The impact of thermal conductivity and diffusion rates on water vapor transport through gas diffusion layers

Proper water management in a hydrogen-fueled polymer electrolyte membrane (PEM) fuel cell is critical for performance and durability. A mathematical model has been developed to elucidate the effect of thermal conductivity and water vapor diffusion coefficient in the gas diffusion layers (GDLs). The fraction of product water removed in the vapor phase through the GDL as a function of GDL properties/set of material and component parameters and operating conditions has been calculated. The current model enables identification of conditions wherein condensation occurs in each GDL component. The model predicts the temperature gradient across various components of a PEM fuel cell, providing insight into the overall mechanism of water transport in a given cell design. The water condensation conditions and transport mode in the GDL components depend on the combination of water vapor diffusion coefficients and thermal conductivities of the GDL components. Different types of GDLs and water transport scenarios are defined in this work, based on water condensation in the GDL and fraction of water that the GDL removes through the vapor phase, respectively.     

Tyrosine and phenylalanine catabolism by Lactobacillus cheese flavor adjuncts

Bacterial metabolism of Tyr and Phe has been associated with the formation of aromatic compounds that impart barny-utensil and floral off-flavors in cheese. In an effort to identify possible mechanisms for the origin of these compounds in Cheddar cheese, we investigated Tyr and Phe catabolism by Lactobacillus casei and Lactobacillus helveticus cheese flavor adjuncts under simulated Cheddar cheese-ripening (pH 5.2, 4% NaCl, 15 degrees C, no sugar) conditions. Enzyme assays of cell-free extracts indicated that L. casei strains catabolize Tyr and Phe by successive, constitutively expressed transamination and dehydrogenation reactions. Similar results were obtained with L. helveticus strains, except that the dehydrogenase enzymes were induced during incubation under cheese-ripening conditions. Micellar electrokinetic capillary chromatography of supernatants from L. casei and L. helveticus strains incubated under simulated cheese-ripening conditions confirmed that Tyr and Phe transamination and dehydrogenation pathways were active in both species and also showed these reactions were reversible. Major products of Tyr catabolism were phydroxy phenyl lactic acid and p-hydroxy phenyl acetic acid, while Phe degradation gave rise to phenyl lactic acid, phenyl acetic acid, and benzoic acid. However, some of these products were likely formed by nonenzymatic processes, since spontaneous chemical degradation of the Tyr intermediate p-hydroxy phenyl pyruvic acid produced p-hydroxy phenyl acetic acid, p-hydroxy phenyl propionic acid, and p-hydroxy benzaldehyde, while chemical degradation of the Phe intermediate phenyl pyruvic acid gave rise to phenyl acetic acid, benzoic acid, phenethanol, phenyl propionic acid, and benzaldehyde.     

Experimental Characterization of the Outdoor MIMO Wireless Channel Temporal Variation

Time-variant multiple-input multiple-output (MIMO) channels are measured in an outdoor campus environment at 2.45 GHz with directional patch arrays and omnidirectional monopole arrays. A number of useful metrics are proposed for quantifying time variation in MIMO channels: eigenvalue level crossing rate, eigenvector angular deviation, and capacity loss for delayed transmit and receive channel state information (CSI). Measurements in four different environments confirm the strong correlation between angular spread of multipath and MIMO channel time variability. The rate of time variation is also strongly influenced by the type of array, indicating that directional elements may be advantageous for highly mobile environments. The proposed metrics indicate that although the physical communication layer may need to update CSI several times per wavelength, the required rate of adaptation in transmit rate, modulation, and power allocation is much less severe     

Effect of material and geometric parameters on deformations near the notch-tip of a dynamically loaded prenotched plate

