Harnessing the Melting Peculiarities of Ultra‐High Molecular Weight Polyethylene Fibers for the Processing of Compacted Fiber Composites

Summary: Compacted fiber composites offer unique properties due to their lack of an extraneous matrix. The conditions of processing ultra‐high molecular weight polyethylene (UHMWPE) fibers were simulated in a heated pressure cell. In situ X‐ray diffraction measurements were used to follow the relevant transitions and the changes in the degree of crystallinity during melting and crystallization. The results strongly support the suggestion that the hexagonal crystal phase, in which the chain conformation is extremely mobile on the segmental level, constitutes the physical basis of compaction technologies for processing UHMWPE fibers into a single‐polymer composite. This report suggests that using a pseudo‐phase diagram outlining the occurrence of different phases during slow heating and the degree of crystallinity can provide valuable insight into the technological parameters relevant for optimal processing conditions.

Degree of crystallinity as a function of pressure and temperature in a region relevant to compaction processes.     

Distilled Collections from Textual Image Queries

We present a distillation algorithm which operates on a large, unstructured, and noisy collection of internet images returned from an online object query. We introduce the notion of a distilled set, which is a clean, coherent, and structured subset of inlier images. In addition, the object of interest is properly segmented out throughout the distilled set. Our approach is unsupervised, built on a novel clustering scheme, and solves the distillation and object segmentation problems simultaneously. In essence, instead of distilling the collection of images, we distill a collection of loosely cutout foreground “shapes”, which may or may not contain the queried object. Our key observation, which motivated our clustering scheme, is that outlier shapes are expected to be random in nature, whereas, inlier shapes, which do tightly enclose the object of interest, tend to be well supported by similar shapes captured in similar views. We analyze the commonalities among candidate foreground segments, without aiming to analyze their semantics, but simply by clustering similar shapes and considering only the most significant clusters representing non‐trivial shapes. We show that when tuned conservatively, our distillation algorithm is able to extract a near perfect subset of true inliers. Furthermore, we show that our technique scales well in the sense that the precision rate remains high, as the collection grows. We demonstrate the utility of our distillation results with a number of interesting graphics applications.     

Assume,guarantee or repair: a regular framework for non regular properties

We present Assume-Guarantee-Repair (AGR)—a novel framework which verifies that a program satisfies a set of properties and also repairs the program in case the verification fails. We consider communicating programs—these are simple C-like programs, extended with synchronous actions over communication channels. Our method, which consists of a learning-based approach to assume–guarantee reasoning, performs verification and repair simultaneously: in every iteration, AGR either makes another step towards proving that the (current) system satisfies the required properties, or alters the system in a way that brings it closer to satisfying the properties. To handle infinite-state systems we build finite abstractions, for which we check the satisfaction of complex properties that contain first-order constraints, using both syntactic and semantic-aware methods. We implemented AGR and evaluated it on various communication protocols. Our experiments present compact proofs of correctness and quick repairs.

     

Crankback Prediction in Hierarchical ATM Networks

When an ATM node discovers that it cannot continue the setup of a virtual channel under the requested Quality of Service (QoS), it initiates a backtracking procedure called crankback. We propose a novel scheme, referred to as crankback prediction, that decreases the crankback overhead. Under the proposed scheme, nodes check during the connection admission control procedure whether the establishment of a virtual channel has a good chance to be admitted over the entire designated route. If this is not the case, crankback is initiated even before a particular QoS parameter is violated. The main idea behind the proposed scheme is to allocate a quota to the Peer Groups (PGs) along the message path, and then to suballocate this quota to the child PGs of these PGs. This process continues recursively until reaching the 1-level PG, which contains only physical nodes. The main advantage of the proposed scheme is that it lowers the setup delay and the processing and communication load imposed by signaling messages that establish unused portions of Virtual Channels (VCs)     

A three-person perspective on transference.

Different approaches to psychoanalysis may be classed according to the number of persons that they assume to be necessary in order to adequately describe mental life. One-person approaches assume the basic autonomy of the individual to act as a subject in her world, while 2-person approaches assume the irreducibility of object and subject, their essential complementarity and their mutual affirmation as subjects. Three-person approaches, on which the present article focuses, argue that the subject can fully develop only by creating enough space for herself among other persons who compete for subject positions. Such space is created in relation to (at least) 2 other subjects, hence the system of 3 persons. In the 3-person perspective, the position of the subject is defined as First, and the Second is defined by the one with whom the subject identifies and in whom she mirrors herself through cycles of projection and introjection. The position of the Third involves the personification of the cultural matrix and, especially, the way language informs our ability to relate to each other. This is best represented in the universal system of personal pronouns: the subject takes the position of the 1st person (I), the Second takes the position of the 2nd person (You), and the Third is posited as the 3rd person (she or he and it). In psychoanalytic therapy, the patient takes the position of the Subject, the First. Transference is construed as the superposition of both the 2nd and the 3rd persons upon the figure of the analyst, a mental process that (re)creates the necessary conditions for the development of subjecthood. As a result, in the discourse of transference, the position of the analyst keeps fluctuating between the 2nd and 3rd positions: When one takes place on the actual level, the other acts in the background, and vice versa. The therapeutic consequences of this view are discussed; for example, transference love is construed as a process in which the 2nd person struggles to dominate the positioning of the analyst. Other transferential configurations are also discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Human umbilical cord blood stem cells: rational for use as a neuroprotectant in ischemic brain disease

