Photocatalytic activity of a new composite material of Fe (III) oxide nanoparticles wrapped by a matrix of polymeric carbon nitride and amorphous carbon

Polymeric carbon nitride was synthesized from urea and doped with Cu and Fe to act as co-catalysts. The material doped with Fe was a new composite material composed of Fe(III) oxides (acting as a co-catalyst) wrapped by the polymer layers and amorphous carbon. Furthermore, the copper doped material was described in a previous report. The photocatalytic degradation of the azo dye direct blue 1 (DB) was studied using as photocatalysts: pure carbon nitride (CN), carbon nitride doped with Cu (CN-Cu) and carbon nitride doped with Fe (CN-Fe). The catalysts were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), by X-ray photoelectron spectroscopy (XPS) and Brunauer–Emmett–Teller method (BET), etc. The adsorption phenomenon was studied using the Langmuir and Freundlich models. For the kinetic study, a solution of 500 mg L^?1 of DB1 was treated with each catalyst, visible light and H₂O₂. The dye concentration was measured by spectrophotometry at the wavelength of 565 nm, and the removal of the total organic content (TOC) was quantified. BET analysis yielded surface areas of 60.029, 20.116 and 70.662 m²g^?1 for CN, CN-Cu and CN-Fe, respectively. The kinetics of degradation were pseudo-first order, whose constants were 0.093, 0.039 and 0.110 min^?1 for CN, CN-Cu and CN-Fe, respectively. The total organic carbon (TOC) removal reached the highest value of 14.46% with CN-Fe.     

Narrow-FSK optical packet labeling scheme for optical ethernet networks

In this work, an intensity modulation/frequency-shift keying (IM/FSK) orthogonal modulation scheme is achieved by direct modulation of a distributed feedback laser source using its adiabatic chirp characteristics. Optical frequencies for "1" and "0" bits are separated only 0.7 GHz, obtaining a narrow-FSK modulation and, accordingly, a low residual intensity modulation. Ethernet frames at 1.25 Gb/s (GbE) are transmitted with a label inserted using coded mark inversion codification at a 155-Mb/s rate. Error rates for the Ethernet payload and for the label have been measured for different payload extinction ratios, showing the viability of this scheme for distances up to 25 km.     

Synthesis and characterization of Cu-doped polymeric carbon nitride

Polymeric carbon nitride doped with copper through a solid-state reaction was characterized by several techniques, among them are UV-visible spectroscopy, infrared spectroscopy, X-ray photoelectron spectroscopy, etc. The material is a semiconductor with a wide band gap of 2.74 eV. Sites of both Cu(I) and Cu(II) were detected, apparently only coordinated by the polymer. The material comprises crumpled nanosheets, and is substantially an amorphous layered material with a prevalent 2D structure with low inter-planar interactions, as shown by X-ray diffractometry and TeraHertz spectroscopy. Photo-oxidation of benzyl alcohol was used to probe the active sites of the material, comparing them with the non-doped material. The higher activity and selectivity toward salicylic alcohol of the non-doped material can be due to both a more localized electron transfer and a longer lifetime of the hole–electron pair. Cu-CN favored the oxidation of hydroxymethyl group. Therefore, the presence of copper can favor different reaction pathways with respect to the non-doped material.     

Assessment of heavy metal levels in Almendares River sediments--Havana City, Cuba

The Almendares River watershed covers a large portion of Havana, Cuba and is centrally important to both recreational and other activities in the region. In order to assess current water quality conditions prior to planned remediation efforts, the spatial distribution of six heavy metals and other compounds were determined in river sediments at fifteen sampling stations in the watershed. Metal concentrations in sediments ranged from 86.1 to 708.8 for Zn, 39.3 to 189.0 for Pb, 71.6 to 420.8 for Cu, 84.4 to 209.7 Cr, 1.5 to 23.4 for Co, and 1.0 to 4.3 for Cd microg/g dry weight sediment. Calculated enrichment factors (EF; measured metal versus background mineral conditions) were almost always greater than 1.0, suggesting significant anthropogenic impact on metal levels in the river. The highest EF values were seen immediately below Cotorro (EF>10 for Pb, Cu, and Cd), a suburban town that has an active secondary smelter, and below the largest municipal landfill in Havana (EF>10 for Pb, Cu, Cd, and Zn). Further, three sampling stations had multiple metals at concentrations higher than probable effects concentrations (PEC), implying possible local ecotoxicological impacts. Finally, sequential extractions of the sediments indicated that heavy metals were largely associated with the organic fraction, and it was estimated that up to 62% of metals in the sediments would be susceptible to release back into the water column if hydraulic or other changes occurred in the river. These data are being used to prioritize decisions related to the remediation of the river system.     

