Tunable wavelength filters based on nonlinear optical interactionsin semiconductor amplifiers

A novel class of narrow-band tunable wavelength filters is proposed and evaluated. Wavelength selectivity of the proposed filters Is derived from the finite time response of an optical nonlinearity. The nonlinearity is gain saturation in semiconductor optical amplifier structures. The filters are shown to have very narrow passbands tunable over the entire semiconductor gain bandwidth. The key to filter implementation is a device configuration in which the wave-mixing products can be isolated from the amplified inputs. Three integrated optics compatible configurations are considered and shown to have high filter throughputs 34 to 180% and subangstrom bandwidths     

Mathematical modelling of a reverse flow reactor with catalytic surface dynamics

This paper studies a system of partial differential equations modelling the behaviour of a reverse flow reactor. For the parameters appropriate for the oxidation of ammonia on a Pt/Al₂O₃ catalyst in a typical laboratory set-up, the reactor may be split into regions where approximate formulas that determine its behaviour are deduced. Numerical calculations are presented and can be used to compare with the analytical formulas. The physical insight gained from the asymptotic analysis suggests a new switching strategy which is the subject of numerical experiments. The switching strategy is found to be efficient at minimising the ammonia exiting the reactor after reversal.     

Photo-bleaching induced electro-optic polymer modulators with dual driving electrodes operating at 1.55 /spl mu/m wavelength

Electro-optic (EO) polymeric Mach-Zehnder (MZ) modulators with photo-bleaching (PB) induced waveguides and dual driving electrodes operating at 1.55 /spl mu/m wavelength have been demonstrated. The half-wave voltage of the integrated polymeric modulator was 4.5 V in a push-pull configuration with a 1.5 cm interaction length. The extinction ratio was greater than 20 dB, and the fibre-to-fibre insertion loss was 8 dB for the TM polarisation. The achieved fibre-to-fibre insertion loss and driving voltage are the best, to the authors knowledge, in the reported PB induced MZ EO polymeric modulators.     

Metal-defined polymeric variable optical attenuator

A variable optical attenuator (VOA) based on a metal-defined polymeric optical waveguide has been demonstrated for the first time. The metal film stressor deposited on top of the upper cladding layer not only produces the refractive index change within the core layer, but also acts as a thin-film heater allowing thermal tuning of the optical power within a metal-defined optical waveguide. Fabricated devices exhibit greater than 25 dB of optical attenuation with an applied electrical current of /spl sim/40 mA at 1550-nm wavelength. The switching speed of the VOA exhibits 800 /spl mu/s of rising and 720 /spl mu/s of falling time.     

Oriented Barium Titanate Thick Films by Reactive Coating on Rutile

A mechanically stable [110] oriented tetragonal barium titanate layer of ≤50 μm thickness on a rutile substrate has been obtained by reactive coating of screen printed barium titanate submicrometer powder on the substrate and following a two-step firing cycle at 1400°C for 6 min and 1310°C for 60 min. The results have been explained taking into account the BaTiO₃–TiO₂ equilibrium phase diagram.     

Analysis of Optical Losses in a Photoelectrochemical Cell: A Tool for Precise Absorptance Estimation

Optical losses in a photoelectrochemical (PEC) cell account for a substantial part of solar‐to‐hydrogen conversion losses, but limited attention is paid to the detailed investigation of optical losses in PEC cells. In this work, an optical model of combined coherent and incoherent light propagation in all layers of the PEC cell based on spectroscopic measurements is presented. Specifically, photoelectrodes using transparent conductive substrates such as F:SnO₂ coated with thin absorber films are focused. The optical model is verified for hematite photoanodes fabricated by atomic layer deposition and successfully used to determine wavelength‐dependent reflection, transmission, layer absorptances, and charge generation rates. Furthermore, the calculated absorptances enable 20–30% more accurate calculations of the absorbed photon‐to‐current efficiency of PEC cells. Our optical model is a powerful tool for the optimization of the optical performance of PEC cells focusing on single absorber or tandem configurations and represents a cornerstone of a complete (optical and electrical) model for PEC water splitting cells.     

Influence of pressure-assisted polymerization on the microstructure and strength of polymer-infiltrated ceramics

A method of manufacturing polymer-infiltrated ceramics (PICs) is to pre-infiltrate a porous ceramic with a liquid monomer and subsequently polymerize the organic component inside the ceramic structure. The volume reduction during polymerization leads to the formation of pores (defects), which has a detrimental effect on the mechanical properties of PICs. To avoid the generation of defects, a new polymerization method that uses pressure during polymerization was developed. To investigate the influences of pressure and heating rate on strength and microstructure, both parameters were varied. The influences of both parameters on the strength of PICs were studied using a biaxial test. The influence on the microstructure was investigated through microscopy. Fracture toughness and R-curve behavior of the manufactured PICs were determined with the SEVNB method. The process parameters have a strong influence on strength and microstructure of PICs. Defect-free PICs with improved strength could be manufactured using elevated pressure during polymerization. As expected, a distinct R-curve behavior and enhanced fracture toughness relative to composites manufactured using conventional methods was found. The developed manufacturing method leads to defectless PICs with increased mechanic behaviors.     

Three-dimensional integrated optics using polymers

Some of the key components are demonstrated to make three-dimensional (3-D) optical integrated circuits possible using polymers. Fabrication techniques of shadow reactive ion etching, shadow photolithography, and gray-level photolithography to produce complex 3-D integrated optic structures are demonstrated. Vertical waveguide bends exhibit excess losses of <0.3 dB, and vertical power splitters possess predictable output splitting ratios between multiple core levels with excess losses of <0.5 dB. Vertical polarization splitters exhibit power extinction ratios of 15 dB between the output core layers. A 1×4 vertical-horizontal power splitter is also demonstrated. Additionally, these techniques are used to integrate different polymer materials into the same optical circuit while easily solving the mode mismatch problem. To show the technique, a polymer electrooptic modulator is vertically integrated with a low-loss waveguide     

Fabrication and characterization of high-speedpolyurethane-disperse red 19 integrated electrooptic modulators foranalog system applications

The fabrication and characterization of polymeric electrooptic modulators, made of a thermally crosslinkable polyurethane with Disperse Red 19 side chains, are summarized in this paper. Straight channel and Mach-Zehnder modulators have been fabricated, packaged and tested for the fiber-optic analog transmission system applications. Device performances including halfwave voltage, insertion loss, on-off ratio, and modulation frequency responses were measured. Long-term halfwave voltage stability, dc-bias voltage stability, and optical power handling capability at 1.3-μm wavelength were investigated. A carrier-to-noise ratio of 53 dB and 80-channel television transmission have been demonstrated using the packaged polymer modulators     

A STRATEGY FOR RESEARCH ON MODEL FORMULATION

The starting point for this commentary is Sacks' and Doyle's conclusion that a central problem for qualitative physics is automating mathematical model formulation. We believe that model formulation is also a central problem for operations research, and although we have focused on models for production planning rather than for engineering systems analysis, our experience confirms that of Sacks and Doyle, that at least parts of model formulation are amenable to automation. In terms of their recommendations for future research, their strategy seems to emphasize the formalization of mathematical knowledge. We wish to stress that understanding the design or analysis context, the problem domain, and resource constraints on the modeling process is equally important. Methods used in cognitive psychology for understanding human problem solving, such as protocol analysis, can complement mathematical study by helping us understanding the processing that human modelers use to bring mathematical knowledge to bear. We have been using the results of such analyses to guide the creation of a model formulation system (MFS) within the Soar architecture. The use of cognitive studies and computer models in tandem seems to represent a viable strategy for making progress in this area.