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Jean-Louis Havet Myriam Billiau-Loreau Catherine Porte Alain Delacroix 《Journal of Automated Methods and Management in Chemistry》2002,24(4):111-119
Chemometric tools were used to generate the modelling of solvent e inverted exclamation markects on the N-alkylation of an isocyanuric acid salt. The method proceeded from a central composite design applied on the Carlson solvent classification using principal components analysis. The selectivity of the reaction was studied from the production of different substituted isocyanuric derivatives. Response graphs were obtained for each compound and used to devise a strategy for solvent selection. The prediction models were validated and used to search for the best selectivity for the reaction system. The solvent most often selected as the best for the reaction is the N,N-dimethylformamide. 相似文献
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Jacky Porte 《电信纪事》1992,47(3-4):153-158
A discrete optimization method using a noninteraction property between the different sections of cascade switched-capacitor filter is described. The optimization, realized with a reduced set of intermediate parameters caracterizing each section, yields to a non minimum capacitive area structure, but which has very accurate capacitor ratios and which could be realized with minimum unit capacitors. This method may be applied to switched-current filters (aspect ratios of transistor discretization). An eighth order band-pass Cauer filter and a fifth order low-pass Cauer filter show the effectiveness of this method. 相似文献
6.
Constant L. Ruiz P. Abel M. Robach Y. Porte L. Bertolini J.C. 《Topics in Catalysis》2000,14(1-4):125-129
The catalytic properties, with respect to the 1,3-butadiene hydrogenation reaction, of strained Pd films on Cu(110) (lattice mismatch 8%) has been probed as a function of the film thickness. The characterization of the adlayer has been made by the combined use of STM with LEED and AES. For deposits below 1015 Pd/cm2 (i.e., about 1 ML) the catalytic activity is near zero. This is the consequence of the formation of a Pd–Cu surface alloy with tendency for Cu to migrate/segregate to the surface. The catalytic activity suddenly increases to reach a maximum value for about 3 ML; the activity is then one order of magnitude higher than that of the pure Pd(110) surface. This is the consequence of the presence of a strained Pd overlayer, with Pd surface atoms having very unusual geometry, and hence very peculiar electronic and chemical properties. The catalytic activity then decreases as the Pd coverage is increased, and tends to values near that of the pure Pd(110). Gradual relaxation of the film geometry towards that of the normal fcc Pd structure probably exists. 相似文献
7.
Jacques Auger Chantal Lecomte Jacky Paris Eric Thibout 《Journal of chemical ecology》1989,15(4):1391-1398
Acrolepiopsis assectella andPlutella xylostella frass volatiles, trapped on Tenax GC, were examined by capillary gas chromatography. In both moths, the same three disulfides, dimethyl, dipropyl, and methyl propyl, were the most abundant substances, but in different proportions. The synthetic disulfides elicited the same behavioral response by the parasitoid,Diadromus pulchellus as frass. The plant origin of these substances is discussed. 相似文献
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Analogy based estimation (ABE) generates an effort estimate for a new software project through adaptation of similar past projects (a.k.a. analogies). Majority of ABE methods follow uniform weighting in adaptation procedure. In this research we investigated non-uniform weighting through kernel density estimation. After an extensive experimentation of 19 datasets, 3 evaluation criteria, 5 kernels, 5 bandwidth values and a total of 2090 ABE variants, we found that: (1) non-uniform weighting through kernel methods cannot outperform uniform weighting ABE and (2) kernel type and bandwidth parameters do not produce a definite effect on estimation performance. In summary simple ABE approaches are able to perform better than much more complex approaches. Hence,—provided that similar experimental settings are adopted—we discourage the use of kernel methods as a weighting strategy in ABE. 相似文献
9.
Nicolas Prat Jacky Akoka Isabelle Comyn-Wattiau 《Expert systems with applications》2012,39(12):10420-10437
This paper proposes an MDA approach to knowledge engineering, centered on the CommonKADS knowledge model. The latter corresponds to the CIM level of MDA whereas PRR, which represents production rules and rulesets, corresponds to the PIM level. The paper explores the mapping between CommonKADS knowledge models and production rules and rulesets based on PRR. Mapping CommonKADS knowledge models into PRR is very useful, due to the fact that the CIM level remains relatively unexplored, despite its key role in MDA. This motivates our choice to focus on the CIM and PIM levels. Furthermore, the mapping between PIM and PSM (i.e. the implementation of production rules in specific rule-based systems) constitutes less of an issue. To map CommonKADS knowledge models into PRR production rules and rulesets, we propose and illustrate a set of transformations. To ease these transformations, we start by grouping elements of the CommonKADS knowledge models into so-called “inference groups”. We propose and illustrate an algorithm that defines these inference groups automatically. The definition of transformations between models (CIM to PIM levels) requires a specific metamodel for CommonKADS as well as a dedicated metamodel for PRR. Unlike PRR, there is no published CommonKADS metamodel. This paper proposes a comprehensive CommonKADS knowledge metamodel. We describe and discuss an example, applying the whole approach. 相似文献
10.
Tuyet Le-Anh Jorge Villalobos Jacky Estublier 《Electronic Notes in Theoretical Computer Science》2003,82(5):164
Reusability is the holly grail of software engineers. But reusability requires powerful composition mechanisms since the pieces to compose have no reason to match perfectly. Unfortunately, the composition mechanisms available today, mostly method call and component assembly are rather primitive. This paper shows what is the current state of the art in software composition, showing that there is little composition flexibility at code level, even using workflow approaches.The approach presented here claims that composition requires reasoning at different levels of abstraction. Workflow support is first decoupled from real tools, using abstract tool modeling. Contracts have been included to increase the independence between process and tools. Then, we have introduced conceptual abstractions linked by contract to real tools. Finally, we show that it is possible to define composition at the abstract level.The resulting system shows very high adaptability capabilities. Experience shows, however, that to be practical, this approach requires adapted framework and specialized tools. This paper shows the experience gained in implementing many versions of such a framework. The current system is currently in industrial use. 相似文献