Using Markov Learning Utilization Model for Resource Allocation in Cloud of Thing Network

Wireless Personal Communications - The integration of the Internet of Things (IoT) and cloud environment has led to the creation of Cloud of Things, which has given rise to new challenges in IoT...     

Waterborne acrylic–polyaniline nanocomposite as antistatic coating: preparation and characterization

An antistatic and electrically conductive acrylic–polyaniline nanocomposite coating was successfully synthesized by interfacial polymerization of aniline in the presence of acrylic latex. The acrylic latex was prepared through emulsion polymerization, and aniline was polymerized by in situ interfacial polymerization at the interface of acrylic latex/chloroform phase. Fourier transform infrared spectroscopy (FTIR), UV–Vis spectroscopy and CHNS elemental analysis revealed the existence of 6.24 wt% emeraldine salt of polyaniline (PAni) in the dried film of the nanocomposite. Scanning electron microscopy (SEM) confirmed the presence of colloidal polymer particles in the aqueous phase which was confirmed to have some advantages, including prevention of aggregation of particles, dispersibility improvement and enhancement of the PAni nanofibers aspect ratio in the acrylic polymer matrix. According to SEM results, PAni fibers with the length ranging from 12 to 67 µm and diameters between 0.078 and 1 µm, highly dispersed in the acrylic polymer matrix, were successfully synthesized. Thermal, electrical and mechanical properties of the acrylic copolymer were significantly affected by PAni incorporation. The onset degradation temperature in thermogravimetric analysis revealed that the thermal stability of the nanocomposite was improved compared to that of the pure acrylic copolymer. The nanocomposite film showed electrical conductivity of about 0.025 S/cm at room temperature, along with satisfactory mechanical properties, attractive as an antistatic material in coating applications.     

Effectiveness of PANI/Cu/TiO2 ternary nanocomposite on antibacterial and antistatic behaviors in polyurethane coatings

Surfaces with antibacterial and antistatic functionalities are one of the new demands of todays' industry. Therefore, a facile method for the preparation of multifunctional polyaniline/copper/TiO₂ (PANI/Cu/TiO₂) ternary nanocomposite based on in situ polymerization is presented. This nanocomposite was characterized through the different techniques and was utilized for induction of antibacterial and antistatic properties in polyurethane coatings. Measurement of the conductivity of PANI/Cu/TiO₂ ternary nanocomposite indicated higher electrical conductivity of this nanocomposite compared to pure PANI. The antibacterial activity of the modified polyurethane coatings was tested against Gram-positive and Gram-negative bacteria which led to remarkable reduction in bacterial growth. Besides, it was observed that polyurethane coating with 2 wt % content of ternary nanocomposite has a surface electrical resistance equal 4 × 10⁸ Ω/sq which acquires surface electrical resistance of standard antistatic coatings. The final coatings were also characterized in terms of thermal and mechanical properties to investigate the effect of the ternary nanocomposite on improvement of these properties. © 2020 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48825.     

Preparation and characterization of a polyaniline/poly(butyl acrylate–vinyl acetate) composite as a novel conducting polymer composite

This is the first report on the preparation and characterization of a polyaniline/poly(butyl acrylate–vinyl acetate) composite. The composite was prepared by the emulsion polymerization of aniline in a medium containing poly(butyl acrylate–vinyl acetate). Films prepared from the composite (cast from an aqueous medium) had excellent mechanical properties and could be stretched up to 900%. The resultant composite was soluble in common organic solvents, and a stable water‐based dispersion could also be prepared. An electrical conductivity of 2.2 S cm^?1 was obtained. Cyclic voltammograms revealed that the composite was electroactive. It had excellent adhesion to either glass or steel plate. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2525–2531, 2003     

Synthesis and characterization of cadmium doped lead-borate glasses

Cadmium doped lead-borate glasses were prepared from the melts in appropriate proportions of PbO₂, H₃BO₃ and (15–40 mol%) CdO mixture in the temperature range 700–950°C. The infrared spectra of the glasses in the range 400–4000 cm^-1 show their structures. No boroxol ring formation was observed in the structure of these glasses. Furthermore, doped cadmium atoms were not seen in tetrahedral coordination. But the conversion of three-fold to four-fold coordination of boron atoms in the structure of glasses was observed.     

Physicochemical evaluation of nanocomposite hydrogels with covalently incorporated poly(vinyl alcohol) functionalized graphene oxide

To avoid the negative effect of graphene oxide (GO) nanosheets aggregation in aqueous solutions on physicochemical properties of GO incorporated nanocomposite hydrogels, poly(vinyl alcohol)-functionalized GO (GO-es-PVA) are synthesized and are used for preparation of nanocomposite hydrogels. By graft copolymerization of GO-es-PVA with poly(AA-co-AAm) chains, the nanocomposite hydrogel samples with covalently incorporated GO-es-PVA are achieved. FTIR spectroscopy, XRD analysis, and SEM and EDAX techniques confirm successful synthesis process. It is clear that GO-es-PVA content has significant effect on physicochemical properties of nanocomposite hydrogels, such as improvement of the water uptake properties, porosity, and gel strength. The hydrogel sample with 1:80 mass ratio of GO-es-PVA/AAm has the best physicochemical properties due to the optimum amount of GO-es-PVA, which gives the hydrogel proper viscoelasticity as well as fine porosity and water uptake rate. Interpenetration of PVA chains into the polymeric networks makes the movement of the polymer chains easier, which leads to softer polymeric networks. This phenomenon is called plasticizing effect. The plasticizing nature of PVA and its high hydrophilicity are the main reasons for the fine physicochemical properties. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48025.     