We analyze plane strain thermomechanical deformations of a prenotched rectangular plate impacted on one side by a prismatic body of rectangular cross-section and moving parallel to the axis of the notch. Both the plate and the projectile are made of the same material. Strain hardening, strain-rate hardening and thermal softening characteristics of the material are modeled by the Johnson–Cook relation. The effect of different material parameters, notch-tip radius, impact speed and the length of the projectile on the maximum tensile principal stress and the initiation and propagation of adiabatic shear bands at the notch-tip is analyzed. It is found that for high impact speeds or enhanced thermal softening, two shear bands, one at −10° to the notch ligament and the other at −128° to it, propagate from the notch tip. Otherwise, only one shear band nearly parallel to the notch-ligament initiates at the notch-tip. The notch-tip distortion for high strength materials is quite different from that for low strength materials. The maximum tensile principal stress occurs at a point on the upper surface of the notch-tip and for every set of values of material parameters and impact speeds studied equals about 2.3 times the yield stress of the material in a quasistatic simple tension or compression test. We assume that the brittle failure occurs when the maximum tensile principal stress equals twice the yield stress of the material in a quasistatic simple tension test and a shear band initiates when the effective plastic strain at a point equals 0.5. The effect of material and geometric parameters on the time of initiation of each failure mode is computed. It is found that for low impact speeds (<30 m/s) a material will fail due to the maximum tensile principal stress exceeding its limiting value, and at high impact speeds due to the initiation of a shear band at the notch-tip. Results are also computed for a C-300 steel with material parameters given by Zhou et al. For an impact speed of 50 m/s, the shear band speed and the maximum effective plastic strain-rate before a material point melts are found to be 350 m/s and 5×10⁷/s respectively. Key words: Failure-mode transition, shear bands, thermoviscoplasticity, numerical simulations. This revised version was published online in July 2006 with corrections to the Cover Date.     

Random variability modeling and its impact on scaled CMOS circuits

Random variations have been regarded as one of the major barriers on CMOS scaling. Compact models that physically capture these effects are crucial to bridge the process technology with design optimization. In this paper, 3-D atomistic simulations are performed to investigate fundamental variations in a scaled CMOS device, including random dopant fluctuation (RDF), line-edge roughness (LER), and oxide thickness fluctuation (OTF). By understanding the underlying physics and analyzing simulation results, compact models for random threshold (V _th ) variations are developed. The models are scalable with device specifications, enabling quantitative analysis of circuit performance variability in future technology nodes. Using representative circuits, such as the inverter chain and SRAM cell, key insights are extracted on the trend of variability, as well as the implications on robust design.     

Design of an access mechanism for a high speed distributed wirelessLAN

The medium used by indoor wireless LANs is a shared, scarce resource. Hence, efficient use of this medium is important, which in turn requires an efficient MAC protocol. Moreover, next generation wireless LANs will have to support data rates from 10 to 100 Mbits/s. At these data rates, turnaround times in half-duplex radios are a large overhead. This makes the current wireless standards inefficient. However, busy-tone solutions can get around this problem. In spite of their better performance, the busy-tone protocols are not widely used because of the hardware cost, i.e., the requirement of two transceivers-one each for the data and feedback channel. A novel wireless transceiver architecture which mitigates this hardware cost by overlaying the data channel and the feedback channel in the same frequency band is designed. It is shown that this transceiver can be built with current technology. Based on this wireless transceiver, a new MAC protocol called wireless collision detect (WCD) is proposed. This protocol uses a carrier detect signal to decrease the collision probability and receiver initiated feedback to handle hidden nodes. We derive a mathematical expression for the throughput of the protocol. The simulation results match the analysis. At 100 Mbits/s, WCD achieves 77% efficiency with 192 byte packets. For this scenario, the throughput of the IEEE 802.11 MAC protocol and RI-BTMA is 3% and 52%, respectively     

Wireless medium access control protocols

Technological advances, coupled with the flexibility and mobility of wireless systems, are the driving force behind the Anyone, Anywhere, Anytime paradigm of networking. At the same time, we see a convergence of the telephone, cable and data networks into a unified network that supports multimedia and real-time applications like voice and video in addition to data. Medium access control protocols define rules for orderly access to the shared medium and play a crucial role in the efficient and fair sharing of scarce wireless bandwidth. The nature of the wireless channel brings new issues like location-dependent carrier sensing, time varying channel and burst errors. Low power requirements and half duplex operation of the wireless systems add to the challenge. Wireless MAC protocols have been heavily researched and a plethora of protocols have been proposed. Protocols have been devised for different types of architectures, different applications and different media. This survey discusses the challenges in the design of wireless MAC protocols, classifies them based on architecture and mode of operation, and describes their relative performance and application domains in which they are best deployed.