Manganese ferrite-polyaniline hybrid materials: Electrical and magnetic properties

Magnetic MnFe₂O₄ nanopowders were synthesized by an original solvothermal method in the absence and in the presence of tetra-n-butylammonium bromide (TBAB) and Tween 80 (TW) as surfactants. Manganese ferrite/polyaniline (PANI) hybrid materials were synthesized by in situ polymerization of aniline on the surface of MnFe₂O₄ using ammonium persulfate as oxidant. The purpose of the study was to investigate the influence of the two surfactants on the properties of the MnFe₂O₄ powders and of their composites with PANI. The specific surface area, the cumulative surface area of pores and the cumulative volume of pores are influenced by the nature of surfactant in case of MnFe₂O₄ powders and are higher by comparison to those of the MnFe₂O₄/PANI hybrid materials. The values of saturation magnetization in case of MnFe₂O₄ powders are higher than those of the hybrid materials and are not influenced by the surfactant nature. These features revealed that MnFe₂O₄ powders can be efficiently used as adsorbents for the purification of wastewaters. The values of the electrical conductivity of the composites exhibit a significant increase in comparison to the MnFe₂O₄ powders and depend on the surfactant nature. The highest value of electrical conductivity was achieved by the composite obtained using Tween 80 as surfactant (σ_DC = 54.5·10^?5S?m^?1) which was close to that of PANI (σ_DC = 61.2·10^?5 S?m^?1). The fact that the magnetic and electric properties of the synthesized MnFe₂O₄/PANI composites can be changed by design, demonstrate the high potential of these materials to be used in magneto-electric applications.     

The contribution of proteomics towards deciphering the enigma of Coxiella burnetii

Coxiella burnetii, the causative agent of Q fever, is an intracellular bacterium and a potential weapon for bioterrorism. The widespread throughout the world, zoonosis is manifested clinically as a self-limited febrile illness, as pneumonia (acute Q fever) or as a chronic illness with endocarditis being its major complication. The recent Netherlands Q fever outbreak has driven the bacterium from a relatively cryptic, underappreciated, “niche” microorganism on the sideline of bacteriology, to one of possibly great impact on public health. Advances in the study of this microorganism proceeded slowly, primarily due to the, until recently, obligatory intracellular nature of the pathogen that in its virulent phase I must be manipulated under biosafety level-3 conditions. Proteomic studies, in particular, have generated a vast amount of information concerning several aspects of the bacterium such as virulence factors, detection/diagnostic and immunogenic biomarkers, inter-/intraspecies variation, resistance to antibiotics, and secreted effector proteins with significant clinical impact. The phenomenon observed following the genomics era, that of generation and accumulation of huge amount of data that ultimately end up unexploited on several databases, begins to emerge in the proteomics field as well. This review will focus on the advances in the field of C. burnetii proteomics through MS, attempting in parallel to utilize some of the proteomics findings by suggesting future directions for the improvement of Q fever diagnosis and therapy.     

Games to induce specified equilibria

Media access protocols in wireless networks require each contending node to wait for a backoff time, chosen randomly from a fixed range, before attempting to transmit on a shared channel. However, nodes acting in their own selfish interest may not follow the protocol. In this paper, a static version of the problem is modeled as a strategic game played by non-cooperating, rational players (the nodes). The objective is to design a game which exhibits a unique, a priori mixed-strategy Nash equilibrium. In the context of the media access problem, the equilibrium of the game would correspond to nodes choosing backoff times randomly from a given range of values, according to the given distribution. We consider natural variations of the problems concerning the number of actions available to the players and show that it is possible to design such a game when there are at least two players that each have the largest number of possible actions among all players. In contrast, we show that if there are exactly two players with different number of actions available to them, then it becomes impossible to design a strategic game with a unique such Nash equilibrium.     

Estimation of unknown speaker’s height from speech

In the present study, we propose a regression-based scheme for the direct estimation of the height of unknown speakers from their speech. In this scheme every speech input is decomposed via the openSMILE audio parameterization to a single feature vector that is fed to a regression model, which provides a direct estimation of the persons’ height. The focus in this study is on the evaluation of the appropriateness of several linear and non-linear regression algorithms on the task of automatic height estimation from speech. The performance of the proposed scheme is evaluated on the TIMIT database, and the experimental results show an accuracy of 0.053 meters, in terms of mean absolute error, for the best performing Bagging regression algorithm. This accuracy corresponds to an averaged relative error of approximately 3%. We deem that the direct estimation of the height of unknown people from speech provides an important additional feature for improving the performance of various surveillance, profiling and access authorization applications.     

