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In satellite-switched time-division multiple access (SS/TDMA) systems, the demand assignment control is a suitable scheme for the bursty packets to enhance the capacity efficiency. In the system, by applying the demand assignment scheme, the minimum transmission time could be achieved by the efficient time slot assignment algorithm. According to a given traffic matrix, the minimum transmission time cannot exceed the fixed TDMA frame duration. The spare time may be left at the end of the TDMA frame as the growth space for the future needs. To increase the system efficiency, the spare time could be reduced. In this paper, a demand assignment protocol with a variable frame is proposed for the system. The Markov chain model is applied to analyze the system performance on throughput, balking probability and packet delay. Performance comparison with the previous presented protocol, the proposed protocol could show a simple control technique and the efficient performance results in the system. It is a suitable candidate to be employed in the satellite networks to provide communication between the satellite and earth stations.  相似文献   
2.
Glycidol was used to convert the isocyanate-terminated polyurethane prepolymer to glycidyl-terminated polyurethane prepolymer. The modified polyurethane not only offers some distinct advantages over the commercial polyurethane prepolymer, but also enhances the properties of the epoxy resins. The glycidyl-terminated polyurethane modified epoxy resin proved to be superior to conventional epoxy resins in improving impact strength, fracture energy, and adhesion properties. The compatibility of the compounds in this glycidyl-terminated PU/epoxy system was investigated using different preparation procedures. It was found that the synthesized glycidyl-terminated polyurethane prereacted with curing agents, exhibited a lesser degree of phase separation, and can influence the mechanical properties of polymer blends. The results coincide with the phenomena observed in dynamic mechanical analysis and scanning election microscopy. © 1994 John Wiley & Sons, Inc.  相似文献   
3.
This study investigates the effects of individual negotiation styles on a buyer’s stated behaviour and a supplier’s anticipation of the buyer’s behaviours with regard to opportunism and compliance in a multi-echelon production network under different firm-level governance mechanisms. We design a between-subjects matched-scenario experiment to collect data from both sides of a buyer?supplier dyad. We find that agent negotiation styles do exert influences on opportunism but not compliance. Specifically, we find that the effects of firm-level governing mechanisms dominate the effects of individual negotiation styles with regard to compliance, while individual negotiation styles have influence beyond firm-level governing mechanisms with regard to opportunism. Theoretical contributions of our findings to the current literature and managerial implications to practice are discussed.  相似文献   
4.
A high water retention membrane is developed by co-assembling poly(ethylene glycol) (PEG) grafted activated carbon (AC-PEG) with Nafion. The AC-PEG is prepared via a sol–gel process. The use of PEG as a transporting medium in AC-PEG shows a largely improved water retention ability, a higher proton conductivity and a reduced swelling ratio, making it well suited for proton exchange membrane fuel cells (PEMFCs). Further, the composite membranes show improved mechanical properties at high temperature, thus ensuring the structural stability of membranes during the fuel cell operation. Compositional optimized AC-PEG/Nafion composite membrane (15 wt% compared to Nafion) demonstrates a better performance than the commercially available counterpart, Nafion 212, in fuel cell measurements. To identify the key factor of the improved performance, current interrupt technique is used to quantitatively verify the changes of resistance under different relative humidity environment.  相似文献   
5.
An easy and effective method for producing low methanol-crossover membranes is developed by dispersing sulfonated graphene oxide (SGO) into a Nafion matrix. A SGO/Nafion mixture with low SGO content exhibits unique viscosity behavior and allows for better SGO dispersion within the Nafion. After film casting, the composite membranes show lower methanol and water uptakes, a reduced swelling ratio, improved proton conductivity in low relative humidity, and extremely high methanol selectivity, which can be implemented in direct methanol fuel cells (DMFCs). The regular backbone of the composite membrane shows a higher storage modulus, increased α-relaxation (transition temperature), and improved tolerance to pressure during membrane electrode assembly (MEA). The small angle X-ray spectra indicate the shrinkage of the ionic clusters in the composite membranes, which thus reduce methanol crossover. The hybrid membranes applied to DMFCs demonstrate performances superior to that of the commercial Nafion 115 in 1 M and 5 M methanol solutions.  相似文献   
6.
