Novel Short-chain Crosslinked Cationomeric Polyurethanes

Summary Novel PUs containing pyridinium moieties were synthesized by chain extending isocyanate endcapped prepolymers with N, N’-bis (2-hydroxyethyl) isonicotinamide. The pyridinium moieties in the PUs were chemically crosslinked using short-chain divalent quaternising agents. The polyurethane cationomers were characterized by spectral, thermal and mechanical analysis. Spectral results confirmed the quaternisation of tertiary nitrogen leading to crosslinking. Compared to conventional PUs, the crosslinked PU networks exhibited improved thermal stability. The damping value (i.e.) tan δ for cationomers were improved over a broad temperature range when compared to conventional PU.     

Development of correlation between potassium hydroxide number and conductivity of concentrated natural rubber latex

Increase in the ion concentration in the medium was found to increase conductivity and potassium hydroxide number (KOH No) in natural rubber latex (NRL). Addition of long chain fatty acids can increase the ion concentration in the medium and stability of NRL. A series of concentrated natural rubber latex samples from three different areas with different soils and climatic conditions were tested for the parameters such as KOH No and conductivity. They have been measured over a period of 62 days, upon addition of soap to natural rubber latex concentrate. The result showed that there was a strong positive linear correlation between conductivity and KOH No. The regression equation to express the relationship between the variables has also been found. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Synchronised carrier-based SVPWM signal generation scheme for the entire modulation range extending up to six-step mode using the sampled amplitudes of reference phase voltages

The issues in synchronised implementation of space vector-based pulse width modulation (SVPWM) signal generation are addressed on a conventional DSP platform. With the present day digital signal processors (DSPs) with clock over 10 MHz, it is possible to include additional tasks for synchronisation in the interrupt service routine (ISR). Also, the task of the synchronisation can be easily accommodated within the same ISR without disturbing the time critical pulse width modulation (PWM) operation. The authors systematically present the additional software requirements to determine the time period proportional to the half carrier switching time interval that is required for the synchronisation. First, the DSP implementation of the conventional multi-level SVPWM based on the sampled amplitudes of reference voltages is presented and then the additional requirements to maintain the PWM in synchronisation are discussed. The simulation results as well as experimental results are presented for a five-level PWM signal generation. A five-level inverter configuration, using a 1.5 kW open-end winding induction motor drive, is used for experimentally verifying the SVPWM     

Saponification kinetic study of mica-acrylonitrile graft copolymers

Kinetics of alkaline hydrolysis of mica-acrylonitrile graft copolymers was studied. The dependence of alkali concentration and the time of hydrolysis on the degree of saponification was determined. Chemical and spectroscopical techniques were used to determine the mechanism of hydrolysis.     

Encrypted Network Traffic Classification and Resource Allocation with Deep Learning in Software Defined Network

Wireless Personal Communications - The climate has changed absolutely in every area in just a few years as digitized, making high-speed internet service a significant need in the future. Future...     

Polyurethane-polymethacrylic acid multi-block copolymers and their anionomers through “living” radical mechanism

Summary Polyurethane-polymethacrylic acid multi-block copolymers were synthesized from tetraphenylethane based polyurethane iniferter. Number of polymethacrylic acid blocks and molecular weight of block copolymers increased with increasing polymerization time which proves that the formation of block copolymers is through a living radical mechanism. The multi-block copolymers obtained were converted into their sodium anionomers. The multi-block copolymers and their anionomers have been characterized by FTIR, FTNMR and DSC analysis.     

