Growth kinetics of silver chloride precipitation in a Na2O-B2O3 glass investigated by means of small-angle X-ray scattering and transmission electron microscopy

The kinetics of silver chloride cluster formation in a sodium borate glass heat treated isothermally at different temperatures above the glass transition temperature has been studied with small-angle X-ray scattering (SAXS). It is established that the size distributions of particle number and particle volume have bimodal shapes, i.e. the system of AgCl droplets consists of two populations with significantly different mean radii. The bimodality of the size distribution functions is confirmed by results of transmission electron microscopy (TEM) even if different techniques of sample preparation are used. The resolution limits of the TEM techniques applied amount to 2 nm and are comparable with the smallest particle diameters detectable by the SAXS method. The evolution of the size distributions is discussed in the framework of the theories of nucleation, growth and Ostwald ripening.     

Human factors in order picking: a content analysis of the literature

Order picking (OP) is one of the most labour- and time-intensive processes in internal logistics. Over the last decades, researchers have developed various mathematical planning models that help to increase the efficiency of OP systems, for example, by optimising storage assignments or by specifying routes for the order pickers that minimise travel distance in the warehouse. Human characteristics that are often a major determinant of OP system performance have, however, widely been ignored in this stream of research. This paper systematically evaluates the literature on manual OP systems and conducts a content analysis to gain insights into how human factors (HF) have been considered and discussed in the scientific literature. The results of the analysis indicate that management-oriented efficiency criteria dominated prior research on OP, and that there is a clear lack of attention to HF in the design and management of OP systems. This poses an opportunity for research and design of manual OP systems.     

A New Access to Piperidino-cyclopiperidinecarboxamides – constrained analogues of a pharmaceutical used diaminic building block

6-Piperidino-3-azabicyclo[3.1.0]hexane-6-carboxamide diastereomers 1a and 2a represent conformationally rigid analogues of 3a which is a building block in some pharmaceutical compounds. A new access to these compounds 1a and 2a was found via the cleavage of bicyclic N,N-acetal 6 with hydrocyanic acid as the stereodetermining step. Reaction of derivatives 1a and 2a with bromodiphenyl-butyronitrile 14 gave cyclopiritramide isomers 1c and 2c , respectively. Qualitative preliminary investigations showed different affinities of 1c and 2c to the opiate-μ receptor. These results were discussed on the basis of an X-ray structural analysis of cyclopiritramide isomer 2c . 1-Benzylcyclopiperidine derivatives 1d and 2d were used as model systems for studying the conformation of cyclopiritramide isomer 1c and 2c , respectively.     

Spectral characterization of periglacial surfaces and geomorphological units in the Arctic Lena Delta using field spectrometry and remote sensing

Important environmental parameters in arctic periglacial landscapes (i.e. permafrost temperature, active-layer depth, soil moisture, precipitation, vegetation cover) will very likely change in a warming climate. The thawing of permafrost, especially, might cause massive landscape changes due to thermokarst and an enhanced release of greenhouse gasses from the large amounts of carbon stored in frozen deposits, resulting in positive climate-warming feedback. For the identification, mapping, and quantification of such changes on various scales up to the entire circum-Arctic, remote sensing and spatial data analysis are essential tools. In this study an extensive field-work dataset including spectral surface properties, vegetation, soils, and geomorphology was acquired in the largest Arctic delta formed by a single river, the Siberian Lena River Delta. A portable field spectrometer (ASD FieldSpec Pro FR®) was used for spectral surveys of terrain surfaces, and optical satellite data (Landsat Enhanced Thematic Mapper (ETM+), CHRIS-Proba) were used for the characterization, manual mapping, and automatic classification of typical periglacial land-cover units in the Lena Delta. Qualitative data from soils, vegetation, soil moisture, and relief units were correlated with the field-spectral data and catalogued for a wide variety of surface types. The wide range of micro- and meso-scale variations of periglacial surface features in the delta results in distinctive spectral characteristics for different land-cover units. The three main delta terraces could also be spectrally separated and characterized. The present dataset provides a basis for further spectral data acquisitions in the Lena Delta and for comparisons with periglacial surfaces from other regions.     

Netlib and NA-Net: Building a Scientific Computing Community

Two resources evolved in the early 1980s to serve the needs of the scientific computing community. These resources were Netlib, a software repository that facilitated distribution of public-domain software, and NA-Net, a file of analysts' contact information that eventually supported an online directory and newsletter digest. The authors who created Netlib and NA-Net explain the history of these resources and their continuing impact.     

Microstructure and optical properties of plasmapolymer thin films with embedded silver nanoparticles

Plasmapolymer thin films with embedded silver nanoparticles were deposited by simultaneous plasma polymerization and metal evaporation. The particle size and shape were determined by transmission electron microscopy (TEM) and analysed by optical image processing. The optical properties in the UV/ VIS/NIR spectral region were determined by the plasma resonance absorption of the silver particles. Transmittance spectra were calculated with the Bergman effective medium theory and compared with experimental spectra.     

Effective stress-based finite element error estimation for composite bodies

This paper presents a discretization error estimator for displacement-based finite element analysis applicable to multi-material bodies such as composites. The proposed method applies a specific stress continuity requirement across the intermaterial boundary consistent with physical principles. This approach estimates the discretization error by comparing the discontinuous finite element effective stress function with a smoothed (C⁰ continuous) effective stress function for non-intermaterial boundary elements with a smoothed pseudo-effective stress function for elements which lie on the intermaterial boundary. Examples are presented which illustrate the effectiveness of the multi-material error estimator. The pointwise pseudo-effective stress and the L₂ norm of the estimated stress error are seen to converge with mesh refinement, while Zienkiewicz and Zhu's error estimator failed to converge for elements on the intermaterial boundary due to the physically admissible stress discontinuities that exist on the intermaterial boundary.     

A feature based shape optimization technique for the configuration and parametric design of flat plates

A new feature based shape optimization technique is presented that is capable of modifying the topology (configuration) and shape to reduce the area of 2-D components based on the stress distribution in the component. Shape optimization attempts to maximize material usage to achieve a uniform stress distribution near the allowable limit of the material. Features can be added to the component, or can be modified, in order to optimize the material usage. By using features as a basis for shape modification, the problem of component connectivity can be handled in a consistent, intelligent manner, and the problem of smoothness is eliminated. A program was written to implement the optimization technique and was applied to two example problems, including one from the literature that used a different modification technique. The other example illustrates shape modification capabilities with more complicated geometry. Results from both examples are compared to results obtained using other topological modification techniques.