Hydrogen limitation--a method for controlling the performance of membrane biofilm reactor for autotrophic denitrification of wastewater.

Hydrogen-driven denitrification using the fiber membrane biofilm reactor (MBfR) was evaluated for consistent operation in tertiary wastewater treatment. The possibility of controlling the process rates, as well as biofilm parameters by supplying limited amounts of electron donor (hydrogen), was tested. Limiting the hydrogen supply proved to be efficient in controlling the biofilm growth and performance of the MBfR. Denitrification rates remained unchanged for both synthetic wastewater (SWW) and real municipal wastewater (MWW) effluent as well through the fluctuations in the substrate (NO3-N) concentration. The average denitrification rates were 0.50 (+/- 0.02) g NO3-N per day per m2 for SWW and 0.59 (+/- 0.04) g NO3-N per day per m2 for MWW. Biofilm density rather than thickness was the determining factor in substrate diffusion and biofilm sloughing, ultimately determining operating stability. Limited hydrogen supply assured constant volatile solids (VS) concentration in the biofilm. It was determined that VS/TS ratio higher than 0.25 assured stable biofilm operation. Decrease of VS/TS ratio below 0.25 led to shearing of the nonbiological outer layers of the biofilm. The values of chemical oxygen demand (COD), volatile suspended solids (VSS) and total suspended solids (TSS) in the final effluent were stable and well below wastewater effluent guidelines. Substitutions of bicarbonate with gaseous carbon dioxide as the carbon source did not affect denitrification rates despite lower than optimum pH conditions.     

Hydrogen-driven denitrification of wastewater in an anaerobic submerged membrane bioreactor: potential for water reuse.

An anaerobic submerged membrane bioreactor was coupled with a novel hydrogen delivery system for hydrogenotrophic denitrification of municipal final effluent containing nitrate. The biological treatment unit and hydrogen delivery unit were proven successful in removing nitrate and delivering hydrogen, respectively. Complete hydrogen transfer resulted in reducing nitrate below detectable levels at a loading of 0.14 kg Nm(-3) d(-1). The produced water met all drinking water guidelines except for color and organic carbon. However, the organic carbon was removed by 72% mostly by membrane rejection. To reduce the organic carbon and color of the effluent, post treatment of the produced water is required.     

Trans FA and solid fat contents of margarines marketed in Turkey

Trans FA (TFA), solid fat contents (SFC), and slip melting points of 12 different tub and stick margarines marketed in Turkey were examined in this study. No trans isomers were found in four margarines, which suggests they were formulated from interesterified or blended fats and oils. The products with no TFA generally had more short-chain saturated FA, which suggests coconut oil-based oil components. TFA content of the other 10 products varied from 7.7 to 37.8%. Compared to the products formulated in North America, Turkish margarines contain more TFA and have higher SFC.     

An investigation on wear behavior of UHMWPE/carbide composites at elevated temperatures

Ultra-high molecular weight polyethylene (UHMWPE) is extensively used in frictional applications due to its advanced wear resistance. This advanced polymer is reinforced with hard particulate fillers for further developments against wear conditions. Since elevated temperatures prevail in the service conditions, wear behavior of UHMWPE composites is an important issue for the engineering applications. In the present work, UHMWPE-based composites including silicon carbide (SiC) fillers were fabricated in a compression molding chamber. In the specimen preparation stage, molding pressure, filler amount, and filler particle size were varied to investigate the influence of these variables. Upon deciding the optimum parameters from the wear tests conducted at room temperature, the wear experiments were repeated for the optimum specimen at elevated temperatures, such as 40 and 60°C. According to the results, the wear behavior of the SiC/UHMWPE composites is heavily changed by the effect of elevated temperature. Adhesive effect is pronounced at elevated temperatures while the wear characteristics possess the abrasive effect in the sliding path. In addition, the composites exhibit an accelerated material loss as temperature increases during the frictional system.     

Optimization of clamped circular piezoelectric composite actuators

This paper addresses the design of clamped circular piezoceramic composite unimorph and bimorph configurations, specifically the conflicting requirements of maximum volume displacement for a prescribed bandwidth. An optimization problem is formulated that implements analytical solutions for unimorph and bimorph configurations using laminated plate theory, including the use of oppositely polarized piezoceramic patches. A range of actuator geometric parameters are studied, and bounds for volume displacement and natural frequency of optimal designs are determined and presented via design curves. In the selected design space, Pareto optimization results for unimorph and bimorph configurations show that optimal volume displacement is related to the bandwidth by a universal power law such that the product of the square of the natural frequency and the displaced volume, a “gain-bandwidth” product, is a constant. Characteristic trends are also described that are independent of the actuator radius for the Pareto optimal piezoceramic patch thickness and radius versus normalized bandwidth. The results are relevant, for example, in the design of zero-net mass-flux or synthetic jet actuators used in flow control applications.     

