Due to their long-term stability, even under extreme conditions, oxide ceramics have attracted significant attention in emerging fields like moist-electric generation However, the inherent brittleness and low voltage output of oxide ceramic-based moist-electric generators (MEGs) limit their applications in wearable electronics. Herein, a facile strategy involving the combination of sol-gel electrospinning and calcination is used to fabricate flexible and freestanding TiO2/ZrO2 (TZ) composite nanofiber-based MEGs. The excellent flexibility of the TZ nanofiber membranes can be attributed to the suppression of their crystal structure transformation, dispersion of stress concentration, and reduction of crack propagation via interfacial engineering The porous structure of the electrospun nanofiber membrane features an abundance of charged narrow channels for the diffusion of water molecules and generates a streaming potential: The optimal voltage output reached ~0.8 V, which is the highest value reported for an oxide ceramic-based MEG. Furthermore, the as-fabricated nanofiber-based MEG exhibits good self-cleaning capability to degrade organic pollutants under ultraviolet irradiation. By integrating mechanical flexibility, high performance, and a self-cleaning effect, this work presents a new idea for exploring diverse, efficient, and wearable oxide ceramic-based MEGs.
The agglomeration of point defects in ferroelectric ceramics could be driven by repeated domain switching under cyclic electric
field. The evolution equation of pore concentration under cyclic electric field is derived, with the help of a relation between
the pore concentration and the extent of pore agglomeration. The results of the simulation agree quantitatively with the experimental
data. An integrated framework about the mechanisms of electrically induced fatigue is proposed, which links the mechanisms
at different scales. 相似文献
Cathode material LiMn2O4 thin films were prepared by aqueous solution deposition using lithium acetate and manganese acetate as starting materials. The structures, morphologies, and the first discharge specific capacity of the thin films were investigated as a function of annealing temperature and time. The cycling properties of the thin films were also examined. The results show that LiMn2O4 thin films prepared by this method are homogenous and crack-free. The thin film annealed at 750°C for 30 min has good rechargeability. The capacity loss per cycle is about 0.05% after being cycled 100 times. 相似文献