and male rats were given 37.5, 75, 150, 300, 600 and 1200 mg/Kg/24h of the extract for 60 days. The results show that the drug studied induces an increase of weight growth, an hypotension, an hypoglycaemia and an hypouricaemia in treated animals.     

Poly(lactic acid) plasticized with low‐molecular‐weight polyesters: structural,thermal and biodegradability features

Poly(lactic acid) (PLA) was plasticized with ester oligomers having different structure, molecular weight and carboxylic acid content as end‐functionalities. In particular PLA oligomers and a low‐molecular‐weight polyester of adipic acid and 1,2‐propanediol (an adipate‐based derivative) were used and compared. The plasticizing capability was tested and the final structural and thermal properties of PLA matrix were evaluated by correlating the various features to the chemical and physical characteristics of these additives. SEC, DSC, TGA, tensile tests, XRD and SEM results, even after annealing, were collected, and the related data analysed and evaluated with reference to additive starting properties. All the oligoesters were able to generate flexible compounds, but PLA oligomers provided mixtures with reduced structural and thermal stability. Finally, the best performing blend was tested for biodegradability to definitely assess the material suitability for the final application (sustainable packaging). © 2017 Society of Chemical Industry     

Mechanical,thermal, and rheological properties of graphene‐based polypropylene nanocomposites prepared by melt mixing

In this article, we describe the fabrication by melt mixing of graphene‐polypropylene nanocomposites and present the effect of graphene addition on some selected properties of polypropylene (PP). The graphene nanosheets (GNs) used as nano‐reinforcing agents were obtained through chemical reduction of graphene oxide by hydrazine hydrate. GNs were characterized and successfully dispersed into PP matrix to produce PP/GNs nanocomposites. The effects of GNs content on thermal, mechanical, and rheological properties were reported, and the obtained results were discussed in terms of morphology and state of dispersion and distribution of the GNs within the polymer matrix. Characterization by scanning electron microscopy and X‐ray diffraction of the nanocomposites has shown a relatively good dispersion of GNs in the polymer matrix, with the presence of only few aggregates. Increasing GNs content resulted in a significant increase in both mechanical and thermal properties with only few percent of GNs loading. Rheological behavior of the PP/GNs nanocomposites showed a Maxwellian‐like behavior for low GNs concentrations and a viscoelastic solid‐like behavior for GNs content exceeding the concentration of the percolation threshold. POLYM. COMPOS., 2012. © 2012 Society of Plastics Engineers