The use of stem cells for reparative medicine was first proposed more than three decades ago. Hematopoietic stem cells from bone marrow, peripheral blood and human umbilical cord blood (CB) have gained major use for treatment of hematological indications. CB, however, is also a source of cells capable of differentiating into various non-hematopoietic cell types, including neural cells. Several animal model reports have shown that CB cells may be used for treatment of neurological injuries. This review summarizes the information available on the origin of CB-derived neuronal cells and the mechanisms proposed to explain their action. The potential use of stem/progenitor cells for treatment of ischemic brain injuries is discussed. Issues that remain to be resolved at the present stage of preclinical trials are addressed.     

Hydrothermal degradation of adsorbed sulfur mustard on activated carbon

Thermal and hydrothermal degradations of adsorbed sulfur mustard (HD) on activated carbon particles from a chemical protective over-garment were studied. Carbon loaded with 5 wt.% HD was heated in a closed reactor at temperatures up to 160 °C for 0.5–6 h and analyzed by solid-state ¹³C MAS NMR. On dry carbon at room temperature, HD was stable for months. On a thoroughly pre-wetted carbon, adsorbed HD partially degraded to thiodiglycol (TDG) and TDG-sulfoxide (TDG-SO) within 2–3 months. Heating dry HD-loaded carbon to 160 °C caused partial degradation within 4 h to 1,4-thioxane, along with 1,4-dithiane and vinyl sulfides. Complete degradation within 2.5 h to the same products occurred upon hydrothermal treatment of the HD-loaded carbon, using a water/carbon ratio of 0.3:1. With higher water/carbon ratios of 0.6:1–5:1 at temperatures of 120 °C and above, adsorbed HD hydrolyzed rapidly within 0.5 h. The latter reaction led to the formation of TDG concurrent with either thioxane (at 160 °C) or TDG-SO and TDG-dimer (at 120 °C). The mechanisms of the observed degradation processes are discussed.     

Purification and characterization of laccase from Chaetomium thermophilium and its role in humification

Chaetomium thermophilium was isolated from composting municipal solid waste during the thermophilic stage of the process. C. thermophilium, a cellulolytic fungus, exhibited laccase activity when it was grown at 45 degreesC both in solid media and in liquid media. Laccase activity reached a peak after 24 h in liquid shake culture. Laccase was purified by ultrafiltration, anion-exchange chromatography, and affinity chromatography. The purified enzyme was identified as a glycoprotein with a molecular mass of 77 kDa and an isoelectric point of 5.1. The laccase was stable for 1 h at 70 degreesC and had half-lives of 24 and 12 h at 40 and 50 degreesC, respectively. The enzyme was stable at pH 5 to 10, and the optimum pH for enzyme activity was 6. The purified laccase efficiently catalyzed a wide range of phenolic substrates but not tyrosine. The highest levels of affinity were the levels of affinity to syringaldazine and hydroxyquinone. The UV-visible light spectrum of the purified laccase had a peak at 604 nm (i.e., Cu type I), and the activity was strongly inhibited by Cu-chelating agents. When the hydrophobic acid fraction (the humic fraction of the water-soluble organic matter obtained from municipal solid waste compost) was added to a reaction assay mixture containing laccase and guaiacol, polymerization took place and a soluble polymer was formed. C. thermophilium laccase, which is produced during the thermophilic stage of composting, can remain active for a long period of time at high temperatures and alkaline pH values, and we suggest that this enzyme is involved in the humification process during composting.     

Iron uptake in Ustilago maydis: tracking the iron path

In this study, we monitored and compared the uptake of iron in the fungus Ustilago maydis by using biomimetic siderophore analogs of ferrichrome, the fungal native siderophore, and ferrioxamine B (FOB), a xenosiderophore. Ferrichrome-iron was taken up at a higher rate than FOB-iron. Unlike ferrichrome-mediated uptake, FOB-mediated iron transport involved an extracellular reduction mechanism. By using fluorescently labeled siderophore analogs, we monitored the time course, as well as the localization, of iron uptake processes within the fungal cells. A fluorescently labeled ferrichrome analog, B9-lissamine rhodamine B, which does not exhibit fluorescence quenching upon iron binding, was used to monitor the entry of the compounds into the fungal cells. The fluorescence was found intracellularly 4 h after the application and later was found concentrated in two to three vesicles within each cell. The fluorescence of the fluorescently labeled FOB analog CAT18, which is quenched by iron, was visualized around the cell membrane after 4 h of incubation with the ferrated (nonfluorescent) compounds. This fluorescence intensity increased with time, demonstrating fungal iron uptake from the siderophores, which remained extracellular. We here introduce the use of fluorescent biomimetic siderophores as tools to directly track and discriminate between different pathways of iron uptake in cells.