Effect of 100 KeV Ar+ ion beam irradiation on ZnO thin films – Influence of morphology vis-a-vis electrode/electrolyte interface and its impact on photoelectrochemical water splitting

The present study attempts quantitative determination of changes in the morphological surface features viz. fractal dimension, lower and upper cut off length scale through Power Spectral Density analysis prior to and after irradiation of 100 KeV Ar⁺ ion beam at incidence angles of 0°, 40° and 60° on ZnO thin films. All the unirradiated and irradiated samples are subjected to photoelectrochemical characterization and a correlation between photoelectrochemical performance and morphological parameters is established. Sample irradiated at 40° angle at the fluence of 5 × 10¹⁶ ions/cm² is found to possess maximum fractal dimension of 2.72, lower and upper cut off length scale of 3.16 nm and 63.00 nm respectively. This sample exhibits maximum photocurrent density of 3.19 mA/cm² and applied bias photon-to-current efficiency of 1.12% at 1.23 V/RHE. Hydrogen gas collected for duration of 1 h for the same sample was ~4.83 mLcm^?2.     

Changes in Δ5- and Δ7-sterols during germination and seedling development ofCucurbita maximaduring germination and seedling development ofCucurbita maxima

While seeds ofCucurbita maxima contain both Δ⁵- and Δ⁷-sterols, the former, which have been described earlier, now have been found to disappear during germination. This suggests that a function exists for the Δ⁵-compounds only in the early part of the life cycle ofC. maxima, unlike most of the other higher plants studied. In contrast to the Δ⁵-sterols, the level of Δ⁷-sterols increased during germination as well as during seedling development and maturation. The period of transition between germination and seedling development appeared to be of special importance in terms of sterol changes. This period represented a surge of sterol biosynthesis with an ontogenetic shift in sterol composition from approximately equal amounts of 24α- and 24β-ethyl stereochemistry to a predominance of the former. The sterol composition of the mature plants included only about 5% of the 24β-ethylsterols. The configurational relationships were demonstrated by high resolution¹H-NMR. The sterols of the mature plants were: 25(27)-dehydrochondrillasterol, 24β-ethyl-25(27)-dehydrolathosterol, avenasterol, spinasterol, 22-dihydrospinasterol and 24ξ-methyllathosterol. Based on the changes which occurred in the relative amounts of the Δ⁷-sterols, it did not appear that the Δ⁵-components were being converted to their Δ⁷-analogs. A portion of this work was presented at the meeting of the American Oil Chemists' Society in May, 1985 in Philadelphia.     

Vinyl acetate monomer—a pilot plant study

The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid.     

Development of a simple low-cost solar simulator for indoor collector testing

Indoor test methods for solar collectors are widely accepted and recommended by ASHRAE. The development of a solar simulator for indoor testing and the certification procedure for photo-thermal solar devices is discussed in this paper. The system consists of 14 quartz halogen lamps and provides a testing area of about 1 × 1 m. The irradiance can be varied from 400 to 1500 W/m². This is achieved by varying the input power supplied to individual lamps. The radiation output characteristics of a single lamp have been studied. The distribution of intensity over the covered area of 1·20 × 1·20 m has been recorded using a precision Eppley pyranometer.A variety of collectors—evacuated tubular collectors and flat-plate collectors of both liquid and air heating types—has been tested under sufficiently stable insolation conditions. Results for a conventional solar air heater are presented together with suggestions for further improvements.     

Electricity generation from rice husk in Indian rice mills: Potential and financial viability

Rice husk generated as a by-product of rice processing is an important energy resource. The availability of this resource in India has been assessed and the technologies for exploitation of its energy potential in rice processing industry discussed. Nomographs have been developed for estimation of the husk required to meet the energy demand of parboiling, drying and milling operations. The unit cost of electricity using rice husk gasifier-based power generation systems has been calculated and its financial feasibility assessed in comparison with utility-supplied and diesel-generated electricity. With the cost and efficiency data assumed here, the unit cost of electricity produced by rice husk gasifier-dual fuel engine-generator system varies between Rs 2/kWh and Rs 7/kWh. (Note: 35 Rs approximates to $US 1.)