Maintenance of the undersea section of the Seikan Tunnel

This paper introduces the results of measurements made over a period of 14 years after the Seikan Tunnel was opened for service. Because this tunnel is a very long undersea tunnel with the length of 54 km, the necessity of clarifying the long-term behavior of the tunnel structure was recognized from the start. Various measurements are made to survey the condition of the ground and lining concrete and data thus obtained are used to assess the soundness of the tunnel structure. Judging from the data thus far obtained, the tunnel structure appears to remain in a good condition.     

Effect of Nd2O3 Concentration on the Defect Structure of CeO2–Nd2O3 Solid Solution

An extensive X-ray study of CeO₂–Nd₂O₃ solid solutions was performed, and the densities of solid solutions containing various concentrations of NdO_1.5 were measured using several techniques. Solid solutions containing 0–80 mol% NdO_1.5 were synthesized by coprecipitation from Ce(NO₃)₃ and Nd(NO₃)₃ aqueous solutions, and the coprecipitated samples were sintered at 1400°C. A fluorite structure was observed for CeO₂–NdO_1.5 solid solutions with 0–40 mol% NdO_1.5, which changed to a rare earth C-type structure at 45–75 mol% NdO_1.5. The change in the lattice parameters of CeO₂–NdO_1.5 solid solutions, when plotted with respect to the NdO_1.5 concentration, showed that the lattice parameters followed Vegard's law in both the fluorite and rare earth C-type regions. The maximum solubility limit for NdO_1.5 in CeO₂ solid solution was approximately 75 mol%. The relationship between the density and the Nd concentration indicated that the defect structure followed the anion vacancy model over the entire range (0–70 mol% NdO_1.5) of solid solution.     

Reliability of physiological and subjective responses to physical and psychosocial exposures during a simulated manufacturing task

Responses to physical and psychosocial exposures can be measured using diverse methods, but their reliability, particularly under multiple exposures, is largely unknown. Five classes of methods were used to assess physiological and subjective responses among 24 participants to four combinations of physical and psychosocial exposures while performing two identical sessions of a simulated overhead manufacturing task. As an exploratory analysis, test–retest reliability was quantified using intraclass correlation coefficients (ICC) and coefficients of variation (CV). Discomfort ratings were reliable under less favorable exposures, and ratings of the psychosocial environment were most reliable under favorable social support. Workload ratings were most reliable with high physical exposure and favorable social support, and task performance was reliable overall. EMG and heart rate had relatively low reliability. Slightly less than half of the variables were considered reliable, but reliability depended on exposure conditions.Relevance to industry: The study provides information on the reliability of commonly used exposure measurement methods. The results can guide the selection of physiological and psychological work outcome measurements in future studies and work evaluations.     

Actual ratios of triacylglycerol positional isomers consisting of saturated and highly unsaturated fatty acids in fishes and marine mammals

The distribution of fatty acid species at the (sn-1, 3) position or the (sn-2) position of triacylglycerol (TAG) in natural fats and oils has already been analysed by many researchers and several interesting results have been reported. However, most of these reports only focused on the distribution of fatty acids at the or positions in TAG, and did not take account of the combination of fatty acids in the TAG, i.e., the TAG positional isomers. In this study, the actual ratios of TAG positional isomer pairs, consisting of palmitic acid and highly unsaturated fatty acid (HUFA) such as DHA or EPA, in fish and marine mammals were investigated using a high-performance liquid chromatography/atmospheric pressure chemical ionisation-mass spectrometry (HPLC/APCI-MS) system equipped with tandem jointed non-endcapped polymeric ODS columns. The results show that for combinations of DHA or EPA with two palmitic acids in the TAG of marine mammals, binding was almost all at the α position. In contrast, binding of DHA or EPA was mainly at the β position in fish. The preferred DHA and EPA positions in TAG were the same in the same marine mammal or fish. The binding position tendency of HUFA in TAG positional isomers consisting of two HUFAs and one palmitic acid was the same as that for combinations of one HUFA and two palmitic acids. These results were interpreted as showing that the preferred fatty acid species of sn-glycerol-3-phosphate acyltransferase and 1-acyl-sn-glycerol-3-phosphate acyltransferase in marine mammals are different to those in fish and other animals, or that diacylglycerol acyltransferase in marine mammals favours 1,2-dipalmitoyl-sn-glycerol formed from 1,2-dipalmitoyl-sn-glycerol-3-phosphatidate if HUFA is the reaction substrate.     

