Origin of the threshold voltage instability in SiO/sub 2//HfO/sub 2/ dual layer gate dielectrics

The magnitude of the V/sub T/ instability in conventional MOSFETs and MOS capacitors with SiO/sub 2//HfO/sub 2/ dual-layer gate dielectrics is shown to depend strongly on the details of the measurement sequence used. By applying time-resolved measurements (capacitance-time traces and charge-pumping measurements), it is demonstrated that this behavior is caused by the fast charging and discharging of preexisting defects near the SiO/sub 2//HfO/sub 2/ interface and in the bulk of the HfO/sub 2/ layer. Based on these results, a simple defect model is proposed that can explain the complex behavior of the V/sub T/ instability in terms of structural defects as follows. 1) A defect band in the HfO/sub 2/ layer is located in energy above the Si conduction band edge. 2) The defect band shifts rapidly in energy with respect to the Fermi level in the Si substrate as the gate bias is varied. 3) The rapid energy shifts allows for efficient charging and discharging of the defects near the SiO/sub 2//HfO/sub 2/ interface by tunneling.     

辽宁排山楼金矿T4矿体Au元素富集规律及其对找矿的指示意义

排山楼金矿位于华北地台北缘,为受控于韧性剪切带的大型金矿床。该矿床成因与韧性剪切带密切相关,矿区成矿地质条件优越,具有很好的找矿潜力。通过总结排山楼金矿地质特征及其主要控矿因素,认为区内韧性剪切带为控岩（控矿）构造,控制着赋矿糜棱岩和金矿体的空间展布,向矿区深部赋矿岩石变薄,找矿空间变小。通过分析T4矿体的品位和厚度分布规律发现,矿体厚度及品位分布规律在空间上表现出高度一致性,根据金品位等值线图判断矿体向南西侧伏。研究认为T4矿体在南西深部其厚度及品位降低趋势明显,向深部工业价值不大,应重点加强对其他韧性剪切带找矿潜力的研究。     

岩体尖端裂纹扩展特性研究

岩体在压剪状态下的力学特性研究应用至今已有十余年,发展比较完善。而对于拉剪应力状态下岩体的力学特性,以及在拉剪应力状态下岩体的损伤扩展与演化方面的研究成果较少。为此,对岩体在拉剪应力状态下岩体的损伤扩展与演化进行理论分析研究,在前人提出的裂纹尖端塑性区内方向应变能概念的基础上,基于岩石破坏准则,对复合型裂纹扩展进行了研究,研究成果对解决实际岩体工程问题有一定的参考价值。     

超高强度结构用Q1100特薄钢板的淬火板型控制研究

工程机械不断向着大型化和轻量化方向发展,其用钢强度级别越来越高.Q1100D/E级别超高强度结构用钢是目前国内工程机械领域强度级别最高的钢种,具有优良的成型性、良好的焊接性和低温冲击韧性.但8～10 mm厚度特薄Q1100D/E钢板存在淬火板型控制难度较大、平直度较差的问题,通过研究钢板淬火冷却相变机理,采取提升淬火设备精度等改进措施,使钢板的淬火板型得到有效改善.     

锂离子电池凝胶聚合物电解质

对锂离子凝胶聚合物电解质的结构特征、导电机理、制备方法进行了总结和评述,对锂离子聚合物电解质及锂离子电池的发展进行了预测。     

溶胶凝胶法制备LiNi0．03Mn1．97O4及其电化学性能

采用溶胶凝胶法合成锂离子电池正极材料LiNi0.03Mn1.97O4,使用X射线衍射（XRD）、扫描电子显微镜（SEM）对合成材料的结构及物理性能进行了表征。将合成材料作为锂离子电池正极活性材料,考察烧结温度对其结构及电化学性能的影响。随着烧结温度的升高,尖晶石型结构越来越完整,初始放电比容量增大,但循环性能却逐渐变差。在750℃下烧结温度12h得到了性能较好的HNi0.03Mn1.97O4,首次放电比容量为118．7mA·h／g,50次循环后,其放电比容量仍保持在101．6mA·h／g,适合作为锂离子电池的正极材料。     

基于嵌入式系统的体外除颤器

电击除颤是最有效的治疗室颤(VF)的方法.本文介绍了一种基于嵌入式系统的体外除颤器.该设计选用了两款合适的嵌入式处理器,在保证系统的性能和低功耗要求的同时,方便了系统的实现.整个设计分为监护控制单元、心电采集单元和除颤单元三个部分.试验结果表明,使用该设备可以成功终止室颤.     

规范管理有序开发推进磐安水电产业可持续发展

磐安水电的发展,在推动县域经济社会发展方面的作用是显而易见的,特别是通过实施全国第二、第四批水电农村电气化县建设,农村水电蓬勃发展,农村电气化建设和经济社会发展速度明显加快,为社会主义新农村建设提供了重要的基础保障。     

Study of the Reliability Impact of Chlorine Precursor Residues in Thin Atomic-Layer-Deposited HfO2 Layers

Atomic layer deposition (ALD) with HfCl₄ as a precursor is widely used for HfO₂ fabrication. Due to the nature of the precursor under study, i.e., HfCl₄ and H₂O, the presence of chlorine residues in the film due to insufficient hydrolysis is eminent. Obviously, the chlorine residue in the HfO₂ film is suspected to affect the quality of the HfO₂ film. In this paper, The authors reduced the concentration of chlorine residues by increasing the H₂O oxidant pulse time in between the deposition cycles from 0.3 to 10 and 90 s. Time-of-flight secondary ion mass spectrometry analysis shows that this decreases the chlorine concentration in the HfO₂ film by more than one order of magnitude. However, time-dependent dielectric breakdown analysis shows that the lifetime remains quasi unaffected (within identical error bars) for the different injection cycles. Charge pumping analysis was done by varying both pulse frequency and amplitude to investigate the creation of defects, but negligible differences were observed. Therefore, the presence of chlorine residues has no significant impact on the trap generation and reliability of ALD HfO₂ layers, and this result corresponded with the mobility result. The experimental picture is confirmed with first-principle calculations that show that the presence of chlorine residues does not induce defect levels in the bandgap of HfO₂     

岩体开挖卸荷过程力学特性研究

基于岩体开挖卸荷过程中力学参数变化理论,建立卸荷岩体有限元分析模型,运用ADINA有限元分析软件对岩体进行三维卸荷数值仿真研究.结果表明,岩体在开挖卸荷过程中,岩体的弹性模量、粘聚力和内摩擦角等力学参数随开挖卸荷量的增大而减小,但不是从初始值一直减小到零,而是随岩体的裂隙、结构面张开扩展到一定程度后,保持一定的量级不再减小.