Organofunctionalized catalyst surfaces highly active and selective for carbon–carbon bond-forming reactions

This article illustrates two types of organofunctionalized heterogeneous catalysts for variety of organic carbon–carbon bond-forming reactions, summarizing our previous reports and also presenting new data. Organic amines with an alkoxysilane moiety were immobilized on inorganic silica-alumina surfaces (SA-NR₂) by simple silane-coupling reactions between the silica-alumina surface (SA) and the alkoxysilane. This SA-NR₂ acted as acid–base bifunctional heterogeneous catalysts for carbon–carbon bond-forming reactions, such as cyano-ethoxycarbonylation, Michael reaction of nitriles, and nitro-aldol reaction. These reactions did not occur with either SA or homogeneous amine compounds. In addition, the mixture of SA and homogeneous amine showed low catalytic activity due to undesirable acid–base neutralization reaction. Achiral organic silane-coupling reagents with a variety of functional groups were also immobilized on a SiO₂ surface that had been immobilized with chiral bis(oxazoline) (BOX), to which Cu ions were coordinated to make chiral Cu–BOX complexes on the SiO₂ surface. The SiO₂-supported Cu–BOX complex catalyst functionalized with achiral 3-methacryloxypropyltrimethoxysilane dramatically increased enantioselectivity in the asymmetric Diels–Alder reaction of cyclopentadiene and 3-acryloyl-2-oxazolidinone. The organofunctionalized catalysts showed much better performances for the C–C bond-forming reactions compared to the corresponding homogeneous systems. The heterogeneous catalysts thus obtained were characterized by solid-state ¹³C and ²⁹Si MAS NMR, FT-IR, UV/vis, XAFS, ESR, XRF, and elemental analysis.     

Selective isopentane formation from CH3OH on a new one-atomic layer ZrO2/ZSM-5 hybrid catalyst

A new one-atomic layer ZrO₂/ZSM-5 hybrid catalyst was prepared by using the repeated reactions between Zr(OC₂H₅)₄ and of the OH groups of the external surfaces of ZSM-5, followed by calcination. The one-atomic layer ZrO₂ attached on the ZSM-5 surface was characterized by means of X-ray diffraction, X-ray fluorescence and EXAFS. The ZrO₂ overlayer is suggested to epitaxially grow on the ZSM-5(001) plane in a [111] direction of tetragonal ZrO₂. The one-atomic layer ZrO₂/ZSM-5 is a unique catalyst which produces selectively isopentane from CH₃OH.     

Virtual metamorphosis

The virtual metamorphosis system lets people change their forms into any other form in a virtual scene. To realize these changes, a computer vision system estimates facial expressions and body postures and reproduces them in a computer graphics avatar in real time. We introduce three systems in order of their development: the Virtual Kabuki system, Networked Theater and “Shall We Dance?”     

Family M42 aminopeptidase from the syntrophic bacterium Symbiobacterium thermophilum: characterization using recombinant protein

The chromosomal DNA of the syntrophic thermophile Symbiobacterium thermophilum contains open reading frames of the genes encoding family M42 aminopeptidases, Pep1079, Pep1080, and Pep1081. To characterize these peptidases, the genes were cloned into Escherichia coli and overexpressed. Our experiments using the recombinant proteins confirmed that Pep1079, Pep1080, and Pep1081 are components of arginyl or lysinyl aminopeptidases that require Co2+ for enzymatic activity. Coexistence of Pep1079 and Pep1080 is necessary for expressing high peptidase activity. Pep1081 enhances the activity of Pep1079 and Pep1080.     

Optimum conditions for second harmonic generation by hot-electron and electron-transfer effects in semiconductors

Optimum conditions for second harmonic generation (SHG) are derived analytically in both semiconductors with a velocity-saturation characteristic due to hot-electron effect and with an N-shaped characteristic due to electron-transfer effect. The d.c. bias fields for a maximum conversion efficiency are approximately the value of the ratio of a saturation velocity to a low-field mobility for a saturated characteristic and the value slightly less than the threshold field for an N-shaped characteristic. For a saturated characteristic, the shape closer to a rectangular gives a higher conversion efficiency. An n-type Ge is most superior to all of p-type Ge, n- and p-types Si. For an N-shaped characteristic, steeper spike shape gives a higher conversion efficiency. An n-type GaInSb is most superior to both of n-types GaAs and InP.     

Aerobic Alcohol Oxidation by Ruthenium Species Stabilized on Nanocrystalline Magnesium Oxide by Basic Ionic Liquids

The selective oxidation of various alcohols into their corresponding aldehydes and ketones was achieved by ruthenium species stabilized on the nanocrystalline magnesium oxide (NAP‐MgO) by the incorporation of choline hydroxide, a basic ionic liquid, in excellent yields. The procedure is simple, efficient and environmentally benign. The catalyst can be used for four cycles with almost consistent activity.     

Development of a measuring method for several types of programmed tool paths for NC machine tools using a laser displacement interferometer and a rotary encoder

Many circular motion measuring methods for NC machine tools have been proposed, however, the drawback common to many of these methods is the restriction on the radius size due to the short measuring range of the displacement transducers used. Moreover, most of these measurement tools are specialized, and can only perform circular test path measurements. A circularity test method using a laser displacement interferometer and a rotary encoder has been developed. The measuring method features a much longer range of motion than ordinal circular test methods such as the double ball bar (DBB) method and, therefore, the radius restriction on these measurements is greatly reduced. Moreover, this measuring system can also be used for the evaluation of positioning accuracy and other more complex test paths.

The proposed device consists primarily of a laser displacement interferometer and a rotary encoder. The holders for the interferometer head and the retroreflector are connected with a stainless steel rod. The retroreflector holder has a synthetic resin linear bearing allowing it to move relative to the interferometer head so that both optical components are always facing each other. The laser interferometer measures the change in distance between the interferometer head and the retroreflector, and the rotary encoder measures the rotation angle of the stainless steel rod.

In this paper, the background, measuring principle and apparatus structure are briefly described. The experimental setup is also presented. The apparatus was employed in several measuring experiments, including circularity tests for a vertical machining center. The results from these experiments support the validity of this measurement apparatus.     

Data Driven Cyber-Physical System for Landslide Detection

Mobile Networks and Applications - Natural disaster is one of the most important research topics worldwide. In this paper, a data driven cyber-physical system is introduced to detect landslides....