An assessment of total RMR classification system using unified simulation model based on artificial neural networks

Engineering design has great importance in the cost and safety of engineering structures. Rock mass rating (RMR) system has become a reliable and widespread pre-design system for its ease of use and variety in engineering applications such as tunnels, foundations, and slopes. In RMR system, six parameters are employed in classifying a rock mass: uniaxial compressive strength of intact rock material (UCS), rock quality designation (RQD), spacing of discontinuities (SD), condition of discontinuities (CD), condition of groundwater (CG), and orientation of discontinuities (OD). The ratings of the first three parameters UCS, RQD, and SD are determined via graphic readings where the last three parameters CD, CG, and OD are estimated by the tables that are composed of interval valued linguistic expressions. Because of these linguistic expresions, the estimated rating values of the last three become fuzzy especially when the related conditions are close to border of any two classes. In such cases, these fuzzy situations could lead up incorrect rock class estimations. In this study, an empirical database based on the linguistic expressions for CD, CG, and OD is developed for training Artificial Neural Network (ANN) classifiers. The results obtained from graphical readings and ANN classifiers are unified in a simulation model (USM). The data obtained from five different tunnels, which were excavated for derivation purpose, are used to evaluate classification results of conventional method and proposed model. Finally, it is noted that more accurate and realistic ratings are reached by means of proposed model.     

Foresight analysis of wind power in Turkey

The Turkish wind energy industry is one of the most competitive and fastest growing industries in the energy sector. Industrial energy demands, Kyoto agreement and carbon trade are shown as probable causes. Currently, Turkey has a total installed capacity of about 48.5 GW for electricity from all energy sources. High energy prices and unstable suppliers have stimulated Turkey's growing interest in wind business and wind power. This paper analyzes Turkey's wind energy future perspective and power generation strategy with a view to explaining Delphi approach to wind energy development. In this study, the two‐round Delphi survey was conducted by experts to determine and measure the expectations of the sector representatives through online surveys where a total of 70 experts responded from 24 different locations. The majority of the Delphi survey respondents were from 23 different universities (60%), electricity generation industries (21%), two different governmental organizations (11%), nongovernmental organizations (6%) and other institutions (2%). The article discusses not only the expert sights on wind energy technology but also all bibliometrical approaches. The results showed that Turkey's wind power installed capacity is expected to exceed 40 GW by the end of the 2020 s and in the middle of the 2030 s, and Turkey would be the European leading country in the field of electricity generation from the wind. Copyright © 2011 John Wiley & Sons, Ltd.     

Microstructural features and electrical properties of copper oxide added potassium sodium niobate ceramics

In this study, effects of 0.5, 1.0 and 1.5 mole% CuO addition on the properties of potassium sodium niobate (K_0.5Na_0.5)NbO₃-KNN ceramics were investigated. Pure KNN and CuO-added KNN pellet samples were sintered at 1100 and 1090 °C for 4 h, respectively. Phase analysis showed that all samples crystallized in pure orthorhombic perovskite phase. Addition of 1.0 and 1.5 mole% CuO caused grain growth, densification and formation of a liquid phase at the grain boundaries. Curie temperature has shifted from 480 to 435 °C with increasing CuO ratio. The most remarkable characteristic of the hysteresis loops were the constricted nature of the 0.5 mole% CuO-added KNN's curve and the antiferroelectric-like appearance of the 1.5 mole% CuO-added KNN's curve. Piezeoelectric properties of d₃₃ = 120 pC/N, k_p = 0.27 and Q_m = 772 were obtained from the 1.5 mole% CuO-added KNN.     

Stabilized electrospinning of heat stimuli/in situ crosslinkable nanofibers and their self‐same nanocomposites

We present a strategy for stabilizing the morphological integrity of electrospun polymeric nanofibers by heat stimuli in situ crosslinking. Amorphous polymer nanofibers, such as polystyrene (PS) and its co‐polymers tend to lose their fiber morphology during processing at temperatures above their glass transition temperature (T_g) typically bound to happen in nanocomposite/structural composite applications. As an answer to this problem, incorporation of the crosslinking agents, phthalic anhydride (PA) and tributylamine (TBA), into the electrospinning polymer solution functionalized by glycidylmethacrylate (GMA) copolymerization, namely P(St‐co‐GMA), is demonstrated. Despite the presence of the crosslinker molecules, the electrospinning polymer solution is stable and its viscosity remains unaffected below 60 °C. Crosslinking reaction stands‐by and can be thermally stimulated during post‐processing of the electrospun P(St‐co‐GMA)/PA‐TBA fiber mat at intermediate temperatures (below the T_g). This strategy enables the preservation of the nanofiber morphology during subsequent high temperature processing. The crosslinking event leads to an increase in T_g of the base polymer by 30 °C depending on degree of crosslinking. Crosslinked nanofibers are able to maintain their nanofibrous morphology above the T_g and upon exposure to organic solvents. In situ crosslinking in epoxy matrix is also reported as an example of high temperature demanding application/processing. Finally, a self‐same fibrous nanocomposite is demonstrated by dual electrospinning of P(St‐co‐GMA) and stabilized P(St‐co‐GMA)/PA‐TBA, forming an intermingled nanofibrous mat, followed by a heating cycle. The product is a composite of crosslinked P(St‐co‐GMA)/PA‐TBA fibers fused by P(St‐co‐GMA) matrix. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44090.     

Effect of Deep Cryogenic Treatment on Wear Resistance of AISI 52100 Bearing Steel

In this study, the effects of deep cryogenic treatment (DCT) on the wear resistance of AISI 52100 bearing steel were investigated. For this purpose, a number of bearing steel samples were held for different times (12, 24, 36, 48, 60 h) at deep cryogenic temperatures (?145 °C). The wear experiments were carried out in a ball–disk arrangement, by applying loads of 10 and 20 N and a sliding velocity of 0.15 m/s. After conducting the experimental studies, 36 h was found to be the optimal holding time. At this holding time, the wear rate and friction coefficient were decreased, while the hardness reached to maximum values. It was observed that DCT led to significant microstructural changes, which resulted in improved tribological properties.