Electrochemical studies of n-Cd1−xMnxSe thin film photodetector

Studies on dilute semimagnetic semiconductor thin films are of immense importance. Coupled with their semiconducting properties, they have the characteristic magnetic properties, which make them an attractive alternative in a variety of electronic and optoelectronic devices including gas sensors and solar energy conversion devices. The basic materials are cheap and the actual material can easily be obtained from an aqueous alkaline medium (pH=10.5±0.2) by deposition of Cd²⁺, Mn²⁺ and Se^2– ions. The temperature and time for deposition were optimized as 50 °C and 120 min, respectively. The deposits were adherent to the substrate support, uniform and smooth with color changing from deep orange red to yellowish orange as Mn²⁺ concentration was varied from 0 to 0.5. The electrochemical detector cells were formed out of these series of films as the active photoelectrodes, an electrolyte and a counter electrode and were characterized through their electrical properties. A short circuit current (I _sc) of 147 A/cm² and open circuit voltage (V _oc) 468 mV were noticed at x=0.1 under a steady illumination intensity of 20 mW/cm². The calculated conversion efficiency (%) approached to 0.13% whereas the maximum cell fill factor is 38.45%. These electrochemical detectors exhibited a considerable amount of recombination and series resistance effects.     

Header Detection to Improve Multimedia Quality Over Wireless Networks

Wireless multimedia studies have revealed that forward error correction (FEC) on corrupted packets yields better bandwidth utilization and lower delay than retransmissions. To facilitate FEC-based recovery, corrupted packets should not be dropped so that maximum number of packets is relayed to a wireless receiver's FEC decoder. Previous studies proposed to mitigate wireless packet drops by a partial checksum that ignored payload errors. Such schemes require modifications to both transmitters and receivers, and incur packet-losses due to header errors. In this paper, we introduce a receiver-based scheme which uses the history of active multimedia sessions to detect transmitted values of corrupted packet headers, thereby improving wireless multimedia throughput. Header detection is posed as the decision-theoretic problem of multihypothesis detection of known parameters in noise. Performance of the proposed scheme is evaluated using trace-driven video simulations on an 802.11b local area network. We show that header detection with application layer FEC provides significant throughput and video quality improvements over the conventional UDP/IP/802.11 protocol stack     

Cotton linter nano-fibers as the potential reinforcing agent for guar gum

Cotton linter nano-fibers (CLNFs) were prepared from cotton linters by a refining process. The prepared CLNFs were characterized for morphology, crystallinity and degree of polymerization. CLNF was used as a reinforcing agent in guar gum to improve its performance properties. Guar gum/CLNF nanocomposite films were prepared by a solution-casting process. CLNF was added in concentrations of 0.1, 0.25, 0.5 and 1.0 % (w/w) in guar gum. The prepared guar gum/CLNF nano-composite films were characterized for mechanical, thermal, rheological, crystallinity, water vapor transmission rate (WVTR) and light transparency properties. The enthalpy of melting and melting temperature of guar gum increased with increased concentration of CLNF; but up to 0.25 % (w/w) concentration, above which they started decreasing. Tensile strength and Young’s modulus of guar gum increased by 32 and 35 %, respectively, by 0.25 % (w/w) addition of CLNF; however, it decreased on further increase in the concentration of CLNF. The percentage elongation at break and WVTR decreased by 58 and 57 % for 0.25 % (w/w) CLNF-added guar gum. The observed improvements in the properties were due to better interaction between CLNF and guar gum. CLNF was found to have uniformly dispersed in guar gum on addition up to 0.25 % concentration; however, it started forming aggregates at higher concentration, as evident from scanning electron microscopy. Viscosity increased, whereas transparency decreased with increased concentration of CLNF in guar gum.     

Three sibs with mild variety of osteopetrosis

We report three sibs with mild autosomal recessive variety of osteopetrosis. The prominent clinical features were short stature, malocclusion of teeth, hepatosplenomegaly and a typical facial appearance. The only atypical features were microcephaly, a normal upper segment to lower segment ratio and a normal arm span.     