Particle Swarm Optimization for Sorted Adapted Gaussian Mixture Models

Recently, we introduced the sorted Gaussian mixture models (SGMMs) algorithm providing the means to tradeoff performance for operational speed and thus permitting the speed-up of GMM-based classification schemes. The performance of the SGMM algorithm depends on the proper choice of the sorting function, and the proper adjustment of its parameters. In the present work, we employ particle swarm optimization (PSO) and an appropriate fitness function to find the most advantageous parameters of the sorting function. We evaluate the practical significance of our approach on the text-independent speaker verification task utilizing the NIST 2002 speaker recognition evaluation (SRE) database while following the NIST SRE experimental protocol. The experimental results demonstrate a superior performance of the SGMM algorithm using PSO when compared to the original SGMM. For comprehensiveness we also compared these results with those from a baseline Gaussian mixture model-universal background model (GMM-UBM) system. The experimental results suggest that the performance loss due to speed-up is partially mitigated using PSO-derived weights in a sorted GMM-based scheme.     

An overview of web accessibility in Greece: a comparative study 2004–2008

This communication reports on the results of a web accessibility audit of public Web sites in Greece. The audit was conducted in 2008 by the Human Computer Interaction Laboratory of the Institute of Computer Science of FORTH, in its capacity as the Greek National Contact Centre of the European Design for All e-Accessibility Network. In an earlier e-Accessibility study in 2004, that evaluated approximately 250 public and commercial Web sites in Greece, 73% of the sample failed to meet the most basic requirements for web accessibility (). Four years later, in the context of a re-audit, a similar sample was examined for compliance with the same web accessibility standard (WCAG 1.0), as set by the Web Accessibility Initiative of the World Wide Web Consortium. The accessibility checks were conducted during the period from March to September 2008. A comparison of the results indicates that although new web development technologies may have been employed, instead of improving the overall status of e-accessibility, this has resulted in a serious deterioration in overall accessibility levels. Such findings—85% of sites failed to comply with Level A—suggest that Greek Web sites are likely to present even more significant access barriers to people with disability than in the past. As Web Accessibility is poorly understood and, until today, new platforms have failed to deliver products that conform to WCAG, the need emerges for a concrete legislative framework to set accessibility specifications for all public Web sites in Greece.     

Cooking rice in excess water reduces both arsenic and enriched vitamins in the cooked grain

This paper reports the effects of rinsing rice and cooking it in variable amounts of water on total arsenic, inorganic arsenic, iron, cadmium, manganese, folate, thiamin and niacin in the cooked grain. We prepared multiple rice varietals both rinsed and unrinsed and with varying amounts of cooking water. Rinsing rice before cooking has a minimal effect on the arsenic (As) content of the cooked grain, but washes enriched iron, folate, thiamin and niacin from polished and parboiled rice. Cooking rice in excess water efficiently reduces the amount of As in the cooked grain. Excess water cooking reduces average inorganic As by 40% from long grain polished, 60% from parboiled and 50% from brown rice. Iron, folate, niacin and thiamin are reduced by 50–70% for enriched polished and parboiled rice, but significantly less so for brown rice, which is not enriched.     

Influence of Macromolecular Brushes with Polyimide Backbones and Poly(methyl methacrylate) Side Chains on Structure,Physical, and Transport Properties of Polyphthalamide

Composite films based on polyamide (poly(m-phenylene-iso-phthalamide)) (PA) and a brush-like polymer with polyimide (PI) backbone and side poly(methyl methacrylate) chains (PI-PMMA) were prepared by mixing individual solutions of PA and PI-PMMA and subsequent film casting. Macromolecular brushes with the same backbone length and density of side chains but with various lengths of side PMMA chains were synthesized via activator generated by electron transfer atom transfer radical polymerization. Interactions between PA and PI-PMMA, as well as distribution of PI-PMMA filler inside the PA matrix, were studied by viscometry, dynamic light scattering, differential scanning calorimetry, scanning electron microscopy, and IR spectroscopy. The mechanical properties of polymer samples were also investigated. Microphase separation was revealed in PA/PI-PMMA films. The length of side chains influences interactions between PA and PI-PMMA. At the same time, the degree of reduction in the rigidity parameters and in the elasticity parameter depends on the side chain length. Diffusion membranes were prepared on the basis of compositions with the best mechanical properties; these membranes proved to be highly efficient in pervaporation of methanol–hexane mixture. It was established that the fluxes and separation factors of the studied membranes are several times higher as compared to the corresponding characteristics of known commercial membranes. POLYM. ENG. SCI., 60:481–490, 2020. © 2019 Society of Plastics Engineers