Order-disorder transition and its effect on microwave quality factor Q in Ba(Zn1/3Nb2/3)O3 system

Influences of composition deviation from stoichiometry and heat treatment on crystal phases and Q factor in Ba(Zn_1/3Nb_2/3)O₃(BZN) were studied. The structural order and the crystal phases strongly depended on the slight composition deviation from stoichiometric BZN. The maximum Q factor was obtained at the vicinity of the stoichiometric BZN. In the other regions, non-stoichiometric disordered BZN or ordered BZN with secondary phase were formed, and their Q factors were found to be low. For the stoichiometric BZN, the order-disorder phase transition occurred between 1300 and 1400^°C. The crystal-structural ordering of the stoichiometric BZN was improved by post-annealing at below its transition temperature, conserving the density and the grain size. However, no significant Q factor improvement was found. The Q factor of the stoichiometric BZN strongly depends on the density and grain size not on the crystal-structural order. These results suggest that the ceramic microstructure such as the pore and grain boundary, the secondary phase and lattice defect caused by non-stoichiometry affect the variation of the Q factor in BZN system than the crystal-structural ordering.     

Piezoelectric properties of langasite group based on the ionic size of cation

As langasite A₃BC₃D₂O₁₄ compounds group with piezoelectric properties has no phase transition up to the melting point of 1400–1500 °C, they have been applied for the combustion pressure sensor. As they also have a larger electromechanical coupling factor compared to quartz and nearly the same temperature stability as quartz, the surface acoustic wave (SAW) filters are expected based on the digital transformation of wider bandwidth and higher-bit rates. In the case of three-element compounds such as [R₃]_A[Ga]_B[Ga₃]_C[GaSi]_DO₁₄ (R=La, Pr and Nd), the piezoelectric constant increases with the ionic radius R. In the case of four-element compounds such as [A₃]_A[B]_B[Ga₃]_C[Si₂]_DO₁₄ (A=Ca or Sr, B=Ta or Nb), |d₁₁| and k₁₂ values as a function of A_L/B_L ratio showed a linear relationship completely. There are two effects for the substitutions of A- and B-site cations: the substitution of Sr for Ca brings expansion toward [100] and enlargement in |d₁₁| and k₁₂. On the other hand, as the substitution of Ta for Nb brings not much change, the properties are similar. In this study, five-element compounds such as La_3?xSr_xTa_yGa_5?x+ySi_1+x?2yO₁₄ (0≤x≤3, 0≤y≤1) solid solutions analysed by a single crystal X-ray diffraction are compared with the three- and four-element compounds on the coordinates of oxygen ions. As the coordinates positions are located on the extended line of coordinate positions on the three-element compounds as increasing ionic radius of R-ions in A-site, the piezoelectric properties |d₁₁| and k₁₂ are expected become large.     

Solar-hydrogen energy system-model applied to isolated island

Comparison between a petroleum energy system and a solar-hydrogen energy system is studied in the case where an industry is newly introduced to an isolated island. Assuming a hybrid energy system composed of petroleum, solar energy, hydrogen energy and electric energy, we investigate an optimum economy with the use of computer-aided LP (Linear Programming) and QP (Quadratic Programming) models taking account of the cost functions originated from the acquisition prices of the primary energy and the transport prices. Furthermore, the modified LP model makes it possible to take account of the uncertainties arising from the acquisition instability and environmental protection. Some conditions are clarified under which the introduction of a solar-hydrogen energy system is highly feasible.     

Annealing effect on temperature coefficient of resistivity in La1−xSrxMnO3 ceramics

We investigated annealing effects of La_1?xSr_xMnO₃ (x = 0–0.6) on electrical resistivity and the temperature coefficient of resistivity (TCR). The annealed samples’ resistivity was lower than those of non-annealed samples. For example, annealing changed the resistivity of x = 0.3 at 25 °C from 4.50 × 10^?5 to 3.71 × 10^?5 Ω m. Remarkable difference in TCR was observed after annealing, for x = 0.3, 0.45, and 0.5. For x = 0.3, the TCR after annealing was 4000 ppm/°C, which was 1250 ppm/°C greater than that before annealing. We investigated (1) crystal phase, (2) Mn average valence, (3) Mott insulator–metal transition temperature, and (4) microstructure. The microstructure was remarkably varied for annealed x = 0.3 and 0.5. The average grain size of the x = 0.3 increased from 1.60 up to 2.38 μm. Results show that annealing affects resistivity and TCR because of grain growth during annealing.     

Radiotherapy for carcinoma of the esophagus in aged patients

One hundred fifty-four patients with esophageal carcinoma were treated with either irradiation alone or irradiation combined with surgery at the University of Occupational and Environmental Health Hospital between January 1980 and February 1992. The number of patients 75 years old and older was 25. In patients 74 years old and younger, the overall five-year survival rate by Kaplan-Meier method was 24.5%. The survival rate was best in the patients who were treated by a combination of irradiation and surgery. In patients 75 years old and older, the one-year survival rate was 59%, and the three-year rate was 20%. Aged patients had a tendency to be worse in performance status, and there was no correlation between treatment modality and survival time. We conclude that radiotherapy is useful for treating esophageal cancer in aged patients particularly when maintenance of the quality of life is considered.     