A study of cadmium mercury telluride (CMT) thin film structures: some physical observations and characteristics

Polycrystalline thin film structures of the form Cd_1?x Hg _x Te (0 ≤ x ≤ 0.5) were obtained on ultrasonically cleaned glass substrates in an alkaline medium (pH≈ 10 ± 0.2) at 80^°C. The forerunner solutions were obtained from the equimolar solutions of CdCl₂, HgCl₂ and 0.33 M-refluxed Na₂TeSO₃. The preparation parameters such as temperature, pH, deposition time and speed of mechanical stirring were optimized. The as-prepared samples were tightly adherent to the substrate support, less smooth, diffusely reflecting and were analysed for composition. It appeared that incorporation of Hg²⁺ in the lattice of CdTe replaced divalent Cd²⁺ predominantly. However, a small amount of Te^2? replacement by Hg²⁺ ions has also been observed at higher levels of Hg in CdTe (> 0.1 mol. %). The samples were then characterized optically to determine the absorption coefficient, mode of optical transition and the optical bandgaps. The estimated band-gap decreased, typically from 1.51 to 0.83 eV as Hg content in CdTe was increased from 0 to 0.5. The dc electrical conductivity measurements were made in the temperature range from 300 to 550 K and it was observed that the conductivity increased rapidly up to x = 0.1 and thereafter remained more or less the same. The thermopower measurements showed n-type conduction of these films. Both carrier concentration (n) and mobility (μ) were computed from these studies and found to be dependent on the working temperature and the film composition. The surface morphologies of these as-grown layers were then observed via a scanning electron microscope. CdTe crystals are more or less crystalline spherical and hexagonal prismatic in shape whereas HgCdTe samples appear glassy and show hexagonal prismatic whiskers, some less frequent forms of needles.     

Secure data processing for IoT middleware systems

The Journal of Supercomputing - Increasingly, more manufacturing companies are equipping their products with smart capabilities which allow them to provide more informed services to customers....     

Hybrid Erasure-Error Protocols for Wireless Video

Many recently proposed cross-layer protocols for wireless video, have advocated the relay of corrupted packet to higher layers. Such protocols lead to both errors and erasures at the compressed video application layer. We generically refer to such schemes as hybrid erasure-error protocols (HEEPs). In this paper, we analyze the utility of HEEPs for efficient transmission of video over wireless channels. In order to maintain the generic nature of the deductions in this paper, we base our analysis on two (rather abstract) communication schemes for wireless video: hybrid error-erasure cross-layer design (CLD) and hybrid error-erasure cross-layer design with side-information (CLDS). We make a comparative analysis of the channel capacities of these schemes over single and multi-hop wireless channels to identify the conditions under which the HEEPs can provide improved performance over conventional (CON) protocols. In addition, we employ Reed Solomon (RS) and low-density parity check (LDPC)-code-based forward-error correction (FEC) schemes to illustrate that the improvement in capacity can easily enable an FEC scheme employed in conjunction with a HEEP to provide improved throughput. Finally we compare the performance of CON, CLD, and CLDS in terms of video quality using the H.264 video standard. The simulation results show a significant advantage for the HEEPs     

Optimal Unicast Capacity of Random Geometric Graphs: Impact of Multipacket Transmission and Reception

