Approaches to controlled polymerization of methyl acrylate through functional anionic initiators

Summary Controlled living polymerization of methyl acrylate has been achieved at room temperature using functional carbanionic initiators in THF solvent. Methyl acrylate oligomers with reactive chain ends have been synthesized.NCL Communication No. 4990     

A simple Cooperative diversity method based on network path selection

Cooperative diversity has been recently proposed as a way to form virtual antenna arrays that provide dramatic gains in slow fading wireless environments. However, most of the proposed solutions require distributed space-time coding algorithms, the careful design of which is left for future investigation if there is more than one cooperative relay. We propose a novel scheme that alleviates these problems and provides diversity gains on the order of the number of relays in the network. Our scheme first selects the best relay from a set of M available relays and then uses this "best" relay for cooperation between the source and the destination. We develop and analyze a distributed method to select the best relay that requires no topology information and is based on local measurements of the instantaneous channel conditions. This method also requires no explicit communication among the relays. The success (or failure) to select the best available path depends on the statistics of the wireless channel, and a methodology to evaluate performance for any kind of wireless channel statistics, is provided. Information theoretic analysis of outage probability shows that our scheme achieves the same diversity-multiplexing tradeoff as achieved by more complex protocols, where coordination and distributed space-time coding for M relay nodes is required, such as those proposed by Laneman and Wornell (2003). The simplicity of the technique allows for immediate implementation in existing radio hardware and its adoption could provide for improved flexibility, reliability, and efficiency in future 4G wireless systems.     

Secure Broadcasting Over Fading Channels

We study a problem of broadcasting confidential messages to multiple receivers under an information-theoretic secrecy constraint. Two scenarios are considered: 1) all receivers are to obtain a common message; and 2) each receiver is to obtain an independent message. Moreover, two models are considered: parallel channels and fast-fading channels. For the case of reversely degraded parallel channels, one eavesdropper, and an arbitrary number of legitimate receivers, we determine the secrecy capacity for transmitting a common message, and the secrecy sum-capacity for transmitting independent messages. For the case of fast-fading channels, we assume that the channel state information of the legitimate receivers is known to all the terminals, while that of the eavesdropper is known only to itself. We show that, using a suitable binning strategy, a common message can be reliably and securely transmitted at a rate independent of the number of receivers. We also show that a simple opportunistic transmission strategy is optimal for the reliable and secure transmission of independent messages in the limit of large number of receivers.     

Thiol modification of difunctional castor oil and its utility as room temperature setting elastomeric material

Difunctional castor oil has been reacted with thioglycolic acid for the synthesis of castor oil dithioglycolate (CODT). Elastomeric products have been obtained from CODT alone and in combination with liquid polysulfide polymer LP-33 by oxidative cure with manganese dioxide. Semireinforced (SRF) carbon black has been used as a filler. CODT has also been evaluated as a flexibilizer for liquid epoxy resin (Synpol 200).     

Carbon Copying Onto Dirty Paper

A generalization of the problem of writing on dirty paper is considered in which one transmitter sends a common message to multiple receivers. Each receiver experiences on its link an additive interference (in addition to the additive noise), which is known noncausally to the transmitter but not to any of the receivers. Applications range from wireless multiple-antenna multicasting to robust dirty paper coding. We develop results for memoryless channels in Gaussian and binary special cases. In most cases, we observe that the availability of side information at the transmitter increases capacity relative to systems without such side information, and that the lack of side information at the receivers decreases capacity relative to systems with such side information. For the noiseless binary case, we establish the capacity when there are two receivers. When there are many receivers, we show that the transmitter side information provides a vanishingly small benefit. When the interference is large and independent across the users, we show that time sharing is optimal. For the Gaussian case, we present a coding scheme and establish its optimality in the high signal-to-interference-plus-noise limit when there are two receivers. When the interference power is large and independent across all the receivers, we show that time-sharing is again optimal. Connections to the problem of robust dirty paper coding are also discussed