Investigation of the action of flame retardants in cellulose. I. Investigation of the flame retardant action of 2,2′-oxybis(5,5-dimethyl-1,3,2-dioxaphosphorinane-2,2′-disulfide) in cellulose

Pyrolysis experiments were performed in high vacuum and under reduced air pressure (100 Pa). The volatile products of pure cellulose and cellulose containing various amounts of flame retardant 2,2′-oxybis (5,5-dimethyl-1,3,2-dioxaphosphorinane-2,2′-disulfide), i.e., Sandoflam 5060 of Sandoz AG, were studied by means of gas chromatography in combination with mass spectroscopy. The volatile products were characterized with infrared spectroscopy. The studied revealed that the incorporation of the flame retardant enhanced the water release and shifted the onset of this reaction to lower temperature. On the basis of these findings an explanation for the mechanism of flame retardancy in generated cellulose fibers modified with this particular flame retardant is attempted. From experiments with different residual air pressure the influence of oxygen on the primary processes of the pyrolytic degradation of cellulose is being discussed.     

Uniaxial compression of Swiss-type cheese at different strain rates

Rheological behaviour of 48 Swiss-type cheese samples in lubricated uniaxial compression was evaluated at three initial strain rates ranging from 4·76 × 10⁻³ to 7·62 × 10⁻² s⁻¹. Modulus, apparent fracture stress and apparent fracture strain increased significantly with increasing strain rate, which is attributed to the viscoelastic nature of cheese. The influence of strain rate on apparent fracture strain strongly depended on the shape of the stress-strain curves. The relationship between the rheological parameters evaluated at different strain rates proved to be significant. The strain rate dependency of the apparent fracture strain is further explained by the contribution of elastic and viscous components, which was evaluated in relaxation experiments in the linear viscoelastic region.     

Sensory characterization of human milk

Fore and hind milks from a single morning feed collected from 24 nursing mothers over 3 consecutive d were evaluated for sweetness, viscosity, and mouthcoat by a trained adult panel using magnitude estimation. Milks were perceived as sweet, thin, and low in mouthcoat. Hind milks were slightly more viscous and mouthcoating than fore milks. The higher fat content in hind milk was associated with higher estimation of physical viscosity. Milk fat content decreased as maternal age increased. Significant differences occurred between milks in lactose, fat, and protein contents. By use of a sweetness power function curve, the sweetness intensity of human milk was estimated as equivalent to a 2.12% sucrose solution.     

An effective medium model for TM-polarized nonlinear guided wavesin multilayer systems

An effective medium model for TM-polarized nonlinear guided waves is derived. It is shown that a periodic multifilm configuration can be described as a single film with effective dielectric tensor components. Unlike in the TE-case these tensor components depend on the local fields and hence cannot be defined globally. Numerical investigations indicate that the effective medium model can be applied for most situations     

Sensitivity of trigate MOSFETs to random dopant induced threshold voltage fluctuations

In this paper, we investigate random doping fluctuation effects in trigate SOI MOSFETs by solving the three-dimensional (3D) Poisson, drift-diffusion and continuity equations numerically. A single doping impurity atom is introduced in the undoped channel region of the device and the resulting shift of threshold voltage is measured from the simulated I–V characteristics. This enables the derivation of the threshold voltage shift (ΔV_TH) for any arbitrary location of the doping atom in the transistor. Based on an analysis of a sub-20 nm trigate MOSFET device, we find that the typical variation of V_TH per doping atom is a few tens of mV. Inversion-mode (IM) trigate devices are more sensitive to the doping fluctuation effects than accumulation-mode (AM) devices. The threshold voltage shift arising from doping fluctuations is maximum when the doping atom is near the center of the channel region, which means the original SOI film doping, the random contamination effects or any other impurity doping in the channel region is more important than atoms introduced in the channel by the S/D implantation process for sub-20 nm transistors.     

Phase-insensitive all-optical transistors based on second-ordernonlinearities

We demonstrate and compare two phase-insensitive all-optical transistors (AOT's) based on frequency-degenerate quadratic three-wave interactions. In particular, we demonstrate gain using KTP in a type II geometry. Both AOT's exploit the phase insensitivity inherent to three-wave parametric processes when only two fields are input, providing amplification of a small signal at the operating frequency via the interaction with a second-harmonic wave. The first scheme is based on successive up- and down-conversion (i.e., cascading) while the second relies on parametric down-conversion. We obtain gains of 5 and 160 in the two configurations, respectively, with a significant background and output coherent to the pump in the first case, no background and coherence between output and signal in the second     

Analytical model for the high-temperature behaviour of the subthreshold slope in MuGFETs

As MuGFETs are promising contenders for the end of the silicon Roadmap, their high-temperature behaviour needs to be addressed. In this work we investigate the variations of the subthreshold slope (SS) of double-gate devices and MuGFETs with intrinsic doping as a function of the temperature and fin width. Focus is placed on the superlinear behaviour of SS occurring above a certain temperature threshold. Numerical simulations are performed using Comsol Multiphysics^™ and a 1D analytical model is developed. The model, which includes the effect of film and gate oxide thickness, is shown to accurately fit the numerical data. A new definition for the subthreshold slope under high-temperature operation is proposed. The high-temperature subthreshold slope degradation is shown to increase with fin width.     

Cure kinetics of the cardanyl acrylate–styrene system using isothermal differential scanning calorimetry

The curing kinetics of styrene (30 wt %) and cardanyl acrylate (70 wt %), which was synthesized from cardanol and acryloyl chloride, was investigated by differential scanning calorimetry under isothermal condition. The method allows determination of the most suitable kinetic model and corresponding parameters. All kinetic parameters including the reaction order, activation energy E_a and kinetic rate constant were evaluated. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2034–2039, 2002     

Effect of the degree of branching on the glass transition temperature of polyesters

Glass transition temperature dependence on the branching degree can be empirically estimated by excluding additional effects on this parameter as molecular weight distribution, end group interactions or crystallization. In this communication aliphatic–aromatic polyesters with a well defined degree of branching between 0% (linear) and 50% (hyperbranched) are investigated by differential scanning calorimetry. The hydrogen bonding effect of the OH-terminal groups was successfully extracted from the pure branching effect by protection of the end-functionalities. Fractionation of samples with variation of the branching degree and end-functionalities led to series of narrowly distributed molar masses. The dependence of the molecular weight on the glass transition temperature for different branching degrees was calculated and compared for polar and non-polar end groups.