We establish a tight max-flow min-cut theorem for multi-commodity routing in random geometric graphs. We show that, as the number of nodes in the network n tends to infinity, the maximum concurrent flow (MCF) and the minimum cut-sparsity scale as θ(n²r³(n)/k), for a random choice of k = ω(n) source-destination pairs, where n and r(n) are the number of nodes and the communication range in the network respectively. The MCF equals the interference-free capacity of an ad-hoc network. We exploit this fact to develop novel graph theoretic techniques that can be used to deduce tight order bounds on the capacity of ad-hoc networks. We generalize all existing capacity results reported to date by showing that the per-commodity capacity of the network scales as θ(1/r(n)k) for the single-packet reception model suggested by Gupta and Kumar, and as θ(nr(n)/k) for the multiple-packet reception model suggested by others. More importantly, we show that, if the nodes in the network are capable of (perfect) multiple-packet transmission (MPT) and reception (MPR), then it is feasible to achieve the optimal scaling of θ(n²r³(n)/k), despite the presence of interference. In comparison to the Gupta-Kumar model, the realization of MPT and MPR may require the deployment of a large number of antennas at each node or bandwidth expansion. Nevertheless, in stark contrast to the existing literature, our analysis presents the possibility of actually increasing the capacity of ad-hoc networks with n even while the communication range tends to zero!     

Placental protein 14 in endometrium during menstrual cycle and effect of early luteal phase mifepristone administration on its expression in implantation stage endometrium in the rhesus monkey

Placental protein 14 (PP14) is a glycoprotein which is secreted by secretory phase endometrium and decidua in women. Despite the suggestion that PP14 is involved in the process of endometrial maturation for blastocyst implantation, our understanding in this regard is poor. In the present study, the concentrations and distribution patterns of immunodetectable PP14 in the endometrium during proliferative and secretory phases of normal ovulatory menstrual cycles, as well as in implantation stage endometrium in naturally mated ovulatory cycles with or without early luteal phase mifepristone treatment, were investigated using the rhesus monkey as a primate model. Immunopositive PP14 was observed mainly in epithelial cells of glands and it was detected in one major immunopositive band at Mr 28 kDa in tissue homogenate and spent medium. The area of immunopositive precipitation of PP14 in glands was minimal in follicular phase endometrium, and was higher (P < 0.01) in early, mid- and late luteal phase endometrium compared with that in pre- and periovulatory phases of the cycle, but there was no change in its area profile in the glandular compartment throughout the luteal phase. Immunopositivity for PP14 in luminal contents of gland displayed an increasing profile from early to late secretory phases. Thus, the concentrations and the distribution of immunodetectable PP14 in luteal phase endometrium of the rhesus monkey showed marked similarity with those of human endometrium during the natural menstrual cycle. Although there was no marked change in the band characterstics for the protein in implantation stage endometrium following early luteal phase mifepristone treatment, it was markedly decreased (P < 0.01) in tissue homogenate and in vitro spent medium along with a lesser (P < 0.02) degree of immunoprecipitation in the glands in implantation stage samples of mifepristone treatment group compared with that in control group samples. Thus, the contragestional effect of early luteal phase mifepristone treatment appears to be associated with a decrease in the concentration of immunodetectable PP14 in implantation stage endometrial glands and its secretion in the rhesus monkey. It remains to be seen whether this decline is caused from direct antiprogesterone action on endometrial glands during progesterone dominance, or secondarily from associated retarded development of endometrium.     

A high‐throughput assay for screening modifiers of calcium oxalate crystallization

Controlling crystal habit using growth modifiers provides novel avenues for tailoring properties of crystalline materials. Here, we report on the design of a high‐throughput screening assay for rapid identification of growth modifiers using calcium oxalate monohydrate crystallization as a model system. We conducted a systematic study of assay parameters (sample volume, shaking, and temperature) on crystallization kinetics. Crystallization half‐time (t_1/2), defined as the time at which crystallization is 50% complete, was obtained from the logistic fit of kinetic data and used as a measure of growth modifier potency. A test library of 13 peptides composed of aspartic acid and alanine residues was screened to determine their growth promotion or inhibition potentials. Leads identified from this study are in good agreement with ion‐selective electrode measurements and a single time point measurement of free calcium ion concentration is an excellent end‐point for evaluating modifier potency. © 2016 American Institute of Chemical Engineers AIChE J, 62: 3538–3546, 2016