Preparation and characterization of an epoxy nanocomposite toughened by a combination of thermoplastic,layered and particulate nano-fillers

This paper reports the development of an epoxy-based nanocomposite toughened by the combination of thermoplastic, layered and particulate nano-fillers. The main objective of this work is to incorporate poly(acrylonitrile-co-butadiene-co-styrene) (ABS), clay (layered nano-filler) and nano-TiO₂ (particulate nano-filler) into epoxy matrix with the aim of obtaining the quaternary nanocomposite with higher impact strength and lower cost without attenuating the other desired mechanical properties such as tensile strength. Taguchi methodology was applied for the optimization and statistical determination of the significant factors influencing the mechanical properties of the quaternary nanocomposite. Impact and tensile strengths of the quaternary nanocomposite with optimum composition increased by 168% and 64% compared to neat epoxy, respectively. Furthermore, synergistic effect was observed with the addition of three type modifiers. It was found that ABS content has the most significant effect on mechanical properties of the obtained quaternary nanocomposite. Also correlation between morphological and mechanical properties of the nanocomposite was investigated. A dispersion of nano-size ABS and TiO₂ particles along with exfoliated clay nano-platelets in epoxy matrix was achieved as main morphological property of the quaternary nanocomposite. A new morphology was obtained for ABS phase in epoxy rich matrix.     

Synthesis,characterization, and swelling kinetic study of porous superabsorbent hydrogel nanocomposite based on sulfonated carboxymethylcellulose and silica nanoparticles

New superabsorbent nanocomposite was synthesized by free-radical graft polymerization of sulfonated-carboxymethyl cellulose (SCMC) with acrylic acid (AA) in the presence of polyvinylpyrrolidone (PVP) and silica nanoparticles. Carboxymethyl cellulose (CMC) was first sulfonated using chlorosulfonic acid, and then AA monomers were grafted onto SCMC. FTIR results confirmed that sulfonation of CMC as well as grafting of AA monomers onto SCMC has been performed successfully. Moreover, the presence of silica nanoparticles into superabsorbent nanocomposite was evaluated with EDX analysis. The element mappings show a homogenous distribution of silica nanoparticles throughout the hydrogel nanocomposite. SEM images exhibited porous morphology for hydrogel nanocomposite, which was due to the incorporation of PVP in its network. The experimental findings from TGA analysis indicated that incorporation of PVP and silica nanoparticles into the hydrogel network improved thermal stability of superabsorbent nanocomposite. Swelling kinetic studies revealed that superabsorbent nanocomposite hydrogel had higher equilibrium swelling capacity and swelling rate compared with the neat hydrogel sample. Besides that, superabsorbent nanocomposite depicted excellent salt and pH-sensitive behavior in different saline and pH solutions. As a consequence, this hydrogel nanocomposite acts as useful water reservoir, which might be most profitable in agricultural applications.     

Evaluation of initial deposition rate of electroless Ni–P layers by QCM method

Electroless nickel–phosphorus (ENP) initial deposition rates from a glycine bath were studied by means of the quartz crystal microbalance (QCM) method. SEM and EDX methods were also used to study the morphology and elemental analysis of deposits. The effect of pH, temperature and the type of activation process on the initial deposition rate, surface morphology and surface elemental analysis of deposits were evaluated. Increasing the pH and the temperature cause an increase in deposition rate and a decrease in P content of deposits. The phosphorus content of obtained deposits in pre-plate method was greater than in sensitizer–activator process under the same conditions of the alloy deposition. The surface morphology depends on P content of deposits. By decreasing the P content of deposits, the grain size increases.     

PANI-chitosan-TiO2 ternary nanocomposite and its effectiveness on antibacterial and antistatic behavior of epoxy coating

A straightforward approach has been developed for fabricating antibacterial and antistatic epoxy coatings by using polyaniline-chitosan modified TiO₂ ternary nanocomposite. This nanocomposite was synthesized through the following steps. First, chitosan was grafted onto the TiO₂ nanoparticles and then final nanocomposite was prepared via solution polymerization of aniline. Electrical conductivity measurement revealed that nanocomposite with 7.5 wt % of the modified TiO₂ nanoparticles has noticeably higher conductivity compared to polyaniline. Evaluating the coatings' antibacterial property indicated epoxy coatings with the content of ternary nanocomposite show significant bactericidal activity against Gram-positive bacteria and have acceptable antibacterial action against Gram-negative ones. Also, obtained results showed that the ternary nanocomposite would greatly decrease coatings' surface resistivity and when nanocomposite content is about 2 wt % surface resistivity is about 3 × 10⁷ Ω sq⁻¹. On the contrary, the coating with nanocomposite loading exhibits improved thermal and mechanical performance compared to the coating made of neat epoxy. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47629.