Ferroelectric-Paraelectric Phase Transition in Lead Titanate Containing Lattice Defects

A series of lead titanates containing lattice defects was prepared and characterized in terms of inhomogeneously distributed vacancies, □_Pb and □_O•. The tetragonal lattice strain and the Curie temperature varied as functions of the Pb or O deficiency in the crystals. The tetragonal strain for these crystals decreased slowly with increasing temperature as the Curie temperature was approached. The phase transition, which extends over a temperature interval, is interpreted according to a model in which microregions in the crystal differ in composition and therefore have different Curie temperatures.     

IMPLICATE FINAL CAUSES IN DEVELOPING MATERIAL SYSTEMS

Abstract

Causality in changing natural systems can be seen to involve all four Aristotelian causal categories—material, efficient, formal and final. Final causality of materialistic origin can be found in the need to maintain energy flow continuity within dissipative systems. Each interacting dissipative system acts finalistically so as to attract needed energy. In so acting, it continually disturbs its neighborhood by generating potential energy flow disruptions as results of its activities. Final causality based, in this way, on the energy requirements of dissipative systems will generate formal causes as well. In contrast, the emergence of formal causes in mechanistic systems driven solely by efficient causes is extremely unlikely. We suggest viewing the subordination of phenotypic dissipative systems by genotypic counterparts as an historical example of the emergence of formal causes out of the material necessity of maintaining flow continuity. Functional separation between genotypic and phenotypic dissipative systems can occur if the energies to be dissipated are localized, as is the chemical binding energy of molecules with respect to biological functions at a higher scalar level.     

钢铁中多元夹杂物颗粒的三维评估

为了从钢铁中提取各种夹杂物颗粒,考察了采用无水电解质的恒电位和恒电流的提取方法。结果认为,4%的MS［4 % （V/V）甲基水杨酸-1 % （m/V） 水杨酸-1 %（ m/V） 四甲基氯化铵-甲醇）和10%AA（10 %(V/V)乙酰丙酮-1 % （m/V）四甲基氯化铵-甲醇］电解质溶液适用于提取钢铁中夹杂物TiO_{x和TiAl2O5。尽管这些电解提取法可以提取化学性能不稳定的夹杂物颗粒,然而,因为对夹杂物的观察是在萃取完成后于一个滤膜中进行,因此无法确定金属中每种夹杂物的具体位置。为了确定金属中夹杂物的具体位置,将卤-醇的光蚀刻方法用于以Ti和Al除氧的钢样品表面附近出现的夹杂颗粒,使用扫描电子显微技术和俄歇电子能谱（AES）对精细夹杂物颗粒形貌、尺寸和元素的偏析进行评估,不过卤醇却和钢铁中的金属钛和金属铝发生还原反应。对微小夹杂物颗粒的成分的形态、分离进行估测,然后,使用一种低加速能-扫描电子显微技术和俄歇电子能谱（AES）对用聚焦离子束制备微小夹杂物颗粒截面上元素的微观偏析进行评定。在这些研究结果基础上讨论了多元夹杂物颗粒的形成机理。}     

Lamb wave device using PbZrO3-based ceramic substrate

A Lamb wave device using a PbZrO₃ abased piezoelectric ceramic substrate and its application to an oscillator are described. The Lamb wave device which is practically in single-mode operation uses the zeroth-order symmetrical (S₀ ) mode. A delay line oscillator is composed of the S₀ mode device, an amplifier and an electrically controllable phase shifter, whose oscillation frequency varies with the applied voltage. The oscillator has fine frequency modulation characteristics in a wide frequency range from DC to 100 kHz. The device performance is useful for FM signal processing or voltage sensing.