Synthesis of a lithium-encapsulated fullerenol and the effect of the internal lithium cation on its aggregation behavior

A lithium-encapsulated fullerenol Li@C₆₀(OH)₁₈, as an example of a polar solvent-soluble endohedral fullerene derivative, has been synthesized and fully characterized by infrared spectroscopy, nuclear magnetic resonance spectroscopy, UV spectroscopy, electron spin resonance (ESR) spectroscopy, matrix-assisted laser desorption ionization time of flight mass spectrometry (MALDI-TOF-MS), elemental analysis, thermogravimetric analysis, and inductively coupled plasma-atomic emission spectroscopy (ICP-AES), and the particle size was determined using the induced grating (IG) method, and scanning probe microscopy. The encapsulated Li⁺ was clearly detected by ⁷Li NMR at very high field in the range −15 to −19 ppm, an intermediate lithium-encapsulated fullerenol was detected by MALDI-TOF-MS, and the molar ratio of lithium-encapsulated fullerenol to empty fullerenol was quantitatively determined to be 12:88 by ICP-AES. The solid-state ESR and particle size measurements using the IG method showed the characteristic anionic behavior with no external counter cations, in what can be called a “cation-encapsulated anion nanoparticle”, revealing the drastic differences between its properties and those of empty C₆₀(OH)₁₆.      

Enhancement of the diffusional creep of polycrystalline Al2O3 by simultaneous doping with manganese and titanium

The effect of simultaneous doping with manganese and titanium on diffusional creep was studied in dense, polycrystalline alumina over a range of grain sizes (4–80m) and temperatures (1175–1250° C). At a total dopant concentration of 0.32–0.37 cation %, diffusional creep rates were enhanced considerably such that the temperature at which cation mass transport was significant was suppressed by at least 200° C compared to that observed in undoped material. The Mn-Ti (and Cu-Ti) dopant couple was far more effective in enhancing creep rates and suppressing sintering temperatures than the Fe-Ti couple. The enhanced mass transport kinetics are believed to be caused by significant increases in both aluminium lattice and grain-boundary diffusion. When aluminium grain-boundary diffusion is enhanced by increasing the concentration of divalent impurity (Mn²⁺, Fe²⁺) or by creep testing at low temperatures, creep deformation is Newtonian viscous.     

Evaluation of the loading of neck and shoulder musculature in overhead pushing and pulling exertions

Despite substantial epidemiological evidence relating overhead exertions with work‐related musculoskeletal disorders (WMSD) of the neck, effects of such exertions on the loading of neck or cervical spine musculature are not well understood. In this study, the effects of overhead pushing and pulling exertions on the loading of the cervical spine were evaluated using electromyography (EMG) and subjective discomfort ratings. Additionally, the role of gender as well as individual strength on the loading of neck musculature during such exertions was evaluated. Twenty‐four healthy individuals (12 men and 12 women) participated in this study. Each participant performed overhead pushing and pulling exertions, exerting 25%, 50%, and 75% of their respective maximum strengths. Overhead pushing exertions were found to be significantly more strenuous to the neck musculature than were the pulling exertions. Gender had no significant effect on the activities of the neck muscles. Participants with high strength, however, were able to exert more force at comparatively low muscle activation levels. Subjective discomfort ratings were strongly correlated with the EMG data. At various workplaces, avoiding overhead exertions is rather impossible due to material, interface, and site constraints. Based on the results of this study, however, during such exertions, an interchange between directions of force application could prevent sustained loading of the neck muscles, fatigue, and consequently the probability of neck WMSD incidents. © 2011 Wiley Periodicals, Inc.     

Dynamics in a compound cavity semiconductor laser induced by smallexternal-cavity-length change

For the short-range variations of the external cavity length, the dynamic behaviors of a semiconductor laser with optical feedback are investigated by the numerical simulations and experiments. Under the condition of a single-mode oscillation, the laser output power shows periodic undulation along the external cavity length whose period is equal to half of the optical wavelength. At weak to moderate external optical feedback, stable, periodic, quasi-periodic, and chaotic oscillations of the laser output power are observed within the periodic undulation. Experimental results of periodic and quasi-periodic oscillations obtained by the laser output power and the optical spectrum support the predictions from the numerical analysis based on the rate equations     

Laparoscopic colpopoiesis using sigmoid colon

Superficial siderosis of the central nervous system (CNS) is a rare disease resulting in the accumulation of haemosiderin in the meninges, the brain surface, the spinal cord and the cranial nerves. The pigment is deposited as a result of chronic bleeding in the subarachnoid space. This produces a clinical picture of deafness, ataxia, cranial nerve deficits and in the latest stages dementia. In some cases the source of bleeding can be identified, whilst in others it can not. Despite its rarity the disease should be considered in the differential diagnosis of sensorineural deafness, particularly as it is a progressive and in some cases curable disease which is easily diagnosed by magnetic resonance imaging (MRI). In this case report the haemosiderin was derived from an ependymoma of the fourth ventricle with extension into the cerebello-pontine angle. The first symptom was a worsening sensorineural hearing loss.