Lignin valorization by forming toughened thermally stimulated shape memory copolymeric elastomers: Evaluation of different fractionated industrial lignins

Lignin‐based thermal responsive dual shape memory copolymeric elastomers were prepared with a highly branched prepolymer (HBP, A₂B₃ type) via a simple one‐pot bulk polycondensation reaction. The effect of fractionated lignin type (with good miscibility in the HBP) on copolymer properties was investigated. The thermal and mechanical properties of the copolymers were characterized by DMA, DSC, and TGA. Tensile properties were dominated by HBP <45% lignin content while lignin dominated >45% content. The copolymers glass transition temperature (T_g) increased with lignin content and lignin type did not play a significant role. Thermally stimulated dual shape memory effects (SME) of the copolymers were quantified by cyclic thermomechanical tests. All copolymers had shape fixity rate >95% and >90% shape recovery for all compositions. The copolymer shape memory transition temperature (T_trans) increased with lignin content and T_trans was 20°C higher than T_g. Lignin, a renewable resource, can be used as a netpoint segment in polymer systems with SME behavior. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41389.     

Dielectric relaxation of conductive carbon black reinforced ethylene‐octene copolymer vulcanizates

The dielectric relaxation behavior of different conducting carbon black‐filled ethylene‐octene copolymer (EOC) vulcanizates prepared by melt‐mixing method has been studied as a function of frequency (100 Hz–5 MHz) over a wide range of temperatures (25–100°C). The effect of filler loading and frequency on AC conductivity, dielectric permittivity, impedance, and dielectric loss tangent (tanδ) has been studied. The nature of variation of the dielectric permittivity with the filler loadings was explained on the basis of interfacial polarization of the filler in the polymer matrix. The effect of filler loading on the real and complex part of the impedance was explained by the relaxation dynamics of the polymer chains in the vicinity of the fillers. The effect of filler and temperature on dielectric loss tangent, dielectric permittivity, AC conductivity, and Nyquist plot was also reported. The bound rubber (BR) value increases with increase in filler loading suggesting the formation of strong interphase, which is correlated with dielectric loss. Thermal activation energy (E_a) was found to be decreasing with the temperature, which follows the Arrhenius relation: τ_b = τ₀ exp(−E_a/K_BT) where τ_b is the relaxation time for the bulk material. From the plot of lnτ_b versus inverse of absolute temperature (1/T), the activation energies (E_a) were found to be 0.37 and 0.44eV, respectively. The percolation threshold was observed with 40 phr carbon black loading. POLYM. COMPOS., 37:342–352, 2016. © 2014 Society of Plastics Engineers     

The Syntheses and Characterization of Interpenetrating Polymer Networks (IPNs) Derived from Cardanol-Based Dye and Linseed Oil-Based Polyurethanes

Interpenetrating Polymer Networks, from glycerol modified linseed oil polyurethanes and cardanol-based dyes, which are yet to be extensively studied were synthesized using benzoyl peroxide as initiator and ethylene glycol dimethacrylate as cross-linker. These polymers were characterized by Fourier transform infrared spectra, thermal analysis techniques such as thermogravimetric analysis, derivative thermogravimetry and differential thermal analysis. The kinetic parameters such as activation energy and orders of reaction were ascertained using Freeman-Carroll and Freeman-Anderson methods. The effects of changes in polyurethane to dye monomer weight ratio on the properties of such polymers were investigated at 1.2 and 1.6 NCO/OH ratios.     

酸化井产油量时间序列的混沌特征识别

现有的油气井产量预测方法以传统技术经济预测的惯性原理为基础。混沌理论的产生与发展对这种预测原理提出了挑战。目前有关酸化井产量变化混沌特征识别与预测的相关研究还鲜有公开报道。采用相空间重构和关联维数提取技术,对西部某油田一油井酸化后60 d的产油量时间序列研究发现,此井产油量时间序列的饱和嵌入维数和对应的吸引子维数分别为11和2.64,由此说明该井酸化后的生产系统动态演化规律为高维空间中的奇异吸引子,因而产油量变化表现出混沌特征;并且说明影响该井产油量变化的基本变量为3～11个。从而为单井生产系统动力学模型的建立,特别是人工神经网络预测模型的输入层节点数量的确定提供了定量的参考。