Effect of re-oxidation on dielectric properties in Ni-MLCC

The effect of re-oxidation treatment on the solubility of dopants and the dielectric properties of rare-earths (La, Ho) and V-substituted BaTiO₃ solid solutions, assuming the shell phase of X7R dielectrics, was investigated. Ho-V-substituted samples showed larger increase of the lattice parameter and T _c by re-oxidation treatment compared with La-V-substituted samples. Electron spin resonance measurements revealed that the oxidation of V³⁺ to V⁴⁺ or V⁵⁺ appeared in the range in which the increase of lattice parameter by re-oxidation treatment was observed. This suggests that the increase of T _c is due to the change of preferential occupational site of Ho ion from A-site to B-site, being accompanied with the oxidation of V³⁺. We also investigated the effect of re-oxidation treatment on the electrical properties and microstructure in Ni-MLCC samples, using rare-earths (La, Ho, Yb) and acceptors (Mn, V) doped BaTiO₃ based X7R dielectrics. The change in temperature characteristic of the dielectric constant by re-oxidation treatment was observed for the MLCC samples containing V with smaller content. In the case of Ho-V- and Yb-V-doped samples showed larger increase of the dielectric constant at around 120 °C compared with La-V-doped samples. The relationship between the microstructure and electrical properties of the MLCC sample was investigated by impedance measurement at elevated temperature.     

Fuzzy critical chain method for project scheduling under resource constraints and uncertainty

This paper develops a fuzzy critical chain method for project scheduling under resource constraints and uncertainty. The method consists of developing a desirable deterministic schedule under resource constraints, and adding a project buffer (PB) to the end of the schedule to deal with uncertainty. The size of the project buffer is determined by computations with fuzzy numbers. During project execution, the proposed method focuses on the penetration level in the project buffer, and dynamically updates the schedule to provide a more accurate schedule for actual progress. The use of a project buffer makes the method akin to critical chain project management (CCPM), although no feeding buffers are used. The proposed method is useful for both project planning and execution.     

Mg2SiO4–TiO2 composite ceramics prepared using a liquid phase deposition process

Forsterite (Mg₂SiO₄) indicates a high quality factor (Q·f) of 270,000 GHz and a low dielectric constant ? _r of 6.8, which are applicable for microwave and millimeter-wave dielectric devices. However, a large negative temperature coefficient of resonant frequency (τ _f) of ?73 ppm/°C hinders stability. Actually, Mg₂SiO₄–TiO₂ composite ceramics prepared by ordinary solid state reaction showed improved τ _f to 0 ppm/°C. However, Q·f of the composite ceramics decreased because other phases such as MgTi₂O₅, MgTiO₃ and MgSiO₃ were created in the reaction between TiO₂ and Mg₂SiO₄ during sintering. This study uses a different process to prepare the Mg₂SiO₄–TiO₂ composite ceramics to prevent the production of the secondary phase. Porous Mg₂SiO₄ ceramics were prepared by sintering Mg₂SiO₄ with pore-forming agents. Then, TiO₂ was inserted into the pores using liquid phase deposition (LPD). Deposited TiO₂ in the pores was anatase form. The increase of the inserted anatase TiO₂ amount contributed to improvement of τ _f.     

Precursor phenomenon on ferroelectric transition in multiferroic YMn2O5

Series of RMn₂O₅ (R = Sm-Lu, Bi, Y) are simultaneously ferroelectric and antiferromagnetic at low temperatures. The ferroelectric Curie temperature (T_CE = 25–40 K) is slightly lower than the antiferromagnetic Néel temperature (T_N = ～45 K), implying that the ferroelectricity is induced with the antiferromagnetic long-range order in RMn₂O₅. Previously, we have investigated the thermal expansion anomaly in YMn₂O₅ at higher temperatures than T_N = 45 K, which would be the precursor phenomenon relating to the ferroelectric transition. This study tries to investigate a further detailed precursor phenomenon to make clear the origin of the ferroelectricity in YMn₂O₅. Particularly, we focus on the temperature factors of each cation in the temperature range from 50 K to 170 K. The single crystal X-ray diffraction of YMn₂O₅ was integrated at 298 K and 112 K by using a single crystal diffractometer with an imaging plate. The structural parameters were well refined as Pbam at both temperatures. In the refined result, it was found that the thermal ellipsoid became more anisotropic for the Mn or the Y ions with decreasing temperature from 298 K to 112 K. In addition, the long principal axis of the thermal ellipsoids rotated in the a–b plane with decrease of temperature. At 112 K, the long principal axis of Mn³⁺ thermal ellipsoid in a–b plane is almost parallel to the direction from the apex to the base of the pyramid square. The direction agrees with a possible ionic displacement speculated from the irreducible representation analysis.