Hydrogen production by co-cultures of Clostridium butyricum and Rhodospeudomonas palustris: Optimization of yield using response surface methodology

Both dark and photo-fermentation can be used for biological hydrogen production; either performed separately, in two-stage systems, or in co-culture. A single stage process is less laborious and costly; however, the two types of microorganisms have different nutritional requirements requiring optimization of culture conditions. Here a response surface methodology (RSM) with a Box-Behnken design was used to optimize microorganism ratio and substrate and buffer concentrations, and to evaluate their interactive effects for maximization of hydrogen yield. Clostridium butyricum and Rhodopseudomonas palustris were grown on a potato starch/glucose base medium at 30 °C under continuous illumination (40 W m^?2 light intensity). The highest hydrogen yield, 6.4 ± 1.3 mol H₂/mol glucose, was obtained with a substrate concentration of 15 g/L, buffer concentration of 50 mM, and microorganism ratio of 3. The observed strong interaction between buffer and substrate concentration is most likely due to the need to optimize the pH for co-cultures.     

Electrothermally Actuated RF MEMS Switches Suspended on a Low-Resistivity Substrate

This paper presents an electrothermally actuated lateral resistive-contact switch for application to low-gigahertz-band communication systems. It was manufactured on a standard low-resistivity substrate, and its RF performance was improved by suspending the structures 25 mum from the substrate, which is a strategy for future integration with active devices in the system-on-chip concept. Measured insertion losses are -0.26 dB at 1 GHz and -0.65 dB at 6 GHz, return losses are -29 dB at 1 GHz and -25 dB at 6 GHz, and isolations are -52 dB at 1 GHz and -26 dB at 6 GHz. The device is driven by a metal electrothermal actuator, which achieves large displacements and contact forces at much lower temperatures than traditional polysilicon electrothermal actuators. The RF power handling characteristics are also addressed and measured.     

Modeling, characterization, and experimental/numerical comparisonof signal and fluorescence amplification in Ti,Er:LiNbO3waveguides

A complete model for signal and fluorescence amplification in Ti,Er:LiNbO₃ waveguides under 1480 and 980 nm excitation, which includes transitions involving high energy levels, is presented. Most of the waveguide parameters that the model requires have been determined or checked in situ. In order to numerically solve the proposed model, the overlapping factors method has been adapted to these waveguides and improved, obtaining a large computing time reduction with sufficiently accurate results. Finally, results from signal gain and ASE spectral measurements and numerical simulations have been compared. The remarkable agreement confirms both the model assumptions and the used characterization techniques. Moreover, the unusually short computing time which is consumed makes the model suitable for design and optimization processes     

In situ measurement of absorption and emission cross sections in Er3+-doped waveguides for transitions involving thermalizedstates

An application to transitions involving thermalized states of a procedure based on the McCumber theory to determine emission and absorption cross sections in waveguides from transversal fluorescence spectra is presented. The procedure is tested in Er-doped Ti:LiNbO₃ waveguides to provide accurate cross-section values for the recently attractive 550-nm band. We also study the excited-state absorption transition around 860 nm and present, to our knowledge, the first published cross-section values for this transition     

A knowledge-based jig-and-fixture designers' assistant

The state of the art in the technology of jigs and fixtures is reviewed. Heuristic and analytical principles of jig and fixture design are summarised. An interactive knowledge-based program for assisting designers of jigs and fixtures is described. The program incorporates design principles in the form of explicity declared facts and rules as well as numerical procedures. The declarative part of the program is implemented in an expert system shell with a powerful inference engine and comprehensive explanation and trace facilities. Details of these are given, together with a simplified example of a design session using the program.