Textile‐surface interfacial asymmetric polymerization

This research demonstrated that polymerization of aniline on cellulose produces chiroptically active composites. Polymerization of aniline in the presence of cotton fibers consisting of chiral cellulose are performed to prepare a polyaniline (PANI)/cotton composite. The polymerization is conducted at the cotton interface. The resultant PANI/cotton composite shows chiroptical activity elucidated with diffuse reflectance circular dichroism. In this reaction, textile‐surface interfacial asymmetric polymerization is performed with imprinting of chiral structure from the cotton as a natural chiroptically active polymer to the PANI. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41118.     

Thermally Controlled,Patterned Graphene Transfer Printing for Transparent and Wearable Electronic/Optoelectronic System

Graphene has been highlighted as a platform material in transparent electronics and optoelectronics, including flexible and stretchable ones, due to its unique properties such as optical transparency, mechanical softness, ultrathin thickness, and high carrier mobility. Despite huge research efforts for graphene‐based electronic/optoelectronic devices, there are remaining challenges in terms of their seamless integration, such as the high‐quality contact formation, precise alignment of micrometer‐scale patterns, and control of interfacial‐adhesion/local‐resistance. Here, a thermally controlled transfer printing technique that allows multiple patterned‐graphene transfers at desired locations is presented. Using the thermal‐expansion mismatch between the viscoelastic sacrificial layer and the elastic stamp, a “heating and cooling” process precisely positions patterned graphene layers on various substrates, including graphene prepatterns, hydrophilic surfaces, and superhydrophobic surfaces, with high transfer yields. A detailed theoretical analysis of underlying physics/mechanics of this approach is also described. The proposed transfer printing successfully integrates graphene‐based stretchable sensors, actuators, light‐emitting diodes, and other electronics in one platform, paving the way toward transparent and wearable multifunctional electronic systems.     

Modeling L2 Writer Voice: Discoursal Positioning in Fanfiction Writing

Of various online discourses, distinctive design features of fanfiction discourse have given rise to a new social space that holds great potential for the negotiation of identity. In this study, I propose that fanfiction discourse creates a social space that helps shape the voice construction of the L2 writer. In order to understand how the L2 writer's multiple social positions within fanfiction discourse affect voice construction, I analyze a popular online culture-based writing website, <www.fanfiction.net>. Three dominant design features are identified that allow various forms of participation and levels of engagement by its members: intertextuality, dialogic interaction, and electronic text. These three features are actualized in three different positionings (ideational, interpersonal, and textual) that Ivani? and Camps (2001) believe writers take on when constructing a voice. Results suggest that the two L2 participants in my study created voices in multiple positionings made available by re-purposing a pop-culture storyline or characters, communication with audiences, and digital resources. Overall, this study offers a nuanced view of how voice is projected and negotiated within the intersections of multiple online discourses and how it relates to L2 writing in the digital era.     

Biocomputing with Nanostructures on Lipid Bilayers

Biocomputation is the algorithmic manipulation of biomolecules. Nanostructures, most notably DNA nanostructures and nanoparticles, become active substrates for biocomputation when modified with stimuli‐responsive, programmable biomolecular ligands. This approach—biocomputing with nanostructures (“nano‐bio computing”)—allows autonomous control of matter and information at the nanoscale; their dynamic assemblies and beneficial properties can be directed without human intervention. Recently, lipid bilayers interfaced with nanostructures have emerged as a new biocomputing platform. This new nano‐bio interface, which exploits lipid bilayers as a chemical circuit board for information processing, offers a unique reaction space for realizing nanostructure‐based computation at a previously unexplored dimension. In this Concept, recent advances in nano‐bio computing are briefly reviewed and the newly emerging concept of biocomputing with nanostructures on lipid bilayers is introduced.     

Tone Dual‐Channel MAC Protocol with Directional Antennas for Mobile Ad Hoc Networks

The directional medium access control (MAC) protocol improves the throughput of mobile ad hoc networks but has a deafness problem and requires location information for neighboring nodes. In the dual‐channel directional MAC protocol [12], the use of omnidirectional packets does not require the exact location of destination node. In this letter, we propose a tone dual‐channel MAC protocol with directional antennas to improve the throughput of mobile ad hoc networks. In the proposed MAC protocol, we use a directional CTS and an out‐of‐band directional DATA tone with a new blocking algorithm to improve the spatial reuse. We confirm the throughput performance of the proposed MAC protocol by computer simulations using the Qualnet simulator.     

Amyloid‐β Aggregation with Gold Nanoparticles on Brain Lipid Bilayer

Understanding and manipulating amyloid‐β (Aβ) aggregation provide key knowledge and means for the diagnosis and cure of Alzheimer's disease (AD) and the applications of Aβ‐based aggregation systems. Here, we studied the formation of various Aβ aggregate structures with gold nanoparticles (AuNPs) and brain total lipid extract‐based supported lipid bilayer (brain SLB). The roles of AuNPs and brain SLB in forming Aβ aggregates were studied in real time, and the structural details of Aβ aggregates were monitored and analyzed with the dark‐field imaging of plasmonic AuNPs that allows for long‐term in situ imaging of Aβ aggregates with great structural details without further labeling. It was shown that the fluid brain SLB platform provides the binding sites for Aβ and drives the fast and efficient formation of Aβ aggregate structures and, importantly, large Aβ plaque structures (>15 μm in diameter), a hallmark for AD, were formed without going through fibril structures when Aβ peptides were co‐incubated with AuNPs on the brain SLB. The dark‐field scattering and circular dichroism‐correlation data suggest that AuNPs were heavily involved with Aβ aggregation on the brain SLB and less α‐helix, less β‐sheet and more random coil structures were found in large plaque‐like Aβ aggregates.     

Interleaved TC 8DPSK/OFDM with decision-directed channel estimationon frequency-selective Rayleigh fading channels

Trellis-coded modulation (TCM) is a power and bandwidth efficient signaling scheme. In this letter, we propose interleaved trellis-coded (TC) 8DPSK/OFDM combined with decision-directed (DD) channel estimation on frequency-selective Rayleigh fading channels. We use a subchannel block interleaver in an OFDM symbol interval to randomize the burst errors due to the correlated dispersive fading channel. We also use DD channel estimation using the previous detected 8DPSK symbols in the temporal direction to improve the performance at fast fading. Computer simulations show that the proposed technique has good performance at fast fading