Harnessing “Click”‐Type Chemistry for the Preparation of Novel Electronic Materials

Sequence‐independent or “click”‐type chemistry is applied for the preparation of novel π‐conjugated oligomers. A variety of bi‐functional monomers for Wittig–Horner olefination are developed and applied in a sequential protection–deprotection process for the preparation of structurally similar π‐conjugated oligomers. Selected oligomers are incorporated as the organic semiconductors in light‐emitting diodes and a field‐effect transistor, demonstrating the potential of the approach.     

Simple iterative receivers for MIMO LP-OFDM systems

In this paper,Lp-ofdm is combined with differentMimo schemes in order to improve performance in terms of diversity gain and to exploit capacity brought by theMimo channel. The original contribution is the development of a generic iterative receiver designed forLp mimo transmission able to work whatever the antenna configuration and the spatial coding scheme. By using a globalMmse criterion, interference terms coming from space-time coding and linear precoding are jointly treated leading to a very good trade-off between performance and complexity compared to trellis based detectors particularly for high order modulations, high number of antennas and/or large size of precoding matrices.     

Enhanced inactivation of E. coli bacteria using immobilized porous TiO2 photoelectrocatalysis

Immobilized TiO₂ nanotube electrodes with high surface areas were grown via electrochemical anodization in aqueous solution containing fluoride ions for photocatalysis applications. The photoelectrochemical properties of the grown immobilized TiO₂ film were studied by potentiodynamic measurements (linear sweep voltammetry), in addition to the calculation of the photocurrent response. The nanotube electrode properties were compared to mesoporous TiO₂ electrodes grown by anodization in sulfuric acid at high potentials (above the microsparking potential) and to 1 g/l P-25 TiO₂ powder. Photocatalyst films were evaluated by high resolution SEM and XRD for surface and crystallographic characterization. Finally, photoelectrocatalytic application of TiO₂ was studied via inactivation of E. coli. The use of the high surface area TiO₂ nanotubes resulted in a high photocurrent and an extremely rapid E. coli inactivation rate of ∼10⁶ CFU/ml bacteria within 10 min. The immobilized nanotube system is proven to be the most potent electrode for water purification.     

Adaptive water management in Israel: structure and policy options

Difficulties in integrating technical, economic and institutional factors present a major gap in analytical capacity to guide water policy. This article presents an integrated framework to support water policy and guide water management choices, with application to Israel. That framework rests on the theory of economic policy originally developed by Tinbergen. It sees national water challenges as consisting of external factors, constraints, policy instruments and targets. The need for a modern implementation of the theory of economic policy is motivated by emerging environmental requirements, scarce water, growing demands for domestic use, and ongoing needs to implement existing and potential peace agreements.     

Fast GL(n)-Invariant Framework for Tensors Regularization

We propose a novel framework for regularization of symmetric positive-definite (SPD) tensors (e.g., diffusion tensors). This framework is based on a local differential geometric approach. The manifold of symmetric positive-definite (SPD) matrices, P _n , is parameterized via the Iwasawa coordinate system. In this framework distances on P _n are measured in terms of a natural GL(n)-invariant metric. Via the mathematical concept of fiber bundles, we describe the tensor-valued image as a section where the metric over the section is induced by the metric over P _n . Then, a functional over the sections accompanied by a suitable data fitting term is defined. The variation of this functional with respect to the Iwasawa coordinates leads to a set of \frac12n(n+1)\frac{1}{2}n(n+1) coupled equations of motion. By means of the gradient descent method, these equations of motion define a Beltrami flow over P _n . It turns out that the local coordinate approach via the Iwasawa coordinate system results in very simple numerics that leads to fast convergence of the algorithm. Regularization results as well as results of fibers tractography for DTI are presented.     

Threshold of stimulated Brillouin scattering by use of a solar pumped laser

What is to our knowledge the first stimulated Brillouin scattering experiment using a high-power low-gain solar pumped laser is presented. A threshold reflectivity of 0.23% was reached when a peak power of 20.7 kW was used at 7.6 GHz. A cw solar pumped laser was Q-switched with an acousto-optic modulator, and the bandwidth was narrowed with an intracavity etalon. A high polarization ratio (>99.4%) was achieved by use of an intracavity configuration. Higher reflectivity values were limited because of the lack of availability of optical switches.     

Interface Modifications of InAs Quantum‐Dots Solids and their Effects on FET Performance

InAs nanocrystals field‐effect transistors with an ON/OFF ratio of 10⁵ are reported. By tailoring the interface regions in the active layer step‐by‐step, the evolution of the ON/OFF ratio can be followed from approximately 5 all the way to around 10⁵. The formation of a semiconducting solid from colloidal nanocrystals is achieved through targeted design of the nanocrystal–nanocrystal interaction. The manipulation characteristics of the nanocrystal interfaces include the matrix surrounding the inorganic core, the interparticle distance, and the order of nanocrystals in the 3D array. Through careful analysis of device characteristics following each treatment, the effect of each on the physical properties of the films are able to be verified. The enhanced performance is related to interparticle spacing, reduction in sub‐gap states, and better electronic order (lower σ parameter). Films with enhanced charge transport qualities retain their quantum‐confined characteristics throughout the procedure, thus making them useful for optoelectronic applications.