Switching activity and instruction cycles are two of the most important factors in power dissipation when the supply voltage is fixed. This paper studies the scheduling and assignment problems that minimize the total energy caused by both instruction processing and switching activities for applications with loops on multi-core, multi-Functional-Unit (multi-FU) architectures. An algorithm, EMPLS (Energy Minimization with Probability using Loop Scheduling), is proposed to minimize the total energy (E) while satisfying timing constraint (L) with guaranteed probability (P). We perform scheduling and assignment simultaneously. Our approach shows better performance than the approaches that consider scheduling and assignment in separate phases. Compared with previous work, our algorithm exhibits significant improvement in total energy reduction.  相似文献   
7.
Polyurethane adhesives containing the polyether backbone exhibit a good joint strength in cryogenic environments. In practice, many of the commercially available polyurethane adhesive systems contain free or chemically blocked isocyanates which have some limitations. This study presents the synthesis and characterization of a modified polyurethane type adhesive. Glycidol was used to convert the isocyanate-terminated polyurethane prepolymer to glycidylterminated polyurethane prepolymer. A series of glycidyl-terminated polyurethanes, based on polyoxypropylene glycol (PPG) soft segments having different molecular weights, were synthesized and their adhesive properties on aluminium were evaluated. The effect of the soft segment length on adhesion was examined. The adhesive properties at room temperature and cryogenic temperature are in line with the phenomenon observed in dynamical mechanical analysis (DMA) and in the phase separation behavior of the polyurethanes. Differential scaning calorimetry (DSC) was used to assess the phase separation content. An improvement in the adhesive strengths at room temperature is achieved by adding epoxy resins to the glycidyl-terminated polyurethane resins.  相似文献   
8.
A glycidyl-terminated polyurethane prepolymer was synthesized and used to enhance the properties of epoxy resins. Some properties of glycidyl-terminated PU/epoxy with polyether based (PPG) and polyester based (PBA) glycidyl-terminated PU were investigated in this research. The polyether based glycidyl-terminated PU(PPG) modified epoxy resin proved to be superior to conventional epoxy resins in improved impact strength and fracture energy, but not tensile strength, tensile modulus, flexural strength and flexural modulus. On the other hand, the polyester based glycidyl-terminated PU(PBA) modified epoxy resin had increased mechanical properties while showing slight variation of impact strength and fracture energy. Different mechanisms for this behaviour are advanced in this paper.  相似文献   
9.
2,3-Epoxy-1-propanol has been introduced into isocyanate-terminated polyurethane to form glycidyl-terminated polyurethane resins. A series of glycidyl-terminated polyurethanes based on hydroxyterminated poly(oxypropylene) (poly(oxypropylene) glycol, PPG), toluene diisocyanate (TDI), and 1,4-butanediol (BD) was synthesized with various PPG soft segment lengths (MW 700, 1000 and 2000) and soft segment concentrations (30, 50 and 70 wt.-%). The effects of glycidyl-terminated polyurethane on the adhesion properties and the phase separation were investigated. The adhision properties at liquid nitrogen temperature coincide with the phenomenon observed in the phase separation behavior of polyurethane. Differential scanning calorimetry (DSC) and infrared technique (IR) were used to assess the phase separation content. The enthalpy jump at the glass transition temperature (ΔCp) and the unique spectroscopic features in the N? H and C?O stretching regions were applied to characterized the phase separation behavior. It was found that the modified resins do not only show superior adhesion at liquid nitrogen temperature but also exhibit some unique properties, e.g., room temperature curing and good storage stability.  相似文献   
10.
Glycidol has been introduced into isocyanate-terminated polyurethane to form glycidyl-terminated polyurethane resin. A series of glycidyl-terminated polyurethanes, based on PTMEG, PPG, and polyester soft segments, having different molecular weights were synthesized and their adhesion properties on aluminum were evaluated. The effect of the soft-segment structure, soft-segment length, and temperature on adhesion were examined. It was found that the resin showed superior adhesion at cryogenic temperatures. The results coincide with the phenomenon observed in dynamic mechanical analysis (DMA) and scanning electron microscopy (SEM). In addition, the modified system also offered some distinct advantages over the commercial polyurethane adhesives, e.g., good storage stability and room-temperature curing. © 1994 John Wiley & Sons, Inc